Research Article
Synthesis and Structural Study of the Bis(ethylenediamine)CdFe(CO)4 Monomer
Table 2
Selected bond lengths (Å) and angles (°) for (en)2CdFe(CO)4.
| | Bond distances | | | | | Fe1-C1 | 1.7558(17) | C1-O1 | 1.162(2) | | Fe1-C2 | 1.7642(16) | C2-O2 | 1.174(2) | | Fe1-C3 | 1.7584(17) | C3-O3 | 1.177(2) | | Fe1-C4 | 1.7586(17) | C4-O4 | 1.162(2) | | Cd1-N1 | 2.3976(14) | Cd1-N3 | 2.3819(15) | | Cd1-N2 | 2.3957(14) | Cd1-N4 | 2.4163(14) | | Cd1-Fe1 | 2.6250(2) | | | | Bond angles | | | | | C1-Fe1-C2 | 104.05(7) | N1-Cd1-N2 | 73.50(5) | | C1-Fe1-C3 | 103.08(7) | N1-Cd1-N3 | 125.80(6) | | C1-Fe1-C4 | 97.40(8) | N1-Cd1-N4 | 83.47(5) | | C2-Fe1-C3 | 116.88(8) | N2-Cd1-N3 | 87.46(5) | | C2-Fe1-C4 | 115.88(8) | N2-Cd1-N4 | 132.82(6) | | C3-Fe1-C4 | 115.53(8) | N3-Cd1-N4 | 73.39(5) | | Cd1-Fe1-C1 | 174.29(6) | Fe1-Cd1-N1 | 120.81(4) | | Cd1-Fe1-C2 | 79.06(5) | Fe1-Cd1-N2 | 113.20(4) | | Cd1-Fe1-C3 | 79.39(5) | Fe1-Cd1-N3 | 113.37(4) | | Cd1-Fe1-C4 | 76.90(6) | Fe1-Cd1-N4 | 113.97(4) | | Fe1-C1-O1 | 178.75(16) | Fe1-C3-O3 | 177.92(14) | | Fe1-C2-O2 | 178.08(15) | Fe1-C4-O4 | 176.35(16) |
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