Review Article

Risk Evaluation of Pyrolyzed Biochar from Multiple Wastes

Table 5

Organic contaminant potential and effect of biochar amendment.

FeedstockPyrolysis temp (°C)Detected organic pollutantsEffectReference

Hardwood450°C–500°C10 PAHEnhanced seedling growth.
Greatest capacity to neutralize allelochemicals present in corn residues.
[153]
Corn500°C5 PAHEnhanced seedling growth.
732°C15 PAH
Switch grass850°C17 PAHSuppressed seedling growth.
845°C19 PAH
Coconut, pine nut and walnut shells500°CCarbamazepine and tetracyclineFe3O4 enhancement exhibited fast and high sorption for carbamazepine and tetracycline.
Ball milling is effective for degradation of adsorbed carbamazepine and tetracycline on the adsorbents.
[154]
Pig manure350 and 700°CCarbaryl and atrazineThe pesticides were adsorbed by the biochars.
Hydrolyze faster on elevated pH with biochar 700°C.
Carbaryl and atrazine decomposed by 71.8% and 27.9%.
[51]
Pine wood, corn stalks, peanut shells, rice straw, and wheat straw200, 350, 500, and 700°C,p-Nitrophenol, p-aminophenolPNP degraded through the direct contact with EPFRs.
Biochars degrade PNP in soil and natural water.
EPFR-promoted degradation for 5 biochars and PNP.
[155]
Cottonwood600°CMethylene blue and phosphateExcellent adsorption abilities for the contaminants.[156]
Birchwood and Norway spruce wood380°C–430°CGlyphosate, diuronDuron adsorption enhanced by biochar in soils.
Glyphosate adsorption decreased in sandy soil.
Ageing of soil-biochar mixtures decreased adsorption of both
herbicides.
[157]
Lignin and cellulose500°Cp-NitrophenolPNP decay was only modestly suppressed (12–30%).
Lignin char more reactive than cellulose char.
The Fe impurity in lignin played no role.
[158]
Pig manure, rice and wheat straw350 and 700°CCarbarylEnhanced chemical hydrolysis of carbaryl at high temp.
Promoted biodegradation at low temp. high temp reduced biodegradation of carbaryl.
[41]

EPFRs, environmentally persistent free radicals, PNP, p-Nitrophenol.