Table of Contents
Journal of Fuels
Volume 2014 (2014), Article ID 485045, 9 pages
http://dx.doi.org/10.1155/2014/485045
Research Article

Propane Fuel Cells: Selectivity for Partial or Complete Reaction

1Chemical and Biological Engineering, University of Ottawa, Ottawa, ON, Canada K1N 6N5
2Centre for Catalysis Research and Innovation, University of Ottawa, Ottawa, ON, Canada K1N 6N5
3Chemistry, University of Ottawa, Ottawa, ON, Canada K1N 6N5
4EnPross Inc., 147 Banning Road, Ottawa, ON, Canada K2L 1C5

Received 22 April 2013; Accepted 24 October 2013; Published 20 January 2014

Academic Editors: F. Chen, P. Holtappels, C. Sequeira, and Z. Zhan

Copyright © 2014 Shadi Vafaeyan et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. A. H. Reshak, “MgH2 and LiH metal hydride crystals as novel hydrogen storage materials,” International Journal of Hydrogen Energy, vol. 38, pp. 11946–11954, 2013. View at Google Scholar
  2. A. Al-Othman, A. Y. Tremblay, W. Pell, S. Letaief, B. A. Peppley, and M. Ternan, “A modified silicic acid (Si) and sulphuric acid (S)—Zrp/PTFE/glycerol composite membrane for high temperature direct hydrocarbon fuel cells,” Journal of Power Sources, vol. 224, pp. 158–167, 2013. View at Google Scholar
  3. A. Al-Othman, A. Y. Tremblay, W. Pell, Y. Liu, B. A. Peppley, and M. Ternan, “The effect of glycerol on the conductivity of Nafion-free ZrP/PTFE composite membrane electrolytes for direct hydrocarbon fuel cells,” Journal of Power Sources, vol. 199, pp. 14–21, 2012. View at Publisher · View at Google Scholar · View at Scopus
  4. H. A. Liebhafsky and E. J. Cairns, Fuel Cells and Fuel BAtteries: A Guide to Their Research and Development, John Wiley & Sons, New York, NY, USA, 1968.
  5. J. O. Bockris and S. Srinivasan, Fuel Cells: Their Electrochemistry, McGraw-Hill, New York, NY, USA, 1969.
  6. C. E. Cairns, “Anodic oxidation of hydrocarbons and the hydrocarbon fuel cell,” Adv Electrochem and Electrochem Eng, vol. 8, pp. 337–392, 1971. View at Google Scholar · View at Scopus
  7. M. D. Gross, J. M. Vohs, and R. J. Gorte, “Recent progress in SOFC anodes for direct utilization of hydrocarbons,” Journal of Materials Chemistry, vol. 17, no. 30, pp. 3071–3077, 2007. View at Publisher · View at Google Scholar · View at Scopus
  8. P. Heo, K. Ito, A. Tomita, and T. Hibino, “A proton-conducting fuel cell operating with hydrocarbon fuels,” Angewandte Chemie, vol. 47, no. 41, pp. 7841–7844, 2008. View at Publisher · View at Google Scholar · View at Scopus
  9. S. Y. Hsieh and K. M. Chen, “Anodic oxidation of methane,” Journal of the Electrochemical Society, vol. 124, no. 8, pp. 1171–1174, 1977. View at Google Scholar · View at Scopus
  10. M. G. Sustersic, R. Cordova, W. E. Triaca, and A. J. Arvia, “Electrosorption of methane and its potentiodynamic electrooxidation on platinized platinum,” Journal of the Electrochemical Society, vol. 127, no. 6, pp. 1242–1248, 1980. View at Google Scholar · View at Scopus
  11. F. Hahn and C. A. Melendres, “Anodic oxidation of methane at noble metal electrodes: an “in situ” surface enhanced infrared spectroelectrochemical study,” Electrochimica Acta, vol. 46, no. 23, pp. 3525–3534, 2001. View at Publisher · View at Google Scholar · View at Scopus
  12. O. Savadogo and F. J. Rodriguez Varela, “Low-temperature direct propane polymer electrolyte membranes fuel cell (DPFC),” Journal of New Materials for Electrochemical Systems, vol. 4, no. 2, pp. 93–97, 2001. View at Google Scholar · View at Scopus
  13. C. K. Cheng, J. L. Luo, K. T. Chuang, and A. R. Sanger, “Propane fuel cells using phosphoric-acid-doped polybenzimidazole membranes,” Journal of Physical Chemistry B, vol. 109, no. 26, pp. 13036–13042, 2005. View at Publisher · View at Google Scholar · View at Scopus
  14. F. J. R. Varela and O. Savadogo, “The effect of anode catalysts on the behavior of low temperature Direct Propane Polymer Electrolyte Fuel Cells (DPFC),” Journal of New Materials for Electrochemical Systems, vol. 9, no. 2, pp. 127–137, 2006. View at Google Scholar · View at Scopus
  15. F. T. Bacon and T. M. Fry, “The development and practical application of fuel cells,” Proceedings of the Royal Society A, vol. 334, pp. 427–452, 1973. View at Google Scholar
  16. V. S. Bagotzky, Y. B. Vassiliev, and O. A. Khazova, “Generalized scheme of chemisorption, electrooxidation and electroreduction of simple organic compounds on platinum group metals,” Journal of Electroanalytical Chemistry, vol. 81, no. 2, pp. 229–238, 1977. View at Google Scholar · View at Scopus
  17. H. Wroblowa, B. J. Piersma, and J. O. Bockris, “Studies of the mechanism of the anodic oxidation of ethylene in acid and alkaline media,” Journal of Electroanalytical Chemistry, vol. 6, no. 5, pp. 401–416, 1963. View at Google Scholar · View at Scopus
