Table of Contents
Journal of Metallurgy
Volume 2013 (2013), Article ID 256403, 14 pages
http://dx.doi.org/10.1155/2013/256403
Research Article

Inhibition Effect of Substituted Thiadiazoles on Corrosion Activity of N80 Steel in HCl Solution

Department of Applied Chemistry, Indian School of Mines, Dhanbad 826004, India

Received 29 November 2012; Revised 2 March 2013; Accepted 18 March 2013

Academic Editor: Elena V. Pereloma

Copyright © 2013 M. Yadav et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The inhibition effect of some prepared compounds, namely, thiadiazole derivatives, on N80 steel corrosion in 15% HCl solutions has been studied by using the weight loss, electrochemical polarization, and electrochemical impedance spectroscopy techniques. It was found that the inhibition efficiency of the thiadiazole derivatives, namely, 2-amino-5-(4-methoxyphenyl)-1,3,4-thiazole (AMPT), 2-amino-5-phenyl-1,3,4-thiazole (APT), and 2-amino-5-(4-chlorophenyl)-1,3,4-thiazole (ACPT), increases with the increase in concentration. Inhibition efficiency follows the order AMPT > APT > ACPT. The effect of temperature on the corrosion was investigated by the weight loss method, and some thermodynamic parameters were calculated. The inhibitive action may be attributed to the adsorption of inhibitor molecules on the active sites of the metal surface following Langmuir adsorption isotherm. Polarization measurements indicated that thiadiazole derivatives act as mixed-type corrosion inhibitor. The adsorption of thiadiazole derivatives on N80 surface exposed to inhibitor-containing solutions was confirmed using SEM and FT-IR spectra.