Five Regioisomers of Dimethyl Dodecahedrane Derivatives: A Hybrid DFT B3LYP Study

Lee, Seol; Cho, YongJae; Lee, Kee Hag

doi:https://doi.org/10.1155/2017/5494038

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Abstract Introduction Calculations Results and Discussion Conclusion Conflicts of Interest Acknowledgments Supplementary Materials References Copyright Related Articles

Research Article | Open Access

Volume 2017 | Article ID 5494038 | https://doi.org/10.1155/2017/5494038

Five Regioisomers of Dimethyl Dodecahedrane Derivatives: A Hybrid DFT B3LYP Study

Seol Lee,¹YongJae Cho,¹and Kee Hag Lee¹

Academic Editor: Arturo Espinosa Ferao

Received22 Feb 2017

Revised03 Jun 2017

Accepted03 Jul 2017

Published20 Sept 2017

Abstract

The hybrid density functional (B3LYP/6-31G(d, p)) method was used to understand why 1,2-dimethyl dodecahedrane has not been reported yet. From the direct dimethyl substitution of the dodecahedrane cage, we could have five C₂₀H₁₈(CH₃)₂ derivatives which were geometrically optimized without constraints. The results suggest that 1,16-dimethyl dodecahedrane derivative is the most stable, whereas the 1,2-dimethyl derivative is the most unstable; this implies that the distortion due to steric hindrance interactions would be a crucial effect on the relative energies of the dimethyl dodecahedranes. It would be disadvantaged thermodynamically for 1,2-dimethyl derivative that, in the experimental results, was not synthesized yet. The LUMO of each of the derivatives was equivalently delocalized over the void within the cage, implying that dimethyl derivatives are able to encapsulate atoms at the center of the cage. The HOMO was limitedly delocalized on the cage. The characteristics of the HOMO of derivatives show three patterns, implying that each derivative might undergo one of three entirely different sets of characteristic chemical reactions with electrophilic reagents.

Dedicated to Professor Roald Hoffmann on the occasion of his 80th birthday

1. Introduction

The geometry of fullerenes obeys the isolated-pentagon rule. However, this rule cannot be satisfied for the smallest fullerene C₂₀, which contains twelve 5-membered rings (MRs) and zero 6-MRs. Therefore, the C₂₀ fullerene would be highly reactive owing to the fusion of strained 5-MRs. Furthermore, this strain could be removed through reactions of C₂₀ that form sp³ bonds. By using density functional theory method, the structures and electronic states of alkyl radicals (R, , –4) added to C₂₀ fullerenes were investigated [1]. Also it was proposed that thiyl radical-promoted polycyclization to form dodecahedrane would be exergonic [2].

Density functional calculations of the reactions CX₃ radical + C₂₀H₂₀ (X = H, F, Cl, and Br) based on two pathways (H-displacement and H-abstraction from C₂₀H₂₀) showed that CH₃ radical prefers H-abstraction from C₂₀H₂₀ while F-displacement is favorable for the reaction of CF₃ radical with the fullerene. Exothermic characters of H-abstraction with the lower potential barrier indicate that the H-abstraction would dominate the reaction + C₂₀H₂₀ while endothermic characters with high potential barrier heights for two reaction pathways of C₂₀H₂₀ with indicate unfavorable thermodynamically and kinetically pathways for these reactions [3].

Using the PBE0/cc-pVDZ quantum chemical method, dipole moments, polarizabilities, the first hyperpolarizabilities for 1,2-diethynyldodecahedrane C₂₀H₁₈(CCH)₂ and diethynylmethanododecahedrane C₂₀H₁₈C(CCH)₂ including two neighboring ethynyl groups in vacuum and in tetrahydrofuran (THF) were reported [4].

A dodecahedrane derivative, namely, the symmetric 1,16-dimethyl derivative, has been synthesized experimentally [5–8]. Since then, the synthesis of methyl-substituted dodecahedrane was also confirmed by X-ray analysis. Moreover, Pólya’s theorem was applied to the enumeration of substituted dodecahedrane isomers [9]. The total synthesis of dodecahedrane was confirmed by the single-peak nature of the ¹H and ¹³C NMR spectra [10], as well as the X-ray spectra [11, 12]. Methyl dodecahedrane, 1,4-dimethyl (), 1,6-dimethyl (), 1,16-dimethyl () dodecahedranes, and trimethyl dodecahedrane have subsequently been reported [13–15]. However, at present no 1,2-dimethyl () and 1,7-dimethyl () dodecahedranes have been reported, yet.

