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Journal of Nanomaterials
Volume 2010, Article ID 352914, 8 pages
Research Article

Design and Preparation of Cross-Linked Polystyrene Nanoparticles for Elastomer Reinforcement

1The Key Laboratory for Nanomaterials of Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
2The Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China
3Department of Polymer Science, Beijing University of Chemical Technology, Beijing 100029, China

Received 31 October 2009; Revised 1 February 2010; Accepted 31 March 2010

Academic Editor: Gaurav Mago

Copyright © 2010 Ming Lu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Cross-linked polystyrene (PS) particles in a latex form were synthesized by free radical emulsion polymerization. The nano-PS-filled elastomer composites were prepared by the energy-saving latex compounding method. Results showed that the PS particles took a spherical shape in the size of 40–60 nm with a narrow size distribution, and the glass-transition temperature of the PS nanoparticles increased with the cross-linking density. The outcomes from the mechanical properties demonstrated that when filled into styrene-butadiene rubber (SBR), nitrile-butadiene rubber (NBR), and natural rubber (NR), the cross-linked PS nano-particles exhibited excellent reinforcing capabilities in all the three matrices, and the best in the SBR matrix. In comparison with that of the carbon black filled composites, another distinguished advantage of the cross-linked PS particles filled elastomer composites was found to be light weight in density, which could help to save tremendous amount of energy when put into end products.