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Journal of Nanomaterials
Volume 2015, Article ID 215371, 10 pages
http://dx.doi.org/10.1155/2015/215371
Research Article

CaCl2-Accelerated Hydration of Tricalcium Silicate: A STXM Study Combined with 29Si MAS NMR

1School of Transportation Science and Engineering, Harbin Institute of Technology, Harbin 150090, China
2Department of Civil and Environmental Engineering, University of California at Berkeley, Berkeley, CA 94720, USA
3Faculty of Science and Technology, Tokyo University of Science, 2641 Yamasaki, Noda, Chiba 278-8510, Japan

Received 20 August 2015; Revised 5 November 2015; Accepted 16 November 2015

Academic Editor: Jin-Ho Choy

Copyright © 2015 Qinfei Li et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. J. Thomas, A. J. Allen, and H. M. Jennings, “Hydration kinetics and microstructure development of normal and CaCl2-accelerated tricalcium silicate pastes,” Journal of Physical Chemistry C, vol. 113, no. 46, pp. 19836–19844, 2009. View at Publisher · View at Google Scholar · View at Scopus
  2. M. C. G. Juenger, P. J. M. Monteiro, E. M. Gartner, and G. P. Denbeaux, “A soft X-ray microscope investigation into the effects of calcium chloride on tricalcium silicate hydration,” Cement and Concrete Research, vol. 35, no. 1, pp. 19–25, 2005. View at Publisher · View at Google Scholar · View at Scopus
  3. P. K. Mehta and P. J. M. Monteiro, Concrete: Microstructure, Properties, and Materials, McGraw-Hill, New York, NY, USA, 4th edition, 2014.
  4. V. K. Peterson and A. E. Whitten, “Hydration processes in tricalcium silicate: application of the boundary nucleation model to quasielastic neutron scattering data,” Journal of Physical Chemistry C, vol. 113, no. 6, pp. 2347–2351, 2009. View at Publisher · View at Google Scholar · View at Scopus
  5. E. M. Gartner, J. F. Young, D. A. Damidot, and I. Jawed, “Hydration of portland cement,” in The Structure and Performance of Cements, J. Bensted and P. Barnes, Eds., chapter 3, Spon Press, London, UK, 2nd edition, 2002. View at Google Scholar
  6. M. C. G. Juenger and H. M. Jennings, “The use of nitrogen adsorption to assess the microstructure of cement paste,” Cement and Concrete Research, vol. 31, no. 6, pp. 883–892, 2001. View at Publisher · View at Google Scholar · View at Scopus
  7. J. Skalny, I. Odler, and J. Hagymassy Jr., “Pore structure of hydrated calcium silicates. I. Influence of calcium chloride on the pore structure of hydrated tricalcium silicate,” Journal of Colloid And Interface Science, vol. 35, no. 3, pp. 434–440, 1971. View at Publisher · View at Google Scholar · View at Scopus
  8. E. M. Gartner, K. E. Kurtis, and P. J. M. Monteiro, “Proposed mechanism of C-S-H growth tested by soft X-ray microscopy,” Cement and Concrete Research, vol. 30, no. 5, pp. 817–822, 2000. View at Publisher · View at Google Scholar · View at Scopus
  9. V. S. Ramachandran and R. F. Feldman, “Time-dependent and intrinsic characteristics of portland cement hydrated in the presence of calcium chloride,” Il Cemento, vol. 3, 1978. View at Google Scholar
  10. A. M. Rosenberg, “Study of the mechanism through which calcium chloride accelerates the set of portland cement,” Journal of American Concrete Institute, vol. 61, pp. 1261–1269, 1964. View at Google Scholar
