Crystal Structures of Two Macrocyclic Bischalcones Possessing 26-Membered Rings

Table 3

Intermolecular hydrogen bonds, intramolecular C–H⋯O, and C–H⋯π supramolecular interactions in 1 and 2.

	D–H⋯A	Symmetry	D–H; (Å)	H⋯A; (Å)	D⋯A; (Å)	D–H⋯A; (Å)
Compound 1	C8–H8B⋯O2		0.9700	2.5400	3.469(3)	162
	C14–H14⋯O6		0.9300	2.6000	3.411(2)	146
	C16–H16⋯O2	—	0.931(15)	2.295(15)	2.717(2)	107
	C29–H29B⋯O6		0.9700	2.4500	3.382(2)	161
	C37–H37⋯O5	—	0.970(17)	2.243(17)	2.726(2)	109
	C38–H38⋯O1	—	1.01(2)	2.323(19)	2.717(3)	101
	C7–H7B⋯phenyl ring		0.9700	2.8500	3.708(2)	148
Compound 2	C8–H8B⋯O2	—	0.9700	2.4800	2.852(11)	103
	C9–H9B⋯O1	—	0.9700	2.4100	2.809(10)	104
	C21–H21⋯O3		0.9300	2.5100	3.407(13)	161
	C34–H34⋯O6		0.9300	2.4700	3.371(13)	164
	C14–H14⋯phenyl ring		0.9300	2.8200	3.735	167