Anticorrosive Properties of Poly(o-phenylenediamine)/ZnO Nanocomposites Coated Stainless Steel

<table class="table-group" id="tab2"><tr><td><table class="table"><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr class="thead"><td align="left">EIS parameters</td><td align="center">Pure PoPd</td><td align="center">PoPd/ZnO nanocomposite</td></tr><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr><td align="left">Rs/<svg height="11.425" id="M35" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 12.9875 11.425" width="12.9875" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,11.363)"><path d="M719 146l-18 -146h-243l-5 18q2 4 17 25t24 36l25 42t26.5 52.5t21 56.5t16 65t5.5 68q0 121 -55.5 194.5t-149.5 73.5q-95 0 -150 -72t-55 -199q0 -54 18.5 -114t36.5 -94t48.5 -82.5t32.5 -51.5l-7 -18h-244l-17 146l27 1q17 -49 31.5 -62t45.5 -13h89l-21 21t-26 26.5
l-26 29t-28 35.5l-23 37.5t-20.5 43t-12 45.5t-5.5 51q0 133 88 218.5t219 85.5q132 0 218 -83t86 -218q0 -40 -11.5 -78t-33 -71.5t-39 -56t-44 -51t-32.5 -35.5h84q35 0 48 12t31 63z" id="x3A9"></path></g>
</svg> cm<sup>2</sup></td><td align="center">14.05</td><td align="center">10.44</td></tr><tr><td align="left">Rf/k<svg height="11.425" id="M36" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 12.9875 11.425" width="12.9875" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,11.363)"><path d="M719 146l-18 -146h-243l-5 18q2 4 17 25t24 36l25 42t26.5 52.5t21 56.5t16 65t5.5 68q0 121 -55.5 194.5t-149.5 73.5q-95 0 -150 -72t-55 -199q0 -54 18.5 -114t36.5 -94t48.5 -82.5t32.5 -51.5l-7 -18h-244l-17 146l27 1q17 -49 31.5 -62t45.5 -13h89l-21 21t-26 26.5
l-26 29t-28 35.5l-23 37.5t-20.5 43t-12 45.5t-5.5 51q0 133 88 218.5t219 85.5q132 0 218 -83t86 -218q0 -40 -11.5 -78t-33 -71.5t-39 -56t-44 -51t-32.5 -35.5h84q35 0 48 12t31 63z" id="x3A9"></path></g>
</svg> cm<sup>2</sup></td><td align="center">20.96</td><td align="center">8.38</td></tr><tr><td align="left">Rct/<svg height="11.425" id="M37" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 12.9875 11.425" width="12.9875" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,11.363)"><path d="M719 146l-18 -146h-243l-5 18q2 4 17 25t24 36l25 42t26.5 52.5t21 56.5t16 65t5.5 68q0 121 -55.5 194.5t-149.5 73.5q-95 0 -150 -72t-55 -199q0 -54 18.5 -114t36.5 -94t48.5 -82.5t32.5 -51.5l-7 -18h-244l-17 146l27 1q17 -49 31.5 -62t45.5 -13h89l-21 21t-26 26.5
l-26 29t-28 35.5l-23 37.5t-20.5 43t-12 45.5t-5.5 51q0 133 88 218.5t219 85.5q132 0 218 -83t86 -218q0 -40 -11.5 -78t-33 -71.5t-39 -56t-44 -51t-32.5 -35.5h84q35 0 48 12t31 63z" id="x3A9"></path></g>
</svg> cm<sup>2</sup></td><td align="center">507</td><td align="center">211.4</td></tr><tr><td align="left">Qf-<svg height="11.175" id="M38" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 11.6625 11.175" width="11.6625" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,11.113)"><path d="M667 650l-9 -28q-53 -5 -76 -17t-64 -59q-51 -61 -175 -225q-21 -29 -27 -55l-27 -136q-13 -65 -0.5 -80t83.5 -22l-7 -28h-280l8 28q64 4 81 19t30 83l25 128q6 35 -7 65l-98 231q-17 41 -32.5 52t-68.5 16l8 28h252l-6 -28l-40 -4q-27 -3 -33 -12.5t2 -31.5
q8 -26 43 -107.5t61 -134.5q114 145 174 240q14 24 8 33t-37 13l-34 4l8 28h238z" id="x1D44C"></path></g>
</svg> (<svg height="12.175" id="M39" style="vertical-align:-2.29482pt" version="1.1" viewbox="0 0 9.5625 12.175" width="9.5625" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,7.675)"><path d="M538 96q-38 -45 -84 -76.5t-71 -31.5q-44 0 -15 117q12 49 18 89h-2q-99 -128 -163 -178q-36 -28 -70 -28q-26 0 -44 38h-2q-16 -69 -16 -129q0 -43 11 -75.5t24 -42.5l1 -6q-7 -12 -24.5 -23t-37.5 -11q-40 0 -40 76q0 52 35 202l94 407l78 24l5 -5q-32 -122 -72 -310
