Journal of Nanomaterials

Volume 2014, Article ID 341050, 7 pages

http://dx.doi.org/10.1155/2014/341050

## Fano Resonance of the Symmetry-Reduced Metal Bar Grating Structure

School of Physics and Electronic Science, Hunan University of Science and Technology, Xiangtan 411201, China

Received 4 March 2014; Accepted 9 August 2014; Published 16 October 2014

Academic Editor: Christian Brosseau

Copyright © 2014 Suxia Xie et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

#### Abstract

We demonstrate that Fano resonance and even multipole Fano resonance can be obtained in a symmetry-reduced structure composed of gold bars with different bar sizes or bar shapes on a layer of dielectric. There is a transparency window opened within the frequency region of the absorptive dipole resonance by metallic bars, as long as the narrow grating waveguide mode induced by reducing symmetry is coincided in spectrum with the dipole resonance such that a destructive interference happens between these two resonant modes. Line shape of the transmission spectra of the nanostructure can be modulated effectively by changing the size or shape of the series of metal bars. The results found can be useful in the design of novel optical device.

#### 1. Introduction

Fano resonance as a coherent phenomenon has emerged as a common characteristic of complex, coupled plasmon system [1]. This effect is important in the line shape engineering, and the frequency tunability of plasmonic nanosystems has been well established. Fano resonance can be obtained in materials with negative permeability () and positive dielectric permittivity (), even a material with negative refractive index, where both and are negative [2]. Fano resonance can also be obtained in anisotropic materials, where the intensity of the surface plasmon resonance can be greatly enhanced. Much of the original work on plasmonic Fano resonance was carried out on metallic arrays. The broad resonance providing the continuum for the narrow Fano resonance is a strongly radiative collective dipolar mode formed from a coupling of the plasmons on the individual array elements.

Metallic structures which lead to Fano resonance are divided into three kinds according to structure. The first are the plasmonic nanostructures such as dolmen-type slab arrangements [3], the nonconcentric ring/disk cavity [4–6], symmetry breaking ring/disk [7], and finite clusters of plasmonic nanoparticles [5, 8]. The second are the metallic photonic crystals; for example, an array of gold nanowires placed on a single-mode slab waveguide exhibits a Fano resonance in extinction in transverse electric polarization owing to coupling between the array and the waveguide. The last are the metamaterials. Fano resonance in metamaterials was observed for the first time in asymmetrically split-ring arrays [9]. Then polarization sensitive Fano resonance linked to strong optical activity and circular dichroism in the microwave and optical parts of the spectrum can be engaged through constructing a chiral arrangement of the metamaterial array with respect to the incident electromagnetic wave [10]. A Fano metamaterial with polarization-insensitive resonance, with behavior independent of incidence direction of light, has also been introduced [11]. Fano resonances have recently been observed in a superconducting metamaterial, promising extremely high-Q modes [12]. Fano resonance is associated with the coherent interference of “bright” and “dark” hybridized plasmon modes [1, 13–15]. Bright plasmon modes possess finite dipole moments, where their resonance is spectrally broadened due to radiative damping. In contrast, dark plasmon modes possess zero or nearly zero dipole moments, do not couple efficiently to light, and are therefore not broadened. The coupling between bright and dark plasmon modes occurs through the electromagnetic near-field and can be controlled using symmetry breaking [16–19]. As Fano resonances arise from the interference between two or more oscillators, they possess an inherent sensitivity to changes in geometry or local environment: small perturbations can induce dramatic resonance or line shape shifts. This property renders Fano resonant media particularly attractive for a range of applications, such as the development of chemical or biological sensors.

In this paper, we investigate a Fano resonance planar structure composed of a gold-bar grating placed on a dielectric layer. A distinct structure for the periodic gold grating proposed in this work is the symmetry-reduced arrangement. It is demonstrated that Fano resonance even multipole Fano resonance appears in the transmission spectrum, and there is a transparency window opened within the frequency region of the absorptive dipole resonance by metallic bars, as long as the narrow grating waveguide mode induced by reducing symmetry is coincided in spectrum with the dipole resonance such that a destructive interference happens between these two resonant modes. Line shape of the transmission spectra of the nanostructure can be modulated effectively by changing the size or shape of the series of metal bars. For example, little variation of any bar’s size and location in one lattice may lead to a transparency window in the transmission spectrum, and the width and wavelength of the transparency window can be modulated by each bar’s size and location in the lattice obviously. Additionally, more modulating factor is introduced by the hollow bar in the lattice; the introduction of the inner size of the metallic bar may lead the line shape of the transmission spectra to be modulated better. The results may be helpful for the design of new optical device.

