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Journal of Nanomaterials
Volume 2006, Article ID 76371, 10 pages
http://dx.doi.org/10.1155/JNM/2006/76371

Silica-Polystyrene Nanocomposite Particles Synthesized by Nitroxide-Mediated Polymerization and Their Encapsulation through Miniemulsion Polymerization

1Ingénierie des Matériaux Polymères (IMP), Laboratoire des Matériaux Polymères et des Biomatériaux (LMPB), Université de Lyon 1, Université de Lyon, Villeurbanne Cedex 69003, France
2Laboratoire de Chimie et Procédés de Polymérisation (LCPP), École Supérieure Chimie Physique Electronique de Lyon (CPE), Université de Lyon 1, Université de Lyon, Bâtiment F308, BP 2077, 43 Boulevard du 11 Novembre 1918, Villeurbanne Cedex 69616, France

Received 2 February 2006; Revised 9 November 2006; Accepted 21 November 2006

Copyright © 2006 Bérangère Bailly et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. T. Von Werne and T. E. Patten, “Preparation of structurally well-defined polymer-nanoparticle hybrids with controlled/living radical polymerizations [3],” Journal of the American Chemical Society, vol. 121, no. 32, pp. 7409–7410, 1999. View at Publisher · View at Google Scholar
  2. T. Von Werne and T. E. Patten, “Atom transfer radical polymerization from nanoparticles: a tool for the preparation of well-defined hybrid nanostructures and for understanding the chemistry of controlled/“living” radical polymerizations from surfaces,” Journal of the American Chemical Society, vol. 123, no. 31, pp. 7497–7505, 2001. View at Publisher · View at Google Scholar
  3. T. Von Werne, S. Farmer, I. M. Suehiro, and T. E. Patten, “Composite films of polymer-inorganic hybrid nanoparticles prepared using controlled/“living” radical polymerization,” Polymeric Materials: Science and Engineering, vol. 82, pp. 294–295, 2000. View at Google Scholar
  4. C. Perruchot, M. A. Khan, A. Kamitsi, S. P. Armes, T. Von Werne, and T. E. Patten, “Synthesis of well-defined, polymer-grafted silica particles by aqueous ATRP,” Langmuir, vol. 17, no. 15, pp. 4479–4481, 2001. View at Publisher · View at Google Scholar
  5. H. Böttcher, M. L. Hallensleben, S. Nuss, and H. Wurm, “ATRP grafting from silica surface to create first and second generation of grafts,” Polymer Bulletin, vol. 44, no. 2, pp. 223–229, 2000. View at Publisher · View at Google Scholar
  6. J. Parvole, L. Billon, and J. P. Montfort, “Formation of polyacrylate brushes on silica surfaces,” Polymer International, vol. 51, no. 10, pp. 1111–1116, 2002. View at Publisher · View at Google Scholar
  7. A. Kasseh, A. Ait-Kadi, B. Riedl, and J. F. Pierson, “Organic/inorganic hybrid composites prepared by polymerization compounding and controlled free radical polymerization,” Polymer, vol. 44, no. 5, pp. 1367–1375, 2003. View at Publisher · View at Google Scholar
  8. R. Inoubli, S. Dagréou, A. Khoukh, F. Roby, J. Peyrelasse, and L. Billon, “‘Graft from’ polymerization on colloidal silica particles: elaboration of alkoxyamine grafted surface by in situ trapping of carbon radicals,” Polymer, vol. 46, no. 8, pp. 2486–2496, 2005. View at Publisher · View at Google Scholar
  9. J. Parvole, G. Laruelle, A. Khoukh, and L. Billon, “Surface initiated polymerization of poly(butyl acrylate) by nitroxide mediated polymerization: first comparative polymerization of a bimolecular and a unimolecular initiator-grafted silica particles,” Macromolecular Chemistry and Physics, vol. 206, no. 3, pp. 372–382, 2005. View at Publisher · View at Google Scholar
  10. C. Bartholome, E. Beyou, E. Bourgeat-Lami, P. Chaumont, and N. Zydowicz, “Nitroxide-mediated polymerizations from silica nanoparticle surfaces: “graft from” polymerization of styrene using a triethoxysilyl-terminated alkoxyamine initiator,” Macromolecules, vol. 36, no. 21, pp. 7946–7952, 2003. View at Publisher · View at Google Scholar
  11. C. Bartholome, E. Beyou, E. Bourgeat-Lami, P. Chaumont, F. Lefebvre, and N. Zydowicz, “Nitroxide-mediated polymerization of styrene initiated from the surface of silica nanoparticles. In situ generation and grafting of alkoxyamine initiators,” Macromolecules, vol. 38, no. 4, pp. 1099–1106, 2005. View at Publisher · View at Google Scholar
