Research Article
Crystallization and Structural Characterization of Dimeric and Trimeric Forms of (Neocuproine)CdFe(CO)4
Table 2
Selected bond lengths (
) and angles (°) for [(neocuproine)CdFe(CO)
4]
2.
| | Bond distances | | Cd1–Fe1 | 2.6532(3) | Cd1–Fe1′ | 2.8125(3) | | Cd1–N1 | 2.3635(17) | Cd1–N2 | 2.3621(17) | | Fe1–C1 | 1.780(2) | C1–O1 | 1.154(3) | | Fe1–C2 | 1.770(2) | C2–O2 | 1.146(3) | | Fe1–C3 | 1.775(2) | C3–O3 | 1.163(3) | | Fe1–C4 | 1.772(2) | C4–O4 | 1.165(3) |
| | Bond angles | | Fe1–Cd1–Fe1′ | 111.243(9) | Cd1–Fe2–Cd1′ | 68.642(9) | | C1–Fe1–C2 | 101.75(11) | Fe1–C1–O1 | 176.3(2) | | C1–Fe1–C3 | 103.96(10) | Fe1–C2–O2 | 178.2(2) | | C1–Fe1–C4 | 105.24(10) | Fe1–C3–O3 | 173.5(2) | | C2–Fe1–C3 | 95.81(9) | Fe1–C4–O4 | 172.4(2) | | C2–Fe1–C4 | 93.83(9) | Cd1–Fe1–C1 | 81.01(7) | | C3–Fe1–C4 | 146.59(10) | Cd1′–Fe1–C2 | 108.65(8) | | N1–Cd1–N2 | 71.36(6) | | |
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