The structures of dodecahedrane and its derivatives were studied at the level of molecular mechanics calculations [16, 17], INDO calculations [18], and hybrid density functional B3LYP calculations [19]. Recently the relative energies, electronic properties, and atomic structures of disubstituted C₂₀H₁₈X₂ regioisomers (X = F, Cl, Br, or OH) at the level of B3LYP/6-31G(d,p) have been determined [20]. Here the predominant electronic configurations of the regioisomers with all substituents X which are higher electron negativity than carbon are not so different, but the HOMO and LUMO maps for five regioisomers are not similar, implying that different exohedral complexes may undergo a distinct set of characteristic chemical reactions.

However, to the best of our knowledge, no the first principle calculations of the full optimization of the five dimethyl dodecahedranes, C₂₀H₁₈(CH₃)₂ derivatives using B3LYP/6-31G(d,p), have been reported. Such calculations would be required in order to understand, in the point of energetics, why only three derivatives have been synthesized. Accordingly, in this study we determine the relative energies, electronic properties, and atomic structures of five derivatives with the same spin state, following the methods of Hwang et al. 2012 [20]. Also it is interesting to see the effect of the methyl substituents on the frontier orbitals, because carbon atoms have the same electronegativity in the substituents and the cage.

2. Calculations

In this study, hybrid density functional theory (DFT) with Becke’s three-parameter hybrid method and the Lee-Yang-Parr exchange-correlation functional theory (B3LYP) [21–28] were used to optimize the geometries of the C₂₀H₂₀ and five dimethyl derivatives C₂₀H₁₈(CH₃)₂, as shown in Figure 1. Furthermore, the electron basis set 6-31G(d,p) was used [25]. We fully optimized the geometries of all the C₂₀H₁₈(CH₃)₂ derivatives using the Gaussian 2003 B.04 and Gaussian 2009 D01 package suites [26, 27]. We obtain highly accurate geometries, by using the convergence criterion with tight optimization and an ultrafine pruned (99,590) grid. Here, we analyzed the relative energies as well as the HOMO and LUMO orbitals of the derivatives [20, 28].

(a)

(b)

To attest the veracity of the B3LYP/6-31G(d,p) relative energy values, as shown in Supplementary Material (see Supplementary Material available online at https://doi.org/10.1155/2017/5494038), we calculated single-point energies at the levels of M06-2X [29], PBE [30], B98 [31], B97D3 [32, 33], B3LYPD3 [21, 22, 33], PBED3 [30, 33], and M06-2XD3 [29, 33] with 6-31G(d,p) basis set on the optimized geometries and using the Zero Point Energy-Correction (ZPEC) already obtained at the B3LYP/6-31G(d) level, using Gaussian 2009 D01 package suites [27]. Here D3 represents the dispersion-corrected functional with the D3 version of Grimme’s dispersion with Becke-Johnson damping [33]. Also using the post-HF MP2 [34]/def2-TZVPP [35]//B3LYP/6-31G(d) level, we computed the energies as single-point calculations with the ZPEC already obtained at the B3LYP/6-31G(d) level.

3. Results and Discussion

By performing calculations for the full optimization of the atomic structures of the five C₂₀H₁₈(CH₃)₂ derivatives using B3LYP/6-31G(d,p) without any constraints, we determined the relative energies of the derivatives in Table 1 with the symmetries as shown in Figure 1.

The geometrical structures and the frontier orbitals (HOMOs and LUMOs) of the five C₂₀H₁₈(CH₃)₂ derivatives are shown in Figure 2. The calculated C-C bond length in the cage of neutral C₂₀H₂₀ with symmetry is 1.556 Å, which is in the range of the experimental result (i.e., Å) [36].

(a)

(b)

Figure 2

The (a) HOMOs and (b) LUMOs of the fully optimized geometries of the five C₂₀H₁₈(CH₃)₂ derivatives using B3LYP/6-31G(d,p) calculations. Here -, -, and -axis represent the frontier orbitals, looking from , , and direction, respectively. The HOMOs of C₂₀H₁₈(CH₃)₂ derivatives (isovalue = 0.05). trans-2 (HOMO: −7.08 eV) and the others (HOMO: −7.05); C₂₀H₂₀ (HOMO: −7.09 eV). The LUMOs of C₂₀H₁₈(CH₃)₂ derivatives (isovalue = 0.05). Five dimethyl derivatives (LUMO: 0.98 eV); C₂₀H₂₀ (LUMO: 0.90 eV).

