Spectrophotometric Determination of Palladium(II) Ions Using a New Reagent: 4-(N’-(4-Imino-2-oxo-thiazolidine-5-ylidene)-hydrazino)-benzoic Acid (p-ITYBA)

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d="M368 703H309L44 -163H104L368 703Z"></path></g><g transform="matrix(.013,0,0,-0.013,84.503,-.271)"><path d="M782 731H740L476 -79H474L280 352L133 274L151 239L242 286L473 -219L782 731Z"></path></g><rect height="0.65243" width="6.55046" x="94.472" y="-9.80939"></rect><g transform="matrix(.013,0,0,-0.013,94.472,0)"><path d="M495 86L479 114C446 82 419 66 409 66C401 66 401 72 406 97C420 166 436 231 453 297C489 435 454 448 428 448C406 448 384 439 354 422C305 394 222 327 161 247H159L183 345C200 415 194 448 173 448C143 448 82 410 23 351L38 325C64 349 95 371 105 371C111 371 116 365 109 336L25 -4L31 -12C50 -4 77 3 107 9C119 69 132 122 145 168C197 254 321 381 370 381C387 381 393 374 378 305L329 95C309 17 320 -12 345 -12C372 -12 430 19 495 86Z"></path></g><g transform="matrix(.013,0,0,-0.013,101.022,0)"><path d="M275 270C275 450 212 609 64 710L45 686C145 604 203 442 203 270S147 -63 45 -147L64 -170C213 -68 275 89 275 270Z"></path></g></svg>, %</td><td class="align_center">Sr, %</td></tr><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr><td class="align_left">Spectrophotometry with p-ITYBA</td><td class="align_center">2.18 ± 0.08</td><td class="align_center">1.4</td></tr><tr><td class="align_left">Voltammetry</td><td class="align_center">2.06 ± 0.09</td><td class="align_center">1.8</td></tr><tr class="table-tr"><td colspan="3"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

<div>Results of spectrophotometric determination of palladium(II) in a catalyst using p-ITYBA (Сp-ITYBA = 7.50·10−5 mol·L−1; CNаCl = 0.10 mol·L−1; СUBS = 0.020 mol·L−1; рH = 7.0; λ = 450 nm; l = 1.0 cm; n = 3; P = 0.95).</div>

Journal of Chemistry

tab4

Table 4

Table 4: Spectrophotometric Determination of Palladium(II) Ions Using a New Reagent: 4-(N’-(4-Imino-2-oxo-thiazolidine-5-ylidene)-hydrazino)-benzoic Acid (p-ITYBA)

Table 4 | Spectrophotometric Determination of Palladium(II) Ions Using a New Reagent: 4-(N’-(4-Imino-2-oxo-thiazolidine-5-ylidene)-hydrazino)-benzoic Acid (p-ITYBA) 