Nanocatalysts for Hydrogen Generation from Ammonia Borane and Hydrazine Borane

Table 1

Catalytic performance of metal nanocatalysts for hydrogen generation from hydrazine borane (HB).

Catalysts	Temperature (°C)	𝑛(H2 + N2)/𝑛HB	Reference
RhCl3 precatalyst	25	2.93	[4]
RuCl3 precatalyst	25	~2.9	[4]
Rh NPs/Al2O3	25	~2.6	[4]
Ru NPs/Al2O3	25	~2.7	[4]
Rh NPs/hydroxyapatite	25	3	[101]
Ni NPs/PSSMA	25	2.6~3	[102]
NiCl2 precatalyst	25	3	[103]
Ni NPs/CTAB	50	~3.1	[5]
Pt NPs/CTAB	50	3	[5]
Ru NPs/CTAB	50	3.30±0.05	[104]
Rh NPs/CTAB	50	3.30±0.05	[104]
Ir NPs/CTAB	50	2.25±0.05	[104]
Ni0.97Pt0.03 NPs/CTAB	50	5.07±0.05	[5]
Ni0.89Pt0.11 NPs/CTAB	50	5.79±0.05	[5]
Ni0.77Pt0.23 NPs/CTAB	50	5.29±0.05	[5]
Ni0.89Rh0.11 NPs/CTAB	50	5.1±0.05	[104]
Ni0.89Ir0.11 NPs/CTAB
Ni0.77Ru0.23 NPs/CTAB	50	4±0.05	[104]
RhCl3 precatalyst	50	4.1	[105]
RuCl3 precatalyst	50	3.3	[105]
IrCl3 precatalyst
Rh NPs/CTAB	50	4.4±0.2	[106]
Ni NPs/CTAB	50	3.5±0.1	[106]
Rh4Ni NPs/CTAB	50	5.8±0.2	[106]
Ni@(RhNi-alloy)/Al2O3	50	5.74±0.2	[107]
Ni15Rh-alloy/Al2O3	50	~4.15	[107]