In the five dimethyl derivatives whose geometries were fully optimized, the relative Zero Point Energy-Correction (ZPEC) energies of dimethyl dodecahedranes are arranged in the following order: 1,16-dimethyl derivative (trans-1, ) ≈ 1,7-dimethyl derivative (equatorial, ) ≈ 1,6-dimethyl derivative (trans-2, ) ≈ 1,4-dimethyl derivative (cis-2, ) < 1,2-dimethyl derivative (cis-1, ). The distance between dimethyl groups in the 1,16-dimethyl derivative with the lowest energy is the longest among these. In 1,2-dimethyl derivative, the two substituents are located on the surface of the C₂₀H₂₀ fullerene within a distance that is shorter than the van der Waals distance (i.e., 3.4 Å).

The increasing order of relative ZPEC energies in them is the same to the decreasing order of the distance between the two methyl groups of derivatives. As shown in Figure 3 and Supplementary Materials, the veracity of the B3LYP/6-31G(d,p) relative energy values is attested at the levels of M06-2X, PBE, B98, B97D3, B3LYPD3, PBED3, and M06-2XD3, and MP2 in the point of view that the relative energy of cis-1 is about 10 kJ/mol higher than the others. The difference of relative energies of four isomers except cis-1 is less than 0.7 kJ/mol in the levels of DFT but within 2 kJ/mol in the MP2 method.

Our result suggests that both the strength of the cage distortion and the van der Waals force between the pair of methyl groups of derivatives are important factors that affect the position of exohedral dimethyl substitution on the dodecahedrane cage. And it could be suggested that in 1,2-dimethyl derivative, steric impedance brought on by the nearby two methyl groups is very crucial. It is interesting to compare the results above with the case of C₂₀H₁₈X₂ (X = F, Cl, Br, OH). In this case, except for the dihydroxy derivative, 1,2-disubstituted derivatives have the highest energy whereas 1,16-derivatives have the lowest energy; however, in the dihydroxy derivatives, the increasing order is reversed [20, 37].

Here our calculations concerning the dimethyl dodecahedrane derivatives could explain the fact why three dimethyl dodecahedrane derivatives were reported in X-ray and NMR experiments [7, 15], but the 1,2-dimethyl dodecahedrane derivative has not been synthesized yet. And it could be suggested that the more stable derivative in the viewpoint of energetics could be synthesized easier than others.

In the following substitution reaction, the thermal reaction energies are endothermic:where 2.48, 2.86, 2.56, 3.78, and 5.79 eV of the thermal reaction energies at 298.15 K and 1 atm are absorbed for 1,16-dimethyl derivative (trans-1, ), 1,7-dimethyl derivative (equatorial, ), 1,6-dimethyl derivative (trans-2, ), 1,4-dimethyl derivative (cis-2, ), and 1,2-dimethyl derivative (cis-1, ), respectively. The Gibbs free energies are 10.285, 10.278, 10.283, 10.280, and 10.294 eV for 1,16-dimethyl derivative (trans-1, ), C 1,6-dimethyl derivative (trans-2, ), 1,7-dimethyl derivative (equatorial, ), 1,4-dimethyl derivative (cis-2, ), and 1,2-dimethyl derivative (cis-1, ), respectively.

Even though the very small variation of Gibbs free energy is not sufficient to decide which structure should be totally experimentally disfavored, it could suggest that, in the point of thermodynamics, a synthesis of cis-1 isomer might be a little difficult compared to the others. In the experimental results, dodecahedrane, methyl, and dimethyl derivatives are synthesized [12], but cis-1 and equatorial isomers are not synthesized yet.

Figure 2 shows the HOMOs and LUMOs for the directed dimethyl derivatives of the dodecahedrane cage. When we calculate the energy gaps from the HOMO/LUMO energy levels of the derivatives, C₂₀H₂₀ and C₂₀H₁₈(CH₃)₂ have slightly different energy gaps. Here the HOMOs of the C₂₀H₁₈(CH₃)₂ derivatives with the same number of symmetry elements are very similar, but the HOMOs of derivatives with the different number of symmetry elements are different, despite the fact that the LUMOs among different geometric structures are identical. This suggests that each derivative undergoes one of three distinct sets of characteristic chemical reactions only for the HOMO. It is interesting to see that they are different to the case of disubstituted C₂₀H₁₈X₂ regioisomers (X = F, Cl, Br, or OH) which have five distinct set of reactions for both the HOMO and the LUMO [20].

