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Journal of Nanomaterials
Volume 2013, Article ID 648346, 9 pages
Research Article

Fabrication of Mo+N-Codoped TiO2 Nanotube Arrays by Anodization and Sputtering for Visible Light-Induced Photoelectrochemical and Photocatalytic Properties

Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, China

Received 26 August 2013; Accepted 18 November 2013

Academic Editor: Shenmin Zhu

Copyright © 2013 Min Zhang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Mo,N-codoped TiO2 nanotube arrays (TNAs) were fabricated by a two-step method consisting of electrochemical anodization and subsequent magnetron sputtering of Mo. The samples were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS). The results showed that the Mo,N-codoped TiO2 nanotube arrays exhibited higher visible light absorbance and remarkably enhanced photocurrent density and photocatalytic activity compared with single N-doped TiO2. The highly efficient photoelectrochemical and photocatalytic activity is associated with the codoping effect between Mo and N, which plays a key role in producing new states, narrowing the bandgap, and reducing the recombination thereby effectively improving the visible light absorption and photocatalytic activity of TNAs.