Research Article

Electrochromic Devices Based on Porous Tungsten Oxide Thin Films

Table 1

The lattice parameters of WO3 EC layer prepared at 400, 500, and 600°C and the lattice parameters after lithiating the sample at +2.0 V.

S. No.Sample nameColoration voltageLattice parameter
nmAngle
𝑎 𝑏 𝑐 𝛽

1400°C (Hexagonal)0 V 0 . 7 3 7 9 ± 0 . 0 0 0 8 0 . 7 7 5 6 ± 0 . 0 0 0 2
+2 V 0 . 7 4 1 1 8 ± 0 . 0 0 1 2 0 . 7 6 1 5 2 ± 0 . 0 0 0 3
2500°C (Monoclinic)0 V 0 . 7 3 5 1 ± 0 . 0 0 0 2 0 . 7 5 4 0 ± 0 . 0 0 0 5 0 . 7 7 1 2 ± 0 . 0 0 0 1 9 9 0 . 3 ± 0 . 6
+2 V 0 . 7 3 9 7 ± 0 . 0 0 1 5 0 . 7 4 1 8 ± 0 . 0 0 2 0 . 7 7 1 7 ± 0 . 0 0 0 2 8 9 . 6 ± 1 0 . 1
3600°C (Orthorhombic)0 V 0 . 7 3 5 1 ± 0 . 0 0 1 9 0 . 7 5 6 6 ± 0 . 0 0 1 9 0 . 7 7 2 4 ± 0 . 0 0 2 1 9 0 . 0
+2 V 0 . 7 4 4 5 ± 0 . 0 0 2 3 0 . 7 4 6 9 ± 0 . 0 0 5 8 0 . 7 6 2 4 ± 0 . 0 0 5 5 9 0 . 0