  18. W. T. Grubb and C. J. Michalske, “A high performance propane fuel cell operating in the temperature range of 150–200°C,” Journal of the Electrochemical Society, vol. 111, pp. 1015–1019, 1964. View at Google Scholar
  19. S. Bertholet, E. Gehain, F. Hahn, J. M. Leger, S. Srinivasan, and C. Lamy, “Electrooxidation of methane: PEMFC and in situ electrochemical spectroscopic studies,” in Proceedings of the Meeting Abstracts- Electrochemical Society, vol. 98 of Abstract No. 1D90, Boston, Mass, USA, 1998.
  20. F. J. Rodríguez Varela and O. Savadogo, “Real-time mass spectrometric analysis of the anode exhaust gases of a direct propane fuel cell,” Journal of the Electrochemical Society, vol. 152, no. 9, pp. A1755–A1762, 2005. View at Publisher · View at Google Scholar · View at Scopus
  21. J. M. Soler, E. Artacho, J. D. Gale et al., “The SIESTA method for ab initio order-N materials simulation,” Journal of Physics Condensed Matter, vol. 14, no. 11, pp. 2745–2779, 2002. View at Publisher · View at Google Scholar · View at Scopus
  22. J. P. Perdew, K. Burke, and M. Ernzerhof, “Generalized gradient approximation made simple,” Physical Review Letters, vol. 77, no. 18, pp. 3865–3868, 1996. View at Google Scholar · View at Scopus
  23. W. M. Haynes, CRC Handbook of Chemistry and Physics, CRC Press, 91st edition, 2010.
  24. J. P. Perdew, A. Ruzsinszky, G. I. Csonka et al., “Restoring the density-gradient expansion for exchange in solids and surfaces,” Physical Review Letters, vol. 100, Article ID 136406, 2008. View at Publisher · View at Google Scholar · View at Scopus
  25. D. C. Ford, A. U. Nilekar, Y. Xu, and M. Mavrikakis, “Partial and complete reduction of O2 by hydrogen on transition metal surfaces,” Surface Science, vol. 604, no. 19-20, pp. 1565–1575, 2010. View at Publisher · View at Google Scholar · View at Scopus
  26. T. Jiang, D. J. Mowbray, S. Dobrin et al., “Trends in CO oxidation rates for metal nanoparticles and close-packed, stepped, and kinked surfaces,” Journal of Physical Chemistry C, vol. 113, no. 24, pp. 10548–10553, 2009. View at Publisher · View at Google Scholar · View at Scopus
  27. J. S. Hummelshøj, J. Blomqvist, S. Datta et al., “Communications: elementary oxygen electrode reactions in the aprotic Li-air battery,” Journal of Chemical Physics, vol. 132, no. 7, Article ID 071101, 2010. View at Publisher · View at Google Scholar · View at Scopus
  28. C. D. Taylor, M. Neurock, and J. R. Scully, “A first-principles model for hydrogen uptake promoted by sulfur on Ni(111),” Journal of the Electrochemical Society, vol. 158, no. 3, pp. F36–F44, 2011. View at Publisher · View at Google Scholar · View at Scopus
  29. L. C. Grabow, B. Hvolbæk, and J. K. Nørskov, “Understanding trends in catalytic activity: the effect of adsorbate-adsorbate interactions for Co oxidation over transition metals,” Topics in Catalysis, vol. 53, no. 5-6, pp. 298–310, 2010. View at Publisher · View at Google Scholar · View at Scopus
  30. L. Nykänen and K. Honkala, “Density functional theory study on propane and propene adsorption on Pt(111) and PtSn alloy surfaces,” Journal of Physical Chemistry C, vol. 115, no. 19, pp. 9578–9586, 2011. View at Publisher · View at Google Scholar · View at Scopus
  31. A. Antony, C. Hakanoglu, A. Asthagiri, and J. F. Weaver, “Dispersion-corrected density functional theory calculations of the molecular binding of n-alkanes on Pd(111) and PdO(101),” Journal of Chemical Physics, vol. 136, no. 5, Article ID 054702, 2012. View at Publisher · View at Google Scholar · View at Scopus
  32. C.-L. Kao and R. J. Madix, “The adsorption dynamics of molecular methane, propane, and neopentane on Pd(111): theory and experiment,” Journal of Physical Chemistry B, vol. 106, no. 33, pp. 8248–8257, 2002. View at Publisher · View at Google Scholar · View at Scopus
  33. M. Smutek and S. Černý, “Calorimetric studies of hydrocarbon adsorption on metal films. III. Methane, ethane and propane on molybdenum,” Journal of Catalysis, vol. 47, no. 2, pp. 178–189, 1977. View at Google Scholar · View at Scopus
  34. J. Kua and W. A. Goddard III, “Oxidation of methanol on 2nd and 3rd row group VIII transition metals (Pt, Ir, Os, Pd, Rh, and Ru): application to direct methanol fuel cells,” Journal of the American Chemical Society, vol. 121, no. 47, pp. 10928–10941, 1999. View at Publisher · View at Google Scholar · View at Scopus
  35. M. Pozzo, G. Carlini, R. Rosei, and D. Alfe, “Comparative study of water dissociation on Rh(111) and Ni(111) studied with first principles calculations,” Journal of Chemical Physics, vol. 126, no. 16, Article ID 164706, 2007. View at Publisher · View at Google Scholar · View at Scopus