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Journal of Materials
Volume 2015 (2015), Article ID 372716, 7 pages
http://dx.doi.org/10.1155/2015/372716
Research Article

On the Synthesis of Molybdenum Nanoparticles under Reducing Conditions in Ionic Liquids

1Materials Chemistry Unit, Department of Pure and Applied Chemistry, University of Calabar, PMB 1115, Calabar, Nigeria
2Institute of Chemistry, University of Potsdam, Karl-Liebknecht-Straße 24-25, Building 26, 14476 Golm, Germany
3Max Planck Institute of Colloids and Interfaces, 14476 Golm, Germany

Received 26 June 2015; Accepted 18 August 2015

Academic Editor: Huan-Tsung Chang

Copyright © 2015 Ayi A. Ayi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. F. Caruso, Colloids and Colloid Assemblies, Wiley-VCH, Weinheim, Germany, 2004.
  2. H. E. Bergna and W. O. Roberts, Colloidal Silica—Fundamentals and Applications, vol. 131 of Surfactant Science Series, Taylor & Francis, Boca Raton, Fla, USA, 2006.
  3. M.-C. Daniel and D. Astruc, “Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology,” Chemical Reviews, vol. 104, no. 1, pp. 293–346, 2004. View at Google Scholar · View at Scopus
  4. M. A. El-Sayed, “Some interesting properties of metals confined in time and nanometer space of different shapes,” Accounts of Chemical Research, vol. 34, no. 4, pp. 257–264, 2001. View at Publisher · View at Google Scholar · View at Scopus
  5. A. Biswas, T. Wang, and A. S. Biris, “Single metal nanoparticle spectroscopy: optical characterization of individual nanosystems for biomedical applications,” Nanoscale, vol. 2, no. 9, pp. 1560–1572, 2010. View at Publisher · View at Google Scholar · View at Scopus
  6. N. Semagina and L. Kiwi-Minsker, “Recent advances in the liquid-phase synthesis of metal nanostructures with controlled shape and size for catalysis,” Catalysis Reviews: Science and Engineering, vol. 51, no. 2, pp. 147–217, 2009. View at Publisher · View at Google Scholar · View at Scopus
  7. J. Dupont and J. D. Scholten, “On the structural and surface properties of transition-metal nanoparticles in ionic liquids,” Chemical Society Reviews, vol. 39, no. 5, pp. 1780–1804, 2010. View at Publisher · View at Google Scholar · View at Scopus
  8. E. R. Parnham and R. E. Morris, “Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids,” Accounts of Chemical Research, vol. 40, no. 10, pp. 1005–1013, 2007. View at Publisher · View at Google Scholar · View at Scopus
  9. R. E. Morris, “Ionic liquids and microwaves—making zeolites for emerging applications,” Angewandte Chemie International Edition, vol. 47, no. 3, pp. 442–444, 2008. View at Publisher · View at Google Scholar · View at Scopus
  10. A. Taubert, “Inorganic materials synthesis—a bright future for ionic liquids?” Acta Chimica Slovenica, vol. 52, no. 3, pp. 183–186, 2005. View at Google Scholar · View at Scopus
  11. A. Taubert and Z. Li, “Inorganic materials from ionic liquids,” Dalton Transactions, no. 7, pp. 723–727, 2007. View at Publisher · View at Google Scholar · View at Scopus
  12. Z. Li, Z. Jia, Y. Luan, and T. Mu, “Ionic liquids for synthesis of inorganic nanomaterials,” Current Opinion in Solid State and Materials Science, vol. 12, no. 1, pp. 1–8, 2008. View at Publisher · View at Google Scholar · View at Scopus
  13. F. Endres, S. Zein El Abedin, A. Y. Saad et al., “On the electrodeposition of titanium in ionic liquids,” Physical Chemistry Chemical Physics, vol. 10, no. 16, pp. 2189–2199, 2008. View at Publisher · View at Google Scholar · View at Scopus