Figure 2 shows the effect of the disubstituents on the frontier orbitals of C₂₀H₂₀. The HOMO and LUMO energies of five C₂₀H₁₈(CH₃)₂ derivatives are higher than the HOMO and LUMO levels of C₂₀H₂₀ (HOMO: −7.09 eV; LUMO: 0.90 eV). Also the band gaps of dimethyl substituted derivatives are wider than the gaps of C₂₀H₂₀ and C₂₀ (HOMO: −5.03 eV; LUMO: −3.10 eV). Moreover, the LUMO energies are positive and higher than that of C₂₀H₂₀, which implies that these could function less efficiently as electron acceptors than C₂₀H₂₀.

4. Conclusion

We obtained the fully optimized geometries of the C₂₀H₁₈(CH₃)₂ derivatives (the smallest fullerene disubstituents) without any constraints using the hybrid B3LYP/6-31G(d,p) density functional method. We observed that the relative energy of the C₂₀H₂₀ disubstituted derivatives is mostly dependent on the distance between the pair of two methyl groups. It is interesting to note that the 1,2-dimethyl derivatives is less stable than the 1,16-dimethyl derivative. This implies that, in the C₂₀H₁₈(CH₃)₂ derivatives, the effect of distortion due to the steric hindrance interactions on the relative energy would be crucial. Therefore, our calculations in the point of thermodynamic view could support the experimental results, wherein three dimethyl dodecahedrane derivatives except the 1,2-dimethyl dodecahedrane derivative were preparative-synthetic and suggest that 1,7-dimethyl derivative (equatorial, ) would be synthesized in the near future.

Conflicts of Interest

The authors declare that there are no conflicts of interest regarding the publication of this paper.

Acknowledgments

This study was supported by Wonkwang University in 2015.

Supplementary Materials

Figures S1-S5: The distance between the two methyl groups of Five C₂₀H₁₈Me₂ isomers.

Table S1: Relative energies (kJ/mol) of five regioisomers. All calculations were performed using the optimized B3LYP/6-31G(d,p) geometries.

Table S2: Relative energies, zero point-corrected energies(ZPCE), enthalpies, and Gibbs free energies of five regioisomers. All calculations were performed using the optimized B3LYP/6-31G(d,p) geometries (unit: kJ/mol).

Table S3: Relative Energies(kJ/mol) with Zero Point Energy-corrected to the optimized B3LYP/6-31G(d,p) geometries.

