Application of Samarium- and Terbium-Sensitized Luminescence via a Multivariate-Based Approach for the Determination of Orbifloxacin

Table 3

Analysis of variance (ANOVA) for FI of ORLX-Sm(III) and ORLX-Tb(III) complexes.

Source	DF	Adj SS	Adj MS	F value	P value
ORLX-Sm(III)
Model	3	10.1646	3.3882	438.19	≤0.001
Linear	3	10.1646	3.3882	438.19	≤0.001
pH	1	9.9439	9.9439	1,286.04	≤0.001
MV	1	0.1523	0.1523	19.70	0.001
Temp	1	0.0684	0.0684	8.84	0.012
Error	12	0.0928	0.0077
Curvature	1	0.0009	0.0009	0.11	0.746
Lack of fit	4	0.0369	0.0092	1.17	0.399
Pure error	7	0.0550	0.0079
Total	15	10.2574
ORLX-Tb(III)
Model	4	45628.1	11407.0	997.69	≤0.001
Linear	4	45628.1	11407.0	997.69	≤0.001
pH	1	45319.2	45319.2	3963.75	≤0.001
CT	1	45.4000	45.4000	3.97	0.072
MV	1	129.800	129.800	11.36	0.006
Temp	1	133.600	133.600	11.69	0.006
Error	11	125.800	11.4000
Curvature	1	25.5000	25.5000	2.54	0.142
Lack of fit	3	23.8000	7.90000	0.73	0.568
Pure error	7	76.5000	10.9000
Total	15	45753.8

DF is degrees of freedom, Adj SS is the adjusted sum of squares, and Adj MS is the adjusted mean of squares.