  11. G. W. Groves, P. J. Le Sueur, and W. Sinclair, “Transmission electron microscopy and microanalytical studies of ion-beam-thinned sections of tricalcium silicate paste,” Journal of the American Ceramic Society, vol. 69, no. 4, pp. 353–356, 1986. View at Publisher · View at Google Scholar · View at Scopus
  12. K. E. Kurtis, P. J. M. Monteiro, J. T. Brown, and W. Meyer-Ilse, “High resolution transmission soft X-ray microscopy of deterioration products developed in large concrete dams,” Journal of Microscopy, vol. 196, no. 3, pp. 288–298, 1999. View at Publisher · View at Google Scholar · View at Scopus
  13. K. E. Kurtis, P. J. M. Monteiro, J. T. Brown, and W. Meyer-Ilse, “Imaging of ASR gel by soft X-ray microscopy,” Cement and Concrete Research, vol. 28, no. 3, pp. 411–421, 1998. View at Publisher · View at Google Scholar · View at Scopus
  14. J. Ha, S. Chae, K. W. Chou, T. Tyliszczak, and P. J. M. Monteiro, “Effect of polymers on the nanostructure and on the carbonation of calcium silicate hydrates: a scanning transmission X-ray microscopy study,” Journal of Materials Science, vol. 47, no. 2, pp. 976–989, 2012. View at Publisher · View at Google Scholar · View at Scopus
  15. J. Ha, S. Chae, K. W. Chou, T. Tyliszczak, and P. J. M. Monteiro, “Scanning transmission X-ray microscopic study of carbonated calcium silicate hydrate,” Transportation Research Record, vol. 2142, pp. 83–88, 2010. View at Publisher · View at Google Scholar · View at Scopus
  16. S. R. Chae, J. Moon, S. Yoon et al., “Advanced nanoscale characterization of cement based materials using X-ray synchrotron radiation: a review,” International Journal of Concrete Structures and Materials, vol. 7, no. 2, pp. 95–110, 2013. View at Publisher · View at Google Scholar
  17. P. J. M. Monteiro, L. Clodic, F. Battocchio et al., “Incorporating carbon sequestration materials in civil infrastructure: a micro and nano-structural analysis,” Cement and Concrete Composites, vol. 40, pp. 14–20, 2013. View at Publisher · View at Google Scholar · View at Scopus
  18. D. Hernández-Cruz, C. W. Hargis, S. Bae et al., “Multiscale characterization of chemical—mechanical interactions between polymer fibers and cementitious matrix,” Cement and Concrete Composites, vol. 48, pp. 9–18, 2014. View at Publisher · View at Google Scholar · View at Scopus
  19. S. Yoon, J. Ha, S. R. Chae, D. A. Kilcoyne, and P. J. M. Monteiro, “X-ray spectromicroscopic study of interactions between NaCl and calcium silicate hydrates,” Magazine of Concrete Research, vol. 66, no. 3, pp. 141–149, 2014. View at Publisher · View at Google Scholar · View at Scopus
  20. G. Johansson, J. Dynes, A. Hitchcock, T. Tyliszczak, G. Swerhone, and J. Lawrence, “Chemically sensitive tomography at 50 nm spatial resolution using a soft X-ray scanning transmission X-ray microscope,” Microscopy and Microanalysis, vol. 12, supplement S02, pp. 1412–1413, 2006. View at Google Scholar
  21. Z. Yangquanwei, S. Neethirajan, and C. Karunakaran, “Cytogenetic analysis of quinoa chromosomes using nanoscale imaging and spectroscopy techniques,” Nanoscale Research Letters, vol. 8, no. 1, article 463, 7 pages, 2013. View at Publisher · View at Google Scholar · View at Scopus
  22. S. Bae, R. Taylor, D. Hernández-Cruz, S. Yoon, D. Kilcoyne, and P. J. M. Monteiro, “Soft X-ray spectromicroscopic investigation of synthetic C-S-H and C3S hydration products,” Journal of the American Ceramic Society, vol. 98, no. 9, pp. 2914–2920, 2015. View at Publisher · View at Google Scholar
