Table of Contents
Journal of Crystallography
Volume 2014, Article ID 271517, 4 pages
http://dx.doi.org/10.1155/2014/271517
Research Article

Crystal and Molecular Structure of 1,1-Bis(methylthio)-5-(4-chlorophenyl)-1,4-pentadien-3-one

1Department of Physics, Christ University, Bangalore, Karnataka 560 029, India
2Department of Chemistry, Sree Narayana College, Cherthala, Kerala 688 524, India

Received 5 November 2013; Accepted 26 February 2014; Published 26 March 2014

Academic Editor: Hasan Küçükbay

Copyright © 2014 Bubbly S. Gudennavar et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The 1,1-bis(methylthio)-5-(4-chlorophenyl)-1,4-pentadien-3-one compound crystallizes in the space group C2/c with unit cell parameters  Å,  Å,  Å, and . The structure was solved by direct methods and refined to an R-factor of 0.0593. Due to the steric interaction between the two methyl groups, one of the methylthio groups is in cis conformation with C11–C10 double bond and the other is in trans conformation. The cinnamoyl group on the carbonyl carbon atom effects more delocalization of the electrons within the molecule so that the structure is highly conjugated and planar.