Research Article
On the Synthesis of Molybdenum Nanoparticles under Reducing Conditions in Ionic Liquids
Table 1
Products obtained from ILs.
| | IL cation | IL anion | Color of the precipitate | Products (JCPDS) | Fraction | Crystal system |
| | Bmim | BF4 | Light yellow | Mo4O11 (65-2473) | | Orthorhombic |
| Bmim
Emim | N(CN)2 | Dark red | MoO3 (47-1081) | | Monoclinic |
| Bmim
Emim | TfO | Brown-olive green | Mo (42-1120)
MoO3 (65-2421) | 59%
41% | Cubic
Orthorhombic |
| Bmim
Emim | Tf2N | Brown | MoO3 (65-2421)
Mo17O47 (13-0345) | | Orthorhombic |
| | Emim | MS | Brown | Mo4O11 (65-2473) | | Orthorhombic |
| | Emim | ES | Dark red | Mo (42-1120) | | Cubic |
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A: for calculation of fractions see experimental part. Unless specified otherwise, the samples are single phase.
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