q-7 -33 0 -55t25 -22q36 0 105.5 75t107.5 145l32 146l75 26h10q-50 -197 -78 -347q-7 -38 6 -38q7 0 31 17t47 39z" id="x1D707"></path></g>
</svg>F cm<sup>−2</sup>)</td><td align="center">145.6</td><td align="center">210.7</td></tr><tr><td align="left">Qf-<svg height="11.825" id="M40" style="vertical-align:-3.13504pt" version="1.1" viewbox="0 0 14.9875 11.825" width="14.9875" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,7.675)"><path d="M495 86q-46 -47 -87 -72.5t-63 -25.5q-43 0 -16 107l49 210q7 34 8 50.5t-3 21t-13 4.5q-35 0 -109.5 -72.5t-115.5 -140.5q-21 -75 -38 -159q-50 -10 -76 -21l-6 8l84 340q8 35 -4 35q-17 0 -67 -46l-15 26q44 44 85.5 70.5t64.5 26.5q35 0 10 -103l-24 -98h2
q42 56 97 103.5t96 71.5q46 26 74 26q9 0 16 -2.5t14 -11.5t9.5 -24.5t-1 -44t-13.5 -68.5q-30 -117 -47 -200q-4 -19 -3.5 -25t6.5 -6q21 0 70 48z" id="x1D45B"></path></g>
<g transform="matrix(.012,-0,0,-.012,8.6,11.762)"><path d="M384 0h-275v27q67 5 81.5 18.5t14.5 68.5v385q0 38 -7.5 47.5t-40.5 10.5l-48 2v24q85 15 178 52v-521q0 -55 14.5 -68.5t82.5 -18.5v-27z" id="x31"></path></g>
</svg></td><td align="center">0.945</td><td align="center">0.894</td></tr><tr><td align="left">Qdl-<svg height="11.175" id="M41" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 11.6625 11.175" width="11.6625" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,11.113)"><path d="M667 650l-9 -28q-53 -5 -76 -17t-64 -59q-51 -61 -175 -225q-21 -29 -27 -55l-27 -136q-13 -65 -0.5 -80t83.5 -22l-7 -28h-280l8 28q64 4 81 19t30 83l25 128q6 35 -7 65l-98 231q-17 41 -32.5 52t-68.5 16l8 28h252l-6 -28l-40 -4q-27 -3 -33 -12.5t2 -31.5
q8 -26 43 -107.5t61 -134.5q114 145 174 240q14 24 8 33t-37 13l-34 4l8 28h238z" id="x1D44C"></path></g>
</svg>(<svg height="12.175" id="M42" style="vertical-align:-2.29482pt" version="1.1" viewbox="0 0 9.5625 12.175" width="9.5625" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,7.675)"><path d="M538 96q-38 -45 -84 -76.5t-71 -31.5q-44 0 -15 117q12 49 18 89h-2q-99 -128 -163 -178q-36 -28 -70 -28q-26 0 -44 38h-2q-16 -69 -16 -129q0 -43 11 -75.5t24 -42.5l1 -6q-7 -12 -24.5 -23t-37.5 -11q-40 0 -40 76q0 52 35 202l94 407l78 24l5 -5q-32 -122 -72 -310
q-7 -33 0 -55t25 -22q36 0 105.5 75t107.5 145l32 146l75 26h10q-50 -197 -78 -347q-7 -38 6 -38q7 0 31 17t47 39z" id="x1D707"></path></g>
</svg>F cm<sup>−2</sup>)
					 </td><td align="center">636</td><td align="center">2148</td></tr><tr><td align="left">Qdl-<svg height="11.825" id="M43" style="vertical-align:-3.13504pt" version="1.1" viewbox="0 0 14.9875 11.825" width="14.9875" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,7.675)"><path d="M495 86q-46 -47 -87 -72.5t-63 -25.5q-43 0 -16 107l49 210q7 34 8 50.5t-3 21t-13 4.5q-35 0 -109.5 -72.5t-115.5 -140.5q-21 -75 -38 -159q-50 -10 -76 -21l-6 8l84 340q8 35 -4 35q-17 0 -67 -46l-15 26q44 44 85.5 70.5t64.5 26.5q35 0 10 -103l-24 -98h2
q42 56 97 103.5t96 71.5q46 26 74 26q9 0 16 -2.5t14 -11.5t9.5 -24.5t-1 -44t-13.5 -68.5q-30 -117 -47 -200q-4 -19 -3.5 -25t6.5 -6q21 0 70 48z" id="x1D45B"></path></g>
<g transform="matrix(.012,-0,0,-.012,8.6,11.762)"><path d="M412 140l28 -9q0 -2 -35 -131h-373v23q112 112 161 170q59 70 92 127t33 115q0 63 -31 98t-86 35q-75 0 -137 -93l-22 20l57 81q55 59 135 59q69 0 118.5 -46.5t49.5 -122.5q0 -62 -29.5 -114t-102.5 -130l-141 -149h186q42 0 58.5 10.5t38.5 56.5z" id="x32"></path></g>
</svg></td><td align="center">1.00</td><td align="center">0.759</td></tr><tr class="table-tr"><td colspan="3"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Impedance parameters for pure PoPd and PoPd/ZnO nanocomposite.

Journal of Nanomaterials

tab2

Table 2

Table 2: Anticorrosive Properties of Poly(o-phenylenediamine)/ZnO Nanocomposites Coated Stainless Steel 