Synthesis, Crystal Structure, and Electrical Properties of a New Molybdylarsenate LiNa₅K₃Mo₁₁As₃O₄₅

Table 2

Main bond distances.

Bond distances (Å)
As1–O30	1.669 (4)	Mo10–O9	2.313(4)
As1–O25	1.677 (4)	Mo10–O14	2.360(4)
As1–O9	1.691 (4)	Mo11–O39	1.707(4)
As1–O10	1.696 (4)	Mo11–O45^iii	1.714(5)
As2–O15^iii	1.663 (4)	Mo11–O21	1.835(4)
As2–O24	1.679 (4)	Mo11–O35	1.915(4)
As2–O13	1.690 (4)	Mo11–O37	2.285(4)
As2–O37	1.695 (4)	K1–O41	2.751(4)
As3–O23	1.675 (4)	K1–O38^vi	2.759(4)
As3–O20	1.677 (4)	K1–O12^i	2.802(4)
As3–O14	1.698 (4)	K1–O17^vii	2.823(4)
As3–O4	1.699 (4)	K1–O43^viii	2.906(4)
Mo1–O28	1.701 (4)	K1–O15	2.912(4)
Mo1–O26	1.731 (4)	K1–O17^i	2.958(5)
Mo1–O6	1.826 (4)	K1–O5	3.115(4)
Mo1–O19	1.923 (4)	K2–O7	2.755(4)
Mo1–O10	2.273 (4)	K2–O28^v	2.770(4)
Mo2–O22	1.706 (4)	K2–O34^v	2.803(4)
Mo2–O41	1.735 (4)	K2–O32^x	2.852(4)
Mo2–O5	1.869 (4)	K2–O45	2.867(5)
Mo2–O18^i	1.972 (4)	K2–O1	2.932(5)
Mo2–O30	2.217 (4)	K2–O31^i	2.979(5)
Mo2–O14	2.285 (4)	K2–O20	3.019(4)
Mo3–O16^ii	1.685 (4)	K3–O29	2.615(4)
Mo3–O32	1.724 (4)	K3–O2^vii	2.713(4)
Mo3–O29	1.943 (4)	K3–O33	2.726(4)
Mo3–O19	1.972 (4)	K3–O22^vii	2.932(5)
Mo3–O24	2.239 (4)	K3–O36^ii	2.964(4)
Mo3–O10	2.266 (4)	K3–O30	3.063(4)
Mo4–O11	1.700 (4)	Na1–O4	2.409(4)
Mo4–O40	1.731 (4)	Na1–O32	2.444(5)
Mo4–O8	1.916 (4)	Na1–O11^i	2.522(5)
Mo4–O3^iii	1.924 (4)	Na1–O26	2.530(5)
Mo4–O4^iii	2.263 (4)	Na1–O33	2.608(5)
Mo4–O13	2.317 (4)	Na1–O10	2.719(5)
Mo5–O38^ii	1.705 (4)	Na1–O23	2.861(5)
Mo5–O33	1.714 (4)	Na1–O30	2.995(5)
Mo5–O5	1.918 (4)	Na2–O43	2.400(6)
Mo5–O8^i	1.943 (4)	Na2–O18^i	2.468(5)
Mo5–O15	2.205 (4)	Na2–O41^viii	2.521(5)
Mo5–O4	2.308 (4)	Na2–O22	2.642(5)
Mo6–O1	1.702 (5)	Na2–O44^viii	2.710(6)
Mo6–O27	1.710 (4)	Na2–O2	2.812(6)
Mo6–O7	1.936 (4)	Na2–O25	2.882(5)
Mo6–O6	1.963 (4)	Na3–O40^xi	2.483(4)
Mo6–O9	2.220 (4)	Na3–O1	2.527(6)
Mo6–O23	2.237 (4)	Na3–O39^v	2.628(5)
Mo7–O17	1.697 (4)	Na3–O3	2.737(4)
Mo7–O2	1.710 (4)	Na3–O27^v	2.749 (5)
Mo7–O29	1.922 (4)	Na3–O31^i	2.786(5)
Mo7–O12	1.964 (4)	Na3–O23	2.845(4)
Mo7–O24	2.252 (4)	Na4–O14	2.313(5)
Mo7–O25	2.280 (4)	Na4–O36	2.401(6)
Mo8–O43	1.712 (4)	Na4–O44	2.412(6)
Mo8–O44^iii	1.712 (4)	Na4–O45	2.416(6)
Mo8–O12	1.889 (4)	Na4–O37^i	2.436(5)
Mo8–O35	1.933 (4)	Na4–O20	2.671(5)
Mo8–O37	2.301 (4)	Na4–O41	2.910(6)
Mo8–O25	2.450 (4)	Na5–O16	2.373(5)
Mo9–O31	1.702 (4)	Na5–O8^x	2.401(4)
Mo9–O34	1.721 (4)	Na5–O27	2.439(6)
Mo9–O3^iii	1.929 (4)	Na5–O42	2.468(5)
Mo9–O21	1.949 (4)	Na5–O35	2.474(5)
Mo9–O20^iii	2.224 (4)	Na5–O39	2.734(5)
Mo9–O13	2.227 (4)	Li–O19	2.037(12)
Mo10–O42	1.710 (4)	Li–O40	2.041(12)
Mo10–O36	1.725 (4)	Li–O34	2.053(13)
Mo10–O18^i	1.894 (4)	Li–O26^xi	2.075(12)
Mo10–O7	1.927 (4)

Symmetry codes:(i) x, y−1, z; (ii) x−1, y, z;(iii)x, y+1, z;(iv)x−1, y−1, z; (v) −x+1, −y+1, −z; (vi) −x+1, −y, −z+1; (vii) −x, −y+1, −z+1; (viii) −x+1, −y+1, −z+1; (ix) −x, −y, −z+1; (x) x+1, y, z; (xi) −x, −y+1, −z; (xii) x+1, y+1, z.