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Mohammad Ahmadian, Sohyla Reshadat, Nader Yousefi, Seyed Hamed Mirhossieni, Mohammad Reza Zare, Seyed Ramin Ghasemi, Nader Rajabi Gilan, Razieh Khamutian, Ali Fatehizadeh, "Municipal Leachate Treatment by Fenton Process: Effect of Some Variable and Kinetics", Journal of Environmental and Public Health, vol. 2013, Article ID 169682, 6 pages, 2013. https://doi.org/10.1155/2013/169682
Municipal Leachate Treatment by Fenton Process: Effect of Some Variable and Kinetics
Due to complex composition of leachate, the comprehensive leachate treatment methods have been not demonstrated. Moreover, the improper management of leachate can lead to many environmental problems. The aim of this study was application of Fenton process for decreasing the major pollutants of landfill leachate on Kermanshah city. The leachate was collected from Kermanshah landfill site and treated by Fenton process. The effect of various parameters including solution pH, Fe2+ and H2O2 dosage, Fe2+/H2O2 molar ratio, and reaction time was investigated. The result showed that with increasing Fe2+ and H2O2 dosage, Fe2+/H2O2 molar ratio, and reaction time, the COD, TOC, TSS, and color removal increased. The maximum COD, TOC, TSS, and color removal were obtained at low pH (pH: 3). The kinetic data were analyzed in term of zero-order, first-order, and second-order expressions. First-order kinetic model described the removal of COD, TOC, TSS, and color from leachate better than two other kinetic models. In spite of extremely difficulty of leachate treatment, the previous results seem rather encouraging on the application of Fenton’s oxidation.
In the past decades, industrial growth and technology development lead to the increasing solid waste production . According to the World Health Organization studies, in the many countries such as France, Canada, America, Norway, England, Spain, and Italy, sanitary landfilling had been recognized as the common, economic and acceptable method for solid waste disposal [2–4]. Landfill leachate is a complex waste matter, which usually causes adverse effects in the environment [5, 6]. The leachate characteristics are depended on the type of solid waste, soil properties, rainfall patterns, and age of landfill site. The concentration of nonbiodegradable and resistant materials with high molecular weight such as humic and fulvic acid arises with increase of the landfill site age .
Due to variable characteristic of landfill leachate, the coherent method for leachate treatment was not developed . The concerning of solid waste leachate may be related to presence of heavy metals and nonbiodegradable organic materials in solid waste leachate and its adverse effects on human and the environment . Application of biological treatment processes (as dominant treatment) cannot remove nonbiodegradable organic materials and additional treatments are required for leachate treatment . Biological treatment processes are suitable for fresh leachate with high ratio of BOD5/COD but cannot be applied in the treatment of aged leachate in which biological treatment occurred, and ratio of BOD5/COD is low .
Chemical treatment methods based on production of hydroxyl radical (OH•) are known as advanced oxidation processes (AOPs) [11, 12]. Oxidation of organic compounds by Fenton solution called the Fenton reaction which is one of the advanced oxidation processes . Fenton reaction is able to destroyed large number of organic compounds without producing toxic byproducts. Another main advantage of Fenton process is that the oxidation and flocculation occur simultaneously that result in removing more organic matters .
Fenton process is done according to the following mechanism :(1)Fe2+ + H2O2 → Fe3+ + •OH + OH−,(2)Fe2+ + H2O2 → Fe2+ + + H+,(3)•OH + H2O2 → + H2O,(4)•OH + Fe2+ → OH− + Fe3+,(5)Fe3+ + → Fe2+ + O2H+,(6)Fe2+ + + H+ → Fe3+ + H2O2,(7)→ H2O2 + O2.
Oxidation potential of hydroxyl radical (OH•) is greater than ozone, one of the strongest oxidizing materials . Hydrogen peroxide alone is not a strong factor in oxygen transfer, and oxidation of organic materials is better performed in the presence of Fe2+ ions . The most important role of Fenton process is removing refractory and toxic organic compounds and increasing the degradability of resistant organic compounds. Fenton processes have been successfully used for treatment of the slaughterhouse, food, olive oil wastewater, and 2,4,6-trichlorophenol from industrial wastewater and landfill leachate [15, 17–22]. This method compared to other advanced oxidation processes is relatively less expensive and requires less time .