#### 2. Material and Methods

The analyzed structure is presented in Figure 1. In our 2D FDTD calculations [20, 21], perfectly matched layer boundary conditions [22] are used at the top and bottom, and periodic boundary conditions are used on the left and right sides of the lattice due to the periodicity of the system. We simulate the structure with a computational window of nm × 2000 nm, where the structure in the direction is uniform and infinite. The structure is periodic and the periodicity is nm, and there are three gold bars contained in the lattice. We send a Gaussian single pulse of light with a wide frequency profile and an incidence angle of 90° illuminating the metal bar grating from the bottom of the lattice in the cross section. Parameters of the Au grating are denoted as the widths of the three bars in the lattice: , , , in which and are fixed as 100 nm. The shape of the middle bar can be set as a tube, and the inner size of the tube is denoted as . Gaps between the three bars are denoted as , . The offset of localization of the middle bar from the center of the lattice in direction is denoted as . The thickness of the dielectric under the Au bar array is fixed as nm, and relative permittivity is set as .

#### 3. Results and Discussions

For the symmetric grating array with identical bar size and bar gap, only the dipole plasmon resonance can be excited by incident waves, corresponding to only one transmission dip (as shown in Figure 2 ( nm)), additionally, there is only one transmission dip, whatever the bar size and gap size is. In contrast, it is interesting to find that there will be a transmission dip at a lower frequency around the dipole resonant transmission dip for the symmetry-reduced bar grating structure with size of the center bar of the lattice getting smaller or larger than the other two. The larger the size of the center bar deviates from the size of other bars, the more obvious the new transmission dip is. Along with offset of the size of the center bar increasing, the new transmission dip gets deeper, which means that its intensity gets stronger; meanwhile, its full width at half maximum gets larger. The new transmission dip with an asymmetrical shape can be attributed to the Fano resonance associated with the coupling of transversal surface plasmon resonance mode and localized surface plasmon resonance mode. In addition, with the increasing of size of center bar of the lattice, center frequency of the new transmission dip hardly moves, but the original transmission dip red shifts obviously accompanied by the increase of full width at half maximum. Besides, the transmission peak between two transmission dips becomes narrow, which forms into a transparency window, as an EIT-like phenomenon when the destructive interference happens between a broad resonance (dipole mode) and a narrow one (usually a subradiant mode). Here the subradiant mode resonance comes from the grating waveguide structure. When light is illuminated on the periodic metal nanobar grating, there is surface plasmon dipole mode excited, but there is no grating waveguide mode excited for the symmetric grating configuration with unified bar size and bar gap; however, the numerical result indicates that a symmetry-reduced periodic metal bar grating can make it an excitable mode, and this interesting asymmetry-induced resonance is in accordance with recent literatures [23–25]. Additionally, the dark mode excitation by the way of breaking or reducing symmetry can be feasible instead of the one by the plasmon-coupling excitation of a radiant resonant mode [26]. Besides, another shallow transmission dip appears at the higher frequency range, and its intensity gets stronger as the size of the center bar increases. This transmission dip may also be attributed to the Fano resonance. As a result, multiple Fano resonances can be obtained and modulated effectively by changing the size of one of the three bars in the lattice.

We also simulate the transmission characteristics of the metal grating structure as size varies of the side bars in the lattice (as shown in Figure 3). It is shown that the results are the same as those in Figure 2 absolutely.

Figure 4 shows the dependence of the transmission spectra of lattice containing 3 bars of a periodic bar array with localization of the center bar; when the center bar is set at the center between the left and the right bar, there is a wide transmission dip in the spectrum associated with the surface plasmon dipole mode. When the center bar moves along the direction, a new transmission dip appears at a lower frequency, which can be attributed to the Fano resonance. With the center bar of the lattice moving on, the Fano resonance mode and the original transmission dip gets wider, but central frequencies of both resonance modes do not shift obviously. Additionally, if the center bar moves further, higher multipolar surface modes can also interfere with the broad dipole mode and generate higher-order Fano resonances when the size of the middle metal bar is increased. In Figure 4, the appearance of the octupolar Fano resonance resulting from these higher order interactions is shown.