  14. A. A. Ayi, V. Khare, P. Strauch, J. Girard, K. M. Fromm, and A. Taubert, “On the chemical synthesis of titanium nanoparticles from ionic liquids,” Monatshefte für Chemie, vol. 141, no. 12, pp. 1273–1278, 2010. View at Publisher · View at Google Scholar · View at Scopus
  15. E. Redel, R. Thomann, and C. Janiak, “Use of ionic liquids (ILs) for the IL-anion size-dependent formation of Cr, Mo and W nanoparticles from metal carbonyl M(CO)6 precursors,” Chemical Communications, no. 15, pp. 1789–1791, 2008. View at Publisher · View at Google Scholar · View at Scopus
  16. E. Redel, R. Thomann, and C. Janiak, “First correlation of nanoparticle size-dependent formation with the ionic liquid anion molecular volume,” Inorganic Chemistry, vol. 47, no. 1, pp. 14–16, 2008. View at Publisher · View at Google Scholar · View at Scopus
  17. J. Krämer, E. Redel, R. Thomann, and C. Janiak, “Use of ionic liquids for the synthesis of iron, ruthenium, and osmium nanoparticles from their metal carbonyl precursors,” Organometallics, vol. 27, no. 9, pp. 1976–1978, 2008. View at Publisher · View at Google Scholar · View at Scopus
  18. C. Vollmer, E. Redel, K. Abu-Shandi et al., “Microwave irradiation for the facile synthesis of transition-metal nanoparticles (NPs) in ionic liquids (ILs) from metal-carbonyl precursors and Ru-, Rh-, and Ir-NP/IL dispersions as biphasic liquid-liquid hydrogenation nanocatalysts for cyclohexene,” Chemistry, vol. 16, no. 12, pp. 3849–3858, 2010. View at Publisher · View at Google Scholar · View at Scopus
  19. R. D. Rogers and K. R. Seddon, Ionic Liquids: Industrial Applications for Green Chemistry, ACS Symposium Series 818, American Chemical Society, 2002.
  20. R. D. Rogers and K. R. Seddon, Ionic Liquids As Green Solvents: Progress and Prospects, ACS Symposium Series 856, American Chemical Society, Washington, DC, USA, 2003.
  21. R. D. Rogers and K. R. Seddon, Ionic Liquids IIIA: Fundamentals, Progress, Challenges, and Opportunities: Properties and Structure, ACS Symposium Series 901, American Chemical Society, 2005.
  22. P. Wasserscheid and T. Welton, Ionic Liquids in Synthesis, Wiley-VCH, Weinheim, Germany, 2007.
  23. B. Kirchner, Ionic Liquids, vol. 290 of Topics in Current Chemistry, Springer, New York, NY, USA, 2009.
  24. V. Khare, Z. Li, A. Mantion et al., “Strong anion effects on gold nanoparticle formation in ionic liquids,” Journal of Materials Chemistry, vol. 20, no. 7, pp. 1332–1339, 2010. View at Publisher · View at Google Scholar · View at Scopus
  25. E. Redel, J. Krämer, R. Thomann, and C. Janiak, “Synthesis of Co, Rh and Ir nanoparticles from metal carbonyls in ionic liquids and their use as biphasic liquid-liquid hydrogenation nanocatalysts for cyclohexene,” Journal of Organometallic Chemistry, vol. 694, no. 7-8, pp. 1069–1075, 2009. View at Publisher · View at Google Scholar · View at Scopus
  26. J. Dupont, G. S. Fonseca, A. P. Umpierre, P. F. P. Fichtner, and S. R. Teixeira, “Transition-metal nanoparticles in imidazolium ionic liquids: recycable catalysts for biphasic hydrogenation reactions,” Journal of the American Chemical Society, vol. 124, no. 16, pp. 4228–4229, 2002. View at Publisher · View at Google Scholar · View at Scopus
  27. E. J. W. Verwey and J. T. G. Overbeek, Theory of the Stability of Lyophobic Colloids, Dover Publications, Mineola, NY, USA, 2nd edition, 1999.