The aim of this study was to investigate the effect of Fenton process for solid waste leachate treatment from Kermanshah landfill (Iran).
2.1. Leachate Characteristics
The Leachate sample was collected from the municipal solid waste landfill in Kermanshah city (Iran). The main characteristics of leachate were summarized in Table 1.
All chemicals were of analytical grade (Merck, Germany), and doubly distilled water was used throughout this study. The hydrogen peroxide (35% w/w) and ferrous sulphate (FeSO4·7H2O) were used for all experiment. The FeSO4 solution was prepared daily. H2SO4 and NaOH (1 N) were used for pH adjustment.
2.3. Experimental Procedure
In this study, the effect of Fenton process of leachate treatment was conducted in environment temperature in glass reactor using jar apparatus as a batch reactor. At first, rapid mix (120 rpm) was applied for 30 s, and then mixers were adjusted for 80 rpm for long time. The effect of various parameters including solution pH, Fe2+ and H2O2 concentrations, Fe2+/H2O2 molar ratio, and reaction time was investigated. All experiments were carried out with 1 L beakers, and the beakers were charged with 500 mL leachate .
2.4. Analytical Methods
The amounts of pH, COD, TOC, TSS, color, and alkalinity were analyzed in the laboratory by following the standard methods . The pH, TOC, color, and alkalinity measurements were performed by using the WTW Multiparameter 340i, Shimadzu model TOC-CSH, spectrophotometer, and titration method, respectively. Closed reflux colorimetric method was used for COD analysis. For COD measurement of the supernatant, supernatant was put in the water bath at 50°C for 30 min for removal of remaining H2O2 in Fenton process experiments . The removal efficiency was calculated by the following equations:
3.1. Effect of Solution pH
The Fenton process efficiency for COD, TOC, TSS, and color removal as a function of solution pH was investigated (Figure 1). According to Figure 1, at low pH, the COD, TOC, TSS, and color removal efficiency are low, and with increasing pH up to 3, removal efficiency increased. After this point, COD, TOC, TSS, and color removal were decreased.
The solution pH plays an important role in Fenton process. Figure 1 is evident that with increasing the initial pH from 1 to 3, the removal efficiency quickly increases and at decreases. The results from this experiment are in line with those studies reported by the researchers [6, 23, 26, 27]. They found that pH near 3 is usually optimum for Fenton oxidation. The low efficiency of Fenton process at is due to the formation of [Fe(II)(H2O)6]2+ complex, which reacts more slowly with H2O2 than [Fe(II)(OH)(H2O)5]+ and therefore produces lower OH radical . Also, if the solution pH is too high, the iron precipitates as Fe(OH)3 and H2O2 decompose to oxygen and that will reduce its concentration in the solution [29, 30].
3.2. Effect of Reaction Time
The effect of reaction time on COD, TOC, TSS, and color removal during Fenton process is presented in Figure 2. The result showed that with rising reaction time, the COD, TOC, TSS, and color removal increased. The equilibrium time for COD, TOC, TSS, and color removal was obtained, 105 min. After the equilibrium time, the COD, TOC, TSS, and color removal did not change significantly.
Reaction time is an important factor in Fenton process. Different reaction time was reported in various studies. The reaction time for Fenton process in various studies has been fluctuated between 30 min and 3 h [6, 23, 27]. In some studies, based on electro-Fenton process, optimum reaction time has been reported less than 30 min .
3.3. Effect of Fe2+ Concentration
Figure 3 shows the effect of Fe2+ concentration on the COD, TOC, TSS, and color removal during Fenton process. It can be seen that the Fenton efficiency of COD, TOC, TSS, and color removal increases with augmenting Fe2+ concentration. The optimum Fe2+ concentration for maximum COD, TOC, TSS, and color removal was 1.6 g/L. Further increase of Fe2+ concentration results in decrease in COD, TOC, TSS, and color removal efficiency.
Based on operational costs and organic material removal efficiency, dosage of Fenton reagents will be determined. Generally, removal of organic matters improves with increasing concentration of iron salt. However, the removal increment may be marginal when the concentration of iron salt is high. Many studies have revealed that the use of a much higher concentration of Fe2+ could lead to the self-inhibition of OH radical by Fe2+ ions and decreasing the degradation rate of pollutants: •OH + Fe2+→ Fe3+ + OH− .