Supplementary Material

References

S. Abe, S. Kawano, Y. Toida et al., “Electronic states of alkyl-radical-functionalized C20 fullerene using density functional theory,” Japanese Journal of Applied Physics, vol. 55, no. 3, Article ID 03DD03, 2016.
View at: Publisher Site | Google Scholar
S. C. Wang and D. J. Tantillo, “Viability of dodecahedrane-forming radical polycyclizations,” Organic & Biomolecular Chemistry, vol. 15, no. 9, pp. 1976–1979, 2017.
View at: Publisher Site | Google Scholar
R. Ghafouri and F. Ektefa, “Theoretical study on the mechanism of reactions of CX3 radicals (X = H, F, Cl and Br) with C20H20 and C20F20 fullerenes,” Journal of Molecular Structure, vol. 1127, pp. 296–302, 2017.
View at: Publisher Site | Google Scholar
S. G. Semenov and M. V. Makarova, “A quantum chemical study of diethynyl derivatives of dodecahedrane and buckminsterfullerene in vacuum and in tetrahydrofuran,” Optics and Spectroscopy, vol. 118, no. 1, pp. 46–49, 2015.
View at: Publisher Site | Google Scholar
L. A. Paquette, D. W. Balogh, R. Usha, D. Kountz, and G. G. Christoph, “Crystal and molecular structure of a pentagonal dodecahedrane,” Science, vol. 211, no. 4482, pp. 575-576, 1981.
View at: Publisher Site | Google Scholar
L. A. Paquette and D. W. Balogh, “An expedient synthesis of 1,16-dimethyldodecahedrane,” Journal of the American Chemical Society, vol. 104, no. 3, pp. 774–783, 1982.
View at: Publisher Site | Google Scholar
G. G. Christoph, P. Engel, R. Usha, D. W. Balogh, and L. A. Paquette, “Comparative X-ray crystal structure analysis of C2v-dimethylmonosecododecahedrane and D3d-dimethyldodecahedrane. The remarkable consequences of a missing framework bond on molecular topology,” Journal of the American Chemical Society, vol. 104, no. 3, pp. 784–791, 1982.
View at: Publisher Site | Google Scholar
L. A. Paquette, “Dodecahedrane—The chemical transliteration of Plato's universe (A Review),” Proceedings of the National Academy of Sciences of the United States of America, vol. 79, no. 14, pp. 4495–4500, 1982.
View at: Publisher Site | Google Scholar
L. A. Paquette, R. J. Ternansky, D. W. Balogh, and W. J. Taylor, “Total synthesis of a monosubstituted dodecahedrane. The methyl derivative,” Journal of the American Chemical Society, vol. 105, no. 16, pp. 5441–5446, 1983.
View at: Publisher Site | Google Scholar
L. A. Paquette, R. J. Ternansky, D. W. Balogh, and G. Kentgen, “Total synthesis of dodecahedrane,” Journal of the American Chemical Society, vol. 105, no. 16, pp. 5446–5450, 1983.
View at: Publisher Site | Google Scholar
H. Prinzbach and W.-D. Fessener, Organic Synthesis, Blackwell, Oxford, UK, 1987.
M. Bertau, F. Wahl, A. Weiler et al., “From pagodanes to dodecahedranes - Search for a serviceable access to the parent (C20H20) hydrocarbon,” Tetrahedron, vol. 53, no. 29, pp. 10029–10040, 1997.
View at: Publisher Site | Google Scholar
L. A. Paquette, Y. Miyahara, and C. W. Doecke, “Preparatively useful dehydrogenative method for dodecahedrane synthesis,” Journal of the American Chemical Society, vol. 108, no. 7, pp. 1716–1718, 1986.
View at: Publisher Site | Google Scholar
I. Santas, D. W. Balogh, C. W. Doecke, A. G. Marshall, and L. A. Paquette, “Gas-phase basicities of cubane, dodecahedrane, and methyl-and 1,16-dimethyldodecahedrane as measured by Fourier transform ion cyclotron resonance mass spectrometry,” Journal of the American Chemical Society, vol. 108, no. 26, pp. 8183–8185, 1986.
View at: Publisher Site | Google Scholar
L. A. Paquette and Y. Miyahara, “Directed alkyl substitution of the dodecahedrane nucleus. The 1,4-dimethyl, 1,6-dimethyl, and 1,4,16-trimethyl derivatives. Indanododecahedrane by stepwise dehydrogenation of a benzylated seco derivative,” The Journal of Organic Chemistry, vol. 52, no. 7, pp. 1265–1272, 1987.
View at: Publisher Site | Google Scholar
N. L. Allinger, H. J. Geise, W. Pyckhout, L. A. Paquette, and J. C. Gallucci, “Structures of norbornane and dodecahedrane by molecular mechanics calculations (MM3), X-ray crystallography, and electron diffraction,” Journal of the American Chemical Society, vol. 111, no. 3, pp. 1106–1114, 1989.
View at: Publisher Site | Google Scholar
F. Wahl, J. Wörth, and H. Prinzbach, “The Pagodane Route to Dodecahedranes: An Improved Approach to the C₂₀H₂₀ Parent Framework; Partial and Total Functionalizations—Does C₂₀-Fullerene Exist?” Angewandte Chemie International Edition, vol. 32, no. 12, pp. 1722–1726, 1993.
