Hydrothermal Synthesis, Characterization, and Visible Light-Driven Photocatalytic Properties of Bi<sub>2</sub>WO<sub>6</sub> Nanoplates

Phuruangrat, Anukorn; Dumrongrojthanath, Phattranit; Ekthammathat, Nuengruethai; Thongtem, Somchai; Thongtem, Titipun

doi:https://doi.org/10.1155/2014/138561

Journal of Nanomaterials

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Research Article | Open Access

Volume 2014 | Article ID 138561 | https://doi.org/10.1155/2014/138561

Hydrothermal Synthesis, Characterization, and Visible Light-Driven Photocatalytic Properties of Bi₂WO₆ Nanoplates

Anukorn Phuruangrat,¹Phattranit Dumrongrojthanath,²Nuengruethai Ekthammathat,²Somchai Thongtem,^3,4and Titipun Thongtem^2,4

Academic Editor: Tao He

Received08 Jan 2014

Revised09 Apr 2014

Accepted09 Apr 2014

Published07 May 2014

Abstract

In this research, the effects on reaction temperature and length of time on Bi₂WO₆ nanoplates by hydrothermal synthesis on morphologies and photocatalytic properties were studied. The products obtained at different reaction temperature and reaction time were characterized by XRD, Raman, FTIR, SEM, and TEM techniques. The photocatalytic properties of the samples were measured by decomposing the rhodamine-B organic dye. XRD pattern was specified as pure orthorhombic well-crystallized Bi₂WO₆ phase for the 180°C and 20 h synthesis. Its FTIR spectrum shows main absorption bands at 400–1000 cm⁻¹, assigned to Bi–O stretching, W–O stretching, and W–O–W bridging stretching modes. SEM and TEM analyses show that the product was composed of nanoplates. Photocatalytic activity of Bi₂WO₆ nanoplates shows the 98.24% degradation of rhodamine-B under the Xe light irradiation within 100 min.

1. Introduction

In the past three decades, semiconducting photocatalyst has attracted extensive attention due to its potential applications in solar energy conversion and environmental remedy [1, 2]. Because of the good chemical stability, high oxidation activity, nontoxicity, and low price, TiO₂ has been the most popular photocatalyst for environmental purification. Among different semiconductors, titania has been investigated most frequently since the discovery of the photocatalytic splitting of water on titania electrodes in 1972 by Fujishima and Honda [1, 3, 4]. The main shortcoming of titania is the absorption of only ultraviolet with the wavelength of less than 387.5 nm, which accounts for only about 4% of sunlight. TiO₂-based photocatalysts have been the most popular and have been shown to be a lot of progress. Due to the fact that TiO₂ can only be activated by the ultraviolet light, the use of TiO₂ is thus limited by its negligible activity under visible light irradiation [4, 5]. It is very urgent to develop highly efficient visible light induced photocatalysts to meet the high requirement of future environmental remedy and energy crisis. Therefore, it is of great importance to develop visible light responsive photocatalysts.

Bismuth tungstate was reported to show photocatalytic activity under visible light irradiation [1, 5]. The Aurivillius family of bismuth oxide layered perovskite has attracted considerable attention due to their important applied properties such as ionic conductivity, photocatalytic activity in waste purification, and ferroelectricity [6, 7]. Their common formula [Bi₂O₂] (A = Ca, Sr, Ba, Pb, Bi, Na, K, and B = Ti, Nb, Ta, Mo, W, Fe) suggests easy tuning of these properties by iso- or aliovalent substitution at the and perovskitic sites with an only empirical restriction that the position should be occupied with ions with the radius of ca. 0.6 Å and over 60% of them having electron configuration. The case differs significantly from series in several aspects. First, there are no positions in the perovskitic slabs, and the possibilities of isovalent substitution among ferroelectrics are very restricted [4–6]. Bi₂WO₆ as an Aurivillius-phase perovskite belongs to the bismuth oxide family with a structure consisting of perovskite layers () between corner-sharing structure of WO₆ octahedrons sandwiched between (Bi₂O₂)²⁺ layers [8–10]. Bismuth tungstate (Bi₂WO₆) is a typical n-type direct band gap semiconductor with a band gap of 2.75 eV and has potential applications in electrode materials, solar energy conversion, and visible-light-driven photocatalysis [9].

