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Journal of Nanomaterials
Volume 2013 (2013), Article ID 542109, 7 pages
Research Article

A Novel Synthesis Method of Porous Calcium Silicate Hydrate Based on the Calcium Oxide/Polyethylene Glycol Composites

Key Laboratory of Three Gorges Reservoir Region’s Eco-Environment, Ministry of Education, Chongqing University, Chongqing 400045, China

Received 9 August 2013; Revised 1 September 2013; Accepted 2 September 2013

Academic Editor: Fan Dong

Copyright © 2013 Wei Guan et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


This paper proposed a novel method to prepare porous calcium silicate hydrate (CSH) based on the calcium oxide/polyethylene glycol (CaO/PEG2000) composites as the calcium materials. The porosity formation mechanism was revealed via X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), Brunauer-Emmett-Teller (BET), and Fourier transformed infrared spectroscopy (FT-IR). The reactivity of silica materials (SiO2) enhanced by increasing pH value. Ca2+ could not sustain release from CaO/PEG2000 and reacted with caused by silica to form CSH until the hydrothermal temperature reached to 170°C, avoiding the hardly dissolved intermediates formation efficiently. The as-prepared CSH, due to the large specific surface areas, exhibited excellent release capability of Ca2+ and OH. This porous CSH has potential application in reducing the negative environmental effects of continual natural phosphate resource depletion.