View at: Publisher Site | Google Scholar
J. M. Schulman and R. L. Disch, “Theoretical studies of dodecahedrane. 2. Dodecahedrane, inclusion compounds, and fluorine derivatives,” Journal of the American Chemical Society, vol. 100, no. 18, pp. 5677–5681, 1978.
View at: Publisher Site | Google Scholar
D. Moran, F. Stahl, E. D. Jemmis, H. F. Schaefer III, and P. V. R. Schleyer, “Structures, stabilities, and ionization potentials of dodecahedrane endohedral complexes,” Journal of Physical Chemistry A, vol. 106, no. 20, pp. 5144–5154, 2002.
View at: Publisher Site | Google Scholar
Y. G. Hwang, S. Lee, and K. H. Lee, “DFT Study for Substitution Patterns of C₂₀H₁₈X₂ Regioisomers (X = F, Cl, Br, or OH),” Bulletin of the Korean Chemical Society, vol. 33, no. 2, pp. 641–646, 2012.
View at: Publisher Site | Google Scholar
A. D. Becke, “Density-functional thermochemistry. III. The role of exact exchange,” The Journal of Chemical Physics, vol. 98, no. 7, p. 5648, 1993.
View at: Publisher Site | Google Scholar
C. Lee, W. Yang, and R. G. Parr, “Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density,” Physical Review B, vol. 37, no. 2, pp. 785–789, 1988.
View at: Publisher Site | Google Scholar
P. J. Stephen, F. J. Devlin, C. F. Chablowski, and M. J. Frisch, “Ab Initio Calculation of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields,” The Journal of Physical Chemistry, vol. 98, no. 45, pp. 11623–11627, 1994.
View at: Publisher Site | Google Scholar
R. H. Herteing and W. Koch, “On the parameterization of the local correlation functional. What is Becke-3-LYP?” Chemical Physics Letters, vol. 268, no. 5-6, pp. 345–351, 1997.
View at: Publisher Site | Google Scholar
W. J. Hehre, K. Ditchfield, and J. A. Pople, “Self-consistent molecular orbital methods. XII. Further extensions of gaussian-type basis sets for use in molecular orbital studies of organic molecules,” The Journal of Chemical Physics, vol. 56, no. 5, pp. 2257–2261, 1972.
View at: Publisher Site | Google Scholar
M. J. Frisch, G. W. Trucks, H. B. Schlegel et al., A Gaussian 03, B.04, Gaussian, Inc., Pittsburgh, Pa, USA, 2003.
M. J. Frisch, G. W. Trucks, H. B. Schlegel et al., Gaussian 09W, Rev: D01, Gaussian, Inc., Pittsburgh, Pa, USA, 2009.
T. Clark and R. Koch, The Chemist’s Electronic Book of Orbitals, Springer Berlin Heidelberg, Berlin, Germany, 1999.
View at: Publisher Site
Y. Zhao and D. G. Truhlar, “The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals,” Theoretical Chemistry Accounts, vol. 120, no. 1, pp. 215–241, 2008.
View at: Publisher Site | Google Scholar
J. P. Perdew, K. Burke, and M. Ernzerhof, “Generalized gradient approximation made simple [Phys. Rev. Lett. 77, 3865 (1996)],” Physical Review Letters, vol. 78, no. 7, p. 1396, 1997.
View at: Publisher Site | Google Scholar
H. L. Schmider and A. D. Becke, “Optimized density functionals from the extended G2 test set,” The Journal of Chemical Physics, vol. 108, no. 23, p. 9624, 1998.
View at: Publisher Site | Google Scholar
A. D. Beck, “Density-functional thermochemistry. V. Systematic optimization of exchange-correlation functionals,” The Journal of Chemical Physics, vol. 107, no. 20, p. 8554, 1997.
View at: Publisher Site | Google Scholar
S. Grimme, S. Ehrlich, and L. Goerigk, “Effect of the damping function in dispersion corrected density functional theory,” Journal of Computational Chemistry, vol. 32, no. 7, pp. 1456–1465, 2011.
View at: Publisher Site | Google Scholar
M. Head-Gordon, J. A. Pople, and M. J. Frisch, “MP2 energy evaluation by direct methods,” Chemical Physics Letters, vol. 153, no. 6, pp. 503–506, 1988.
View at: Publisher Site | Google Scholar
F. Weigend and R. Ahlrichs, “Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: design and assessment of accuracy,” Physical Chemistry Chemical Physics, vol. 7, no. 18, pp. 3297–3305, 2005.
View at: Publisher Site | Google Scholar
B. S. Hudson, D. G. Allis, S. F. Parker, A. J. Ramirez-Cuesta, H. Herman, and H. Prinzbach, “Infrared, Raman, and inelastic neutron scattering spectra of dodecahedrane: An I h molecule in T h site symmetry,” Journal of Physical Chemistry A, vol. 109, no. 15, pp. 3418–3424, 2005.
View at: Publisher Site | Google Scholar
F. Wahl, A. Weiler, P. Landenberger et al., “Towards perfunctionalized dodecahedranes-en route to C20 fullerene,” Chemistry - A European Journal, vol. 12, no. 24, pp. 6255–6267, 2006.
View at: Publisher Site | Google Scholar

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