The Bi₂WO₆ nanostructures with different morphologies such as nanoplates [4, 11], nanocages [7], hierarchical flowers [8], snow-like [9], and nanolaminars [10] have been prepared by solution-phase methods such as hydrothermal [4, 8, 9, 11], refluxing [7], sonochemical method [10], and citrate complex method [12]. However, the hydrothermal method is a widely used technique because of low cost, low temperature, high yield, scalable process, and large scale method [13, 14]. It is able to control the shape and dimension of nanomaterials by reaction time, temperature, pH value, and capping agent during hydrothermal process [13, 15, 16]. Shang et al. [4] prepared Bi₂WO₆ photocatalytic nanoplates with the size of ca. 30 nm. The photocatalytic activity of the as-prepared Bi₂WO₆ was evaluated by the degradation of rhodamine-B (RhB) solution under visible light irradiation within 60 min while photodegradation efficiency of RhB of Bi₂WO₆ nanoparticles reaches 75 min [17]. It was about 8–10 times higher than that of the product prepared by solid-state reaction.

In the present study, we report a facile, low-cost, and green hydrothermal route to synthesize the Bi₂WO₆ nanoplates. The effects of hydrothermal temperature and reaction time on formation of Bi₂WO₆ nanoplates, as well as their photocatalytic activities, were investigated. It was found that the Bi₂WO₆ nanoplates have high visible light photocatalytic activity in the degradation of RhB.

2. Experimental Procedures

Several solutions were formed by dissolving 1.6493 g of sodium tungstate (Na₂WO₄) in 100 mL reverse osmosis (RO) water each and continuously stirred at room temperature for 30 min. Subsequently, 4.8511 g bismuth nitrate (Bi(NO₃)₃) was added to each of these solutions with 30 min continuous stirring at room temperature and followed by adding 3 M NaOH until achieving the desired pH of 10. The solutions were hydrothermally processed at 100–200°C for 0–20 h. In the end, the as-synthesized precipitates were separated by filtration, rinsed with distilled water and ethanol, and dried at 80°C for 24 h for further characterization.

X-ray powder diffraction (XRD) patterns of the products were recorded on a Japan Rigaku D/MAX-γA X-ray diffractometer with graphite monochromator and Cu K_α radiation (λ = 0.154178 nm) at a scanning rate of 0.02 deg/s ranging from 20 to 60 deg. Raman spectra were recorded on a HORIBA JOBIN YVON T64000 Raman spectrometer with 50 mW and 514.5 nm wavelength Ar green laser and FTIR spectra on a BRUKER TENSOR 27 Fourier transform infrared (FTIR) spectrometer with KBr as a diluting agent and operated in the range of 400–4,000 cm⁻¹. SEM images were taken on a JEOL JSM-6335F scanning electron microscope operating at 20 kV and TEM images on a JEOL JEM-2010 JEOL transmission electron microscope (TEM) at an accelerating voltage of 200 kV. UV-visible absorption was carried out on a Perkin Elmer Lambda 25 UV-vis spectrophotometer.

The photocatalytic activities of as-synthesized samples were tested by measuring the degradation of rhodamine-B (RhB) in an aqueous solution under visible light irradiation as light source of Xe lamp. Each 150 mg photocatalyst was suspended in each of 150 mL 10⁻⁵M RhB solution aqueous solutions. The solutions were magnetically stirred for 30 min in dark to establish an adsorption/desorption equilibrium of RhB on the surfaces of the photocatalyst. Then the light was turned on to initiate the photocatalytic reaction. The solution was analyzed by a Lambda 25 spectrophotometer, using 450 W of Xe lamp with wavelength of 553 nm. The decolorization efficiency (%) has been calculated as follows: where C_o is the initial concentration of RhB and is the concentration of RhB after light irradiation.

