Synthesis, Crystal Structure, and Characterization of a New Organic-Inorganic Hybrid Material: (H₃AEP)₂⋅(BiCl₆)⋅3Cl⋅2H₂O

Table 3

Hydrogen bonds for (H₃AEP)₂·(BiCl₆)·3Cl·2H₂O (Å, °).

D–H⋯A	D–H	H⋯A	D⋯A	D–H⋯A
N1–H1A⋯Cl8^i	0.90	2.25	3.107 (8)	158
N1–H1B⋯O2	0.90	1.88	2.732 (10)	156
N2–H2⋯Cl7	0.91	2.32	3.119 (6)	147
N3–H3A⋯Cl5^ii	0.89	2.37	3.243 (7)	168
N3–H3B⋯Cl4^iii	0.89	2.68	3.487 (8)	150
N3–H3C⋯Cl9	0.89	2.70	3.467 (8)	145
N4–H4A⋯O1	0.90	1.90	2.761 (10)	170
N4–H4A⋯Cl8	0.90	2.49	3.190 (7)	134
N4–H4B⋯Cl2	0.90	2.78	3.341 (6)	122
N4–H4A⋯Cl3^iv	0.90	2.81	3.291 (6)	115
N5–H5⋯Cl7	0.91	2.54	3.499 (10)	147
N5–H5⋯Cl9	0.91	2.85	3.452 (7)	129
N6–H6A⋯Cl3^v	0.89	2.45	3.286 (6)	158
N6–H6B⋯Cl4^vi	0.89	2.67	3.345 (7)	133
N6–H6C⋯Cl3^vi	0.89	2.49	3.311 (5)	153
O2–HW1⋯Cl8^vii	0.78	2.61	3.211 (7)	135
O2–HW1⋯Cl5^i	0.78	2.82	3.732 (10)	133
O2–HW2⋯Cl2^vii	0.85	2.64	3.494 (8)	176
O1–HW3⋯Cl1^iv	0.85	2.47	3.261 (6)	153
O1–HW3⋯Cl3^iv	0.85	2.98	3.439 (5)	116
O1–HW4⋯Cl9^viii	0.86	2.17	3.036 (8)	171

i: −𝑥+3/2, 𝑦−1/2, 𝑧; ii: −𝑥+1, −𝑦+1, −𝑧+1; iii: 𝑥+1, 𝑦, 𝑧; iv: 𝑥+1/2, 𝑦, −𝑧+3/2; v: −𝑥+1, 𝑦−1/2, −𝑧+3/2; vi: −𝑥+1/2, 𝑦−1/2, 𝑧; vii: 𝑥+1/2, −𝑦+1/2, −𝑧+1; viii: 𝑥−1/2, 𝑦, −𝑧+3/2.