  12. C. Bartholome, E. Beyou, E. Bourgeat-Lami, P. Chaumont, and N. Zydowicz, “Nitroxide-mediated polymerization of styrene initiated from the surface of fumed silica. Comparison of two synthetic routes,” Polymer, vol. 46, no. 19, pp. 8502–8510, 2005. View at Publisher · View at Google Scholar
  13. S. Blomberg, S. Ostberg, E. Harth, A. W. Bosman, B. Van Horn, and C. J. Hawker, “Production of crosslinked, hollow nanoparticles by surface-initiated living free-radical polymerization,” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 40, no. 9, pp. 1309–1320, 2002. View at Publisher · View at Google Scholar
  14. F. Tiarks, K. Landfester, and M. Antonietti, “Encapsulation of carbon black by miniemulsion polymerization,” Macromolecular Chemistry and Physics, vol. 202, no. 1, pp. 51–60, 2001. View at Publisher · View at Google Scholar
  15. L. P. Ramírez and K. Landfester, “Magnetic polystyrene nanoparticles with a high magnetite content obtained by miniemulsion processes,” Macromolecular Chemistry and Physics, vol. 204, no. 1, pp. 22–31, 2003. View at Publisher · View at Google Scholar
  16. S.-W. Zhang, S.-X. Zhou, Y.-M. Weng, and L.-M. Wu, “Synthesis of SiO2/polystyrene nanocomposite particles via miniemulsion polymerization,” Langmuir, vol. 21, no. 6, pp. 2124–2128, 2005. View at Publisher · View at Google Scholar · View at PubMed
  17. Q. Sun, Y. Deng, and Z. L. Wang, “Synthesis and characterization of polystyrene-encapsulated laponite composites via miniemulsion polymerization,” Macromolecular Materials and Engineering, vol. 289, no. 3, pp. 288–295, 2004. View at Publisher · View at Google Scholar
  18. J. L. Couturier and O. Guerret, WO 0212149, 2002.
  19. W. Stöber, A. Fink, and E. Bohn, “Controlled growth of monodisperse silica spheres in the micron size range,” Journal of Colloid and Interface Science, vol. 26, no. 1, pp. 62–69, 1968. View at Publisher · View at Google Scholar
  20. A. P. Philipse and A. Vrij, “Preparation and properties of nonaqueous model dispersions of chemically modified, charged silica spheres,” Journal of Colloid and Interface Science, vol. 128, no. 1, pp. 121–136, 1989. View at Publisher · View at Google Scholar
  21. E. Bourgeat-Lami and J. Lang, “Encapsulation of inorganic particles by dispersion polymerization in polar media 1. Silica nanoparticles encapsulated by polystyrene,” Journal of Colloid and Interface Science, vol. 197, no. 2, pp. 293–308, 1998. View at Publisher · View at Google Scholar
  22. A. El Harrak, G. Carrot, J. Oberdisse, C. Eychenne-Baron, and F. Boué, “Surface-atom transfer radical polymerization from silica nanoparticles with controlled colloidal stability,” Macromolecules, vol. 37, no. 17, pp. 6376–6384, 2004. View at Publisher · View at Google Scholar
  23. C. Perruchot, M. A. Khan, A. Kamitsi et al., “XPS characterisation of core-shell silica-polymer composite particles synthesised by atom transfer radical polymerisation in aqueous media,” European Polymer Journal, vol. 40, no. 9, pp. 2129–2141, 2004. View at Publisher · View at Google Scholar
  24. A. El Harrak, G. Carrot, J. Oberdisse, J. Jestin, and F. Boué, “Control of the colloidal stability of polymer-grafted-silica nanoparticles obtained by atom transfer radical polymerization,” Macromolecular Symposia, vol. 226, no. 1, pp. 263–278, 2005. View at Publisher · View at Google Scholar
  25. K. Ohno, T. Morinaga, K. Koh, Y. Tsujii, and T. Fukuda, “Synthesis of monodisperse silica particles coated with well-defined, high-density polymer brushes by surface-initiated atom transfer radical polymerization,” Macromolecules, vol. 38, no. 6, pp. 2137–2142, 2005. View at Publisher · View at Google Scholar
  26. B. Zhao and W. J. Brittain, “Polymer brushes: surface-immobilized macromolecules,” Progress in Polymer Science (Oxford), vol. 25, no. 5, pp. 677–710, 2000. View at Publisher · View at Google Scholar
  27. K. Ohno, K. Koh, Y. Tsujii, and T. Fukuda, “Synthesis of gold nanoparticles coated with well-defined, high-density polymer brushes by surface-initiated living radical polymerization,” Macromolecules, vol. 35, no. 24, pp. 8989–8993, 2002. View at Publisher · View at Google Scholar