3. Results and Discussion

To investigate the formation process of Bi₂WO₆ phase, XRD patterns of the samples processed at different temperatures and lengths of time were characterized and shown in Figure 1. The temperature and time have a great influence on the formation of the crystals. Figure 1(a) shows the XRD patterns of the as-synthesized samples at 100–200°C for 20 h by hydrothermal method. It was clearly seen that the crystallization has occurred even at 100°C which can be indexed to Bi₂WO₆ mixed with cubic Bi₂O₃ phase according to the JCPDS number 27-0052 [18]. When the temperature further goes up to 200°C, the XRD patterns of the sample reveal the narrower peaks and the higher intensity, suggesting the enhanced crystallite size. However, the intensities of all diffraction peaks of Bi₂WO₆ synthesized at 180°C for 20 h are the same as the Bi₂WO₆ at 200°C for 20 h. Therefore, the hydrothermally temperature of 180°C is high enough for synthesizing of Bi₂WO₆. At 180 and 200°C, all the diffraction peaks can be readily indexed as pure orthorhombic well-crystallized Bi₂WO₆ structure with cell parameters of = 5.46 Å, = 5.44 Å, and = 16.43 Å, in good agreement with those of the JCPDS number 73-1126 [18]. It was found that the standard intensity of the (113) peak is about five times higher than that of the (200) peak which could be expressed as I₍₁₁₃₎/I₍₂₀₀₎ = 5. However, as for the sample prepared at 180°C for 20 h, the value of I₍₁₁₃₎/I₍₂₀₀₎ was 2.63, suggesting that the crystal has special anisotropic growth in (200) direction [11]. Therefore, the temperature reaction appropriate for the synthesis of Bi₂WO₆ is at 180°C. Figure 1(b) shows the XRD patterns of the samples synthesized by the 180 °C and 0–20 h hydrothermal method. The cubic Bi₂O₃ phase was detected at 180°C for 0 h (before hydrothermal processing). It can be seen that the intensity of the (111) plane of cubic Bi₂O₃ phase at 2θ = 27.93° decreased while intensity of the (113) plane of orthorhombic Bi₂WO₆ phase at 2θ = 28.30° increased. It implied that the percentage of orthorhombic Bi₂WO₆ phase was increased when the reaction time was prolonged from 0 to 15 h at 180°C. When the reaction time was longer than 15 h, all the diffraction peaks can be readily indexed as a pure orthorhombic well-crystallized Bi₂WO₆ structure of the JCPDS number 73-1126 [18]. The XRD results indicate that nanosized Bi₂WO₆ could be selectively synthesized by adjusting the hydrothermal temperature and reaction time, and well-crystallized Bi₂WO₆ crystals can be synthesized at the lowest temperature of 180°C for the reaction time of longer than 15 h.

(a)

(b)

The crystal structure of Bi₂WO₆ as Aurivillius-type structure is layers of perovskite-like (WO₄)²⁻ and fluorite-like (Bi₂O₂)²⁺ layers lying normal to the c direction. The WO₆ octahedrons are joined by equatorial oxygen atoms, whereas the apical oxygen atoms join the WO₆ and BiO₆ polyhedrons. The tungsten exhibits a regular octahedral environment and neighbouring octahedrons are connected to each other by corner sharing. The coordination polyhedrons of bismuth are more complex but each one is bonded to six oxygen atoms [12, 19, 20]. There are only six Raman active and 9 IR active modes for the ideal I4/mmm structure of Bi₂WO₆. These modes can be grouped into symmetric and asymmetric stretching vibrations of the WO₆ octahedrons , bending vibrations of the WO₆ octahedrons , stretching and bending vibrations of the (Bi₂O₂)²⁺ layers , translational motions of the Bi³⁺ ions , and vibrations involving translational motions of Bi³⁺ and W⁶⁺ ions [19, 20]. Raman spectra of the samples are shown in Figure 2(a). The peaks in the range 600–1000 cm⁻¹ were assigned to the stretching of the W–O bonds. In more detail, the vibrations at 789.65 and 820.41 cm⁻¹ of Bi₂WO₆ were associated with the antisymmetric and symmetric A_g modes of terminal O–W–O modes. The peak at 714.61 cm⁻¹ was interpreted as an antisymmetric bridging mode, associated with the tungstate chains [21, 22]. The vibration of 310 cm⁻¹ could be assigned to the translational mode involving simultaneous motion of Bi³⁺ and . The peak at about 300 cm⁻¹ was assigned to the mode of terminal WO₂ groups [21, 23].

(a)

(b)

Figure 2(b) shows FTIR spectra of the as-synthesized Bi₂WO₆ samples. The very weak band located at 3420 cm⁻¹ can be attributed to the symmetric stretching vibration of −OH groups of adsorbed water on surface of Bi₂WO₆ samples. The spectra present the main absorption bands at 400–1000 cm⁻¹ which are assigned to Bi–O stretching, W–O stretching, and W–O–W bridging stretching modes, corresponding to the Bi−O band located at 844.8 cm⁻¹ and the W−O band at 821.6 cm⁻¹ [24–26].

The morphologies of Bi₂WO₆ samples were revealed by field-emission scanning electron microscopy (FE-SEM) as shown in Figure 3. As seen from a low magnification FE-SEM image, the samples exhibited mainly plate-like rectangular shape with a lateral size of average length of 400–600 nm for 180°C 15 h and 300–500 nm for 180°C 20 h. Their magnified images are shown in Figures 3(b) and 3(d), which show many nanoplates with thickness of 50 nm for 180°C 15 h and 20 nm for 180°C 20 h with their smooth surfaces.

(a)

(b)

(c)

(d)

Figure 4 shows TEM images of Bi₂WO₆ samples. The as-synthesized Bi₂WO₆ at 180°C for 15 h shows uniform square nanoplates grown larger and thinner. When the reaction time was further increased to 20 h, the sample was still to be square plate-like morphology with shorter edges. The length of the edges could reach 100–150 nm. The SAED pattern confirms that the nanoplates are single crystalline Bi₂WO₆ since the observed spot pattern corresponded to the most intense diffraction peaks of Bi₂WO₆. The SAED pattern reveals that the crystalline structure can be indexed to the expected orthorhombic crystal lattice of Bi₂WO₆ with characteristic (200), (220), and (020) reflection with as zone axis, in agreement with the above XRD analysis. In this research, the nanoplates preferentially grew along the (001) plane, which is parallel to the direction.