3.4. Effect of H2O2 Dose
The influence of H2O2 dose on COD, TOC, TSS, and color removal is shown in Figure 4. The results showed that removal efficiency of COD, TOC, TSS, and color gradually increases as the H2O2 concentration is fluctuated from 500 mg/L to 3000 mg/L and then slowly decreased. It was observed that maximum COD, TOC, TSS, and color removal were obtained at H2O2 concentration of 3000 mg/L.
Landfill leachate is composed of a complex mixture of organic matter. During the oxidation process, more decomposition of organic matter causes more pollutant removal. This continues until formation of the end byproducts of oxidation reactions that mainly are short chain organic acids and are difficult to be further oxidized . The presence of H2O2 in a high quantity can act as a scavenger for the OH radicals, thus reducing the kinetic rate of Fenton process . In addition, due to decomposition of H2O2 and producing hydrogen gas, application of H2O2 more than the optimum value are caused flotation of generated iron sludge. Also, additional H2O2 causes problems in downstream processes and will prevent wastewater biological treatment [3, 32].
3.5. Effect of Fe2+/H2O2 Molar Ratio
The effect of Fe2+/H2O2 molar ratio on the COD, TOC, TSS, and color removal with different Fe2+/H2O2 molar ratios within a range of 1 to 2 is presented in Figure 5. It can be seen that COD, TOC, TSS, and color removal increase with the rise in Fe2+/H2O2 molar ratio up to 1.88 and after this ratio decrease.
In Fenton process, iron and hydrogen peroxide are two major chemicals that determining operation costs as well as efficiency. Determination of the favorable amount of Fenton’s reagent is highly important. The results showed that removal efficiencies increased with the increase of H2O2/Fe2+ molar ratio, and further increase in H2O2/Fe2+ molar ratio produced less efficient improvement in removals. This fact is due to Fenton’s reaction mechanisms proposed by other researchers . If H2O2/Fe2+ molar ratio is low, the reaction rate follows second pseudoorder up to the stoichiometry ratio of 2Fe(II) H2O2. But, when the H2O2/Fe2+ molar ratio increases, the reaction kinetics approache toward zero order. However, at high H2O2/Fe2+ molar ratios, the mechanism changed, and the reaction became independent of hydrogen peroxide .
3.6. Kinetic Study of Leachate Treatment by Fenton Process
Reaction rates in the reactor must be specially determined to complete description and design of a reactor system and its direct effect on reactor size. Therefore, the study of reaction kinetics to prediction of pollutant removal rates is very important in designing and modeling of treatment process .
Determination of the kinetics of the Fenton on COD, TSS, TOC, and color removal reaction is needed to estimate the time required for COD, TSS, TOC, and color removal. A kinetic analysis was conducted by fitting the time-course performance data with zero-, first-, and pseudo-second-order kinetic equations as shown in Table 2.
Where is the rate of conversion, , , and are reaction rate coefficients, is time, and and are the initial and final concentration of the constituent in the liquid, respectively. The data were appropriately explained with first-order kinetic model (higher ), that presented that the model can successfully simulate COD, TSS, TOC, and color removal in the Fenton process. This results show high relationship between COD, TSS, TOC, and color removal efficiency and its initial concentration. In studies carried out by Guedes et al. and Yasar et al, in removal of synthetic dye by Fenton process, reaction rate is described with first-order kinetic model [17, 34]. The effects of COD, TSS, TOC, and color removal in the Fenton process are shown in Figure 6.
According to Figure 6, the linear relation for each pollutant removal confirms the fact that the kinetics of COD, TSS, TOC and color removal adherents of the exponential law with time.
Results showed that application of Fenton process is inadequate for landfill leachate treatment of Kermanshah city, but leachate characteristics could be greatly improved by Fenton process. The most important role of Fenton process is removing organic and toxic organic compounds and increasing the degradability of resistant organic compounds. Thus this process can be used as pretreatment for biological treatment. The main disadvantage of the Fenton process is that it requires disposal of excess sludge production.
Financial support for this study was provided by Kermanshah University of Medical Science under research project. Also appreciation is due to Social Development & Health Promotion Research Center to support approval of this research.
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