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Journal of Nanomaterials
Volume 2015, Article ID 171545, 9 pages
Research Article

Enhancement of Gas Sensing Characteristics of Multiwalled Carbon Nanotubes by CF4 Plasma Treatment for SF6 Decomposition Component Detection

1State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing 400044, China
2School of Electrical Engineering, Wuhan University, Wuhan 430072, China
3Central Southern China Electric Power Design Institute, Wuhan 430071, China

Received 2 July 2014; Accepted 30 November 2014

Academic Editor: Myoung-Woon Moon

Copyright © 2015 Xiaoxing Zhang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


H2S and SO2 are important gas components of decomposed SF6 of partial discharge generated by insulation defects in gas-insulated switchgear (GIS). Therefore, H2S and SO2 detection is important in the state evaluation and fault diagnosis of GIS. In this study, dielectric barrier discharge was used to generate CF4 plasma and modify multiwalled carbon nanotubes (MWNTs). The nanotubes were plasma-treated at optimum discharge conditions under different treatment times (0.5, 1, 2, 5, 8, 10, and 12 min). Pristine and treated MWNTs were used as gas sensors to detect H2S and SO2. The effects of treatment time on gas sensitivity were analyzed. Results showed that the sensitivity, response, and recovery time of modified MWNTs to H2S were improved, but the recovery time of SO2 was almost unchanged. At 10 min treatment time, the MWNTs showed good stability and reproducibility with better gas sensing properties compared with the other nanotubes.