(a)

(b)

(c)

(d)

The UV-visible absorption spectrum of Bi₂WO₆ is shown in Figure 5, which shows the absorption wavelength of less than 460 nm assigned to the intrinsic energy band gap of Bi₂WO₆ [8].

To study the photocatalytic activities of the hydrothermally synthesized samples, tetraethylated rhodamine (RhB) with a major absorption band at 553 nm was chosen as a model organic pollutant. Figure 6 shows the temporal evolution of the spectra during the photodegradation of RhB photocatalyzed by typical Bi₂MoO₆ nanoplates under visible light illumination. The absorption intensity decreased gradually and the major absorption band shifted from 553 nm to 498 nm in photodegradation process during 180 min, confirming that RhB (553 nm) was deethylated to rhodamine (498 nm) under visible light radiation [27, 28]. The deethylated products of RhB are N,N,N′-triethylated rhodamine (539 nm), N,N′-diethylated rhodamine (522 nm), N-ethylated rhodamine (510 nm), and rhodamine (498 nm) [29, 30]. The absorption peaks corresponding to RhB completely disappeared after about 100 min. It suggests that Bi₂WO₆ nanoplates are the excellent photocatalytic activity.

Figure 7 shows degradation efficiency of the photocatalytic Bi₂WO₆ samples against RhB. It indicates the obvious difference in percent degradation of RhB by both Bi₂WO₆ samples. The control experiment in the absence of Bi₂WO₆ catalyst under identical visible irradiation was also carried out. The results show that photodegradation of RhB by Bi₂WO₆ nanoplates synthesized at 180°C for 20 h is higher than that by Bi₂WO₆ nanoplates synthesized at 180°C for 15 h, due to its higher degree of crystallinity. In case of both Bi₂WO₆ samples, the test for the degradation of RhB was very rapid until reaching 60 min. During photocatalysis, the visible light induced photocatalytic efficiency of the Bi₂WO₆ nanoplates synthesized at 180°C for 20 h (surface area of 53.1 m² g⁻¹) is 98.24% for RhB photodegradation. Comparing to the previous report, the photocatalytic activity of P25 TiO₂ is ~18% after 120 min under visible radiation with λ > 420 nm, reported by Cheng et al. [31]. Lu et al. [32] synthesized octahedron-like hierarchical structure of Bi₂WO₆ by a facile hydrothermal method. It shows a photodegradation of the RhB solution of 56% after the visible irradiation for 6 h. Thus, Bi₂WO₆ nanoplates show higher activities for degradation of RhB under visible light and are new candidate for visible-light-driven photocatalytic degradation of organic dyes.

The photodegradation phenomena of RhB by Bi₂WO₆ can be explained by e⁻/h⁺ recombination [33]. Generally, the e⁻/h⁺ recombination in the materials is divided into two categories: volume and surface recombination. The unique 2D layers of Bi₂WO₆ nanoplates supported the e⁻/h⁺ surface separation, caused by the abundant surface trapping sites and insufficient driving force for e⁻/h⁺ recombination. Thus, the highly photocatalytic efficiency of Bi₂WO₆ nanoplates was accelerated by the interfacial charged transfer process, which can play the role in the content and diffusion of adsorbed RhB. Their surfaces can be modified by the adsorption of some metallic atoms. In general, the e⁻/h⁺ recombination on the semiconductor surface is able to control with ease, because the nanosheets have large space to enhance the photochemical activity.

4. Conclusions

In this research, orthorhombic Bi₂WO₆ nanoplates as a photocatalyst were successfully synthesized by hydrothermal reaction at 180°C for 20 h in the solution with the pH of 10. The photocatalytic activity of Bi₂WO₆ nanoplates was determined to be 98.24% degradation of RhB for 100 min irradiated by Xe light.

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

Acknowledgment

The authors are extremely grateful to the Prince of Songkla University under Contact no. SCI560002S, Thailand.

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Journal of Nanomaterials

Hydrothermal Synthesis, Characterization, and Visible Light-Driven Photocatalytic Properties of Bi2WO6 Nanoplates

Abstract

1. Introduction

2. Experimental Procedures

3. Results and Discussion

4. Conclusions

Conflict of Interests

Acknowledgment

References

Copyright

Hydrothermal Synthesis, Characterization, and Visible Light-Driven Photocatalytic Properties of Bi₂WO₆ Nanoplates