In Figure 5, the calculated transmission spectra of the lattice containing three metal bars with center bar a hollow tube are shown. It is shown that there is only one transmission dip (the dipole mode) of the inner size of the center bar less than 50 nm. The dipole mode transmission dip red shifts slowly when increases; for example, central frequency moves 0.0012 × 10^{14} Hz when inner size of tube rises from 50 nm to 80 nm. As the inner size of the tube increases when is small, the transmission dip moves much faster; it shifts rapidly for 0.1044 × 10^{14} Hz as inner size of tube increases from 80 nm to 90 nm when the inner size is large. As the inner size of the center bar increases, a new shallow transmission dip with an intensity appears (0.8663 at nm); with the inner size increasing continually, the new transmission dip intensity is enhanced dramatically (0.0514 at nm). Moreover, along with the inner tube size increasing, both the full width at half maximum and central frequency change quickly. Central frequencies of both transmission dips red shift obviously along with increasing; especially, the larger the size is, the faster the central frequency moves. For example, the central frequency moves from 3.3932 × 10^{14} Hz to 3.3056 × 10^{14} Hz by a 0.0876 × 10^{14} Hz, with the inner tube size rising from 85 nm to 90 nm. Additionally, the transparency window between the two transmission dips is associated with the EIT-like phenomenon. The central frequency of the transmission peak hardly moves around 3.4 × 10^{14} Hz with increasing with a value close to 1. Additionally, along with the increase of the inner tube size, there is new shallow transmission dip emerging at the higher frequency region, and it may also be attributed to the Fano resonance. So it is improved that Fano resosonance even multiple Fano resonance can be obtained in a periodic metal structure with a series hollow bars, which can be modulated effectively by the dimension of the inner bar size. It is shown in Figure 5 that the dipole mode transmission dip is widened along with the inner size of the tube in the lattice, and it is found that it gets narrow when increases from 85 nm to 90 nm. We can understand it like this: the dipole mode transmission dip red shifts with the inner size of the tube increasing, but the central frequency of the transmission peak between the new transmission dip and the original one stays at the same location all the time, which leads to the result that the left part of the dipole mode transmission dip red-shift is restricted, so the line width is narrowed. It is clear that the bright dipole mode can be transferred into the subradiant waveguiding mode as long as the grating symmetry is reduced, resulting in a transparency narrow band, as shown in the spectra between the dipole mode transmission dip and the Fano resonance (the new transmission dip at the left of the dipole mode) in Figures 2 and 5. It can be understood physically in this way that the destructive interference happens predominantly so that the electromagnetic energy of the dipole resonance is totally transferred to the grating waveguide resonance, which apparently contributes to the transparency window.

To explicitly verify the dipole resonance (transmission dip) and the symmetry-reduction induced Fano resonance (the new transmission dip), the resonant E-filed distributions are plotted. It is interesting to found that strong E-field distribution is localized between the bars for the symmetric gold bar array with unified bar size, bar gap, and bar shape, due to the standing wave induced of the dipole mode (as shown in Figure 6).

It can be obtained that dipole resonance is excited in the symmetry configuration with equal bar size and equal bar gap (as shown in Figure 6). In the symmetry-reduced configuration with the size or inner size of the middle bar increasing in the lattice, dipole modes distributions are changed, the intensity of the electric field localized around the metal bars is weakened dramatically (as shown in Figures 7 and 8), due to the standing wave induced in the structure, which is corresponding the red-shift of the transmission dip in Figures 2 and 5 in the symmetry reduced configuration.

When the plane wave is incident normally to the symmetric metal bar grating, the electric field distributions in the bar grating should have the same vector direction (in phase) and hence it does not excite the transversal grating waveguide mode. However, for the symmetry-reduced case the standing wave of the grating waveguide mode is excitable since the asymmetric bar sizes can break the synchronized phase of the plane wave impinging onto the metal surface; as a result, nodes of the transversal standing wave are formed. The waveguide mode interferes destructively with the channel of absorptive dipole resonance and consequently a transparency window is obtained, which comes from the low-loss nature for the grating modulated waveguiding mode within the dielectric layer. In other words, the Fano resonance mode emerging at the left of the dipole mode transmission dip may be attributed to the coupling of the dipole mode and the waveguide mode, which can be seen clearly in the field distributions in Figures 9 and 10.

#### 4. Conclusion

In conclusion, it is found that under the condition of reducing the grating symmetry by altering the size or shape of a series of metal bars in the nanostructure, Fano resonance or even multipole Fano resonance can be obtained in the transmission spectra. A transparency window associated with the EIT-like phenomenon is obtained between the dipole mode and the Fano resonance. Line shape of the transmission spectra of the nanostructure can be modulated effectively by changing the size or shape of the series of metal bars. The results may be helpful for the design of new optical device.

#### Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

#### Acknowledgments

This work was supported by National Natural Science Foundation of China (under Grant 11304094), Hunan Provincial Natural Science Foundation of China (under Grant 12JJB001), the Scientific Research Fund of Hunan Provincial Education Department (under Grant 13C322), the National Natural Science Foundation of China (under Grant 11247003), Hunan Provincial Department of Education Science Research Key Project of China (under Grant 12A045), Hunan University of Science and Technology Key Bidding Tesearch Topic (under Grant G31102), and Open Project of National Laboratory for Infrared Physics, Chinese Academy of Sciences (under Grant GJKF.20130027).

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