  23. A. L. D. Kilcoyne, T. Tyliszczak, W. F. Steele et al., “Interferometer-controlled scanning transmission X-ray microscopes at the Advanced Light Source,” Journal of Synchrotron Radiation, vol. 10, no. 2, pp. 125–136, 2003. View at Publisher · View at Google Scholar · View at Scopus
  24. S. J. Naftel, T. K. Sham, Y. M. Yiu, and B. W. Yates, “Calcium l-edge XANES study of some calcium compounds,” Journal of Synchrotron Radiation, vol. 8, no. 2, pp. 255–257, 2001. View at Publisher · View at Google Scholar · View at Scopus
  25. F. M. F. de Groot, J. C. Fuggle, B. T. Thole, and G. A. Sawatzky, “2p x-ray absorption of 3d transition-metal compounds: an atomic multiplet description including the crystal field,” Physical Review B: Condensed Matter and Materials Physics, vol. 42, no. 9, pp. 5459–5468, 1990. View at Publisher · View at Google Scholar
  26. R. T. DeVol, R. A. Metzler, L. Kabalah-Amitai et al., “Oxygen spectroscopy and polarization-dependent imaging contrast (PIC)-mapping of calcium carbonate minerals and biominerals,” Journal of Physical Chemistry B, vol. 118, no. 28, pp. 8449–8457, 2014. View at Publisher · View at Google Scholar · View at Scopus
  27. T. Nagai, T. Ito, T. Hattori, and T. Yamanaka, “Compression mechanism and amorphization of portlandite, Ca(OH)2: structural refinement under pressure,” Physics and Chemistry of Minerals, vol. 27, no. 7, pp. 462–466, 2000. View at Publisher · View at Google Scholar · View at Scopus
  28. H. W. F. Taylor, Cement Chemistry, Thomas Telford, London, UK, 2nd edition, 1997.
  29. D. Li, G. M. Bancroft, M. E. Fleet, and X. H. Feng, “Silicon K-edge XANES spectra of silicate minerals,” Physics and Chemistry of Minerals, vol. 22, no. 2, pp. 115–122, 1995. View at Publisher · View at Google Scholar · View at Scopus
  30. J. J. Thomas, H. M. Jennings, and J. J. Chen, “Influence of nucleation seeding on the hydration mechanisms of tricalcium silicate and cement,” Journal of Physical Chemistry C, vol. 113, no. 11, pp. 4327–4334, 2009. View at Publisher · View at Google Scholar · View at Scopus
  31. N. B. Singh and P. N. Ojha, “Effect of CaCl2 on the hydration of tricalcium silicate,” Journal of Materials Science, vol. 16, no. 10, pp. 2675–2681, 1981. View at Publisher · View at Google Scholar · View at Scopus
  32. J. F. Young, R. L. Berger, and F. V. Lawrence Jr., “Studies on the hydration of tricalcium silicate pastes III. Influence of admixtures on hydration and strength development,” Cement and Concrete Research, vol. 3, no. 6, pp. 689–700, 1973. View at Publisher · View at Google Scholar · View at Scopus
  33. J. J. Beaudoin, L. Raki, and R. Alizadeh, “A 29Si MAS NMR study of modified C-S-H nanostructures,” Cement and Concrete Composites, vol. 31, no. 8, pp. 585–590, 2009. View at Publisher · View at Google Scholar · View at Scopus
  34. M. Chloup-Bondant and O. Evrard, “Tricalcium aluminate and silicate hydration. Effect of limestone and calcium sulfate,” in Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials, P. Colombet, H. Zanni, A.-R. Grimmer, and P. Sozzani, Eds., pp. 295–308, Springer, Berlin, Germany, 1998. View at Google Scholar
  35. S. A. Rodger, G. W. Groves, N. J. Clayden, and C. M. Dobson, “Hydration of tricalcium silicate followed by 29Si NMR with cross-polarization,” Journal of the American Ceramic Society, vol. 71, no. 2, pp. 91–96, 1988. View at Publisher · View at Google Scholar · View at Scopus
  36. M. Mägi, E. Lippmaa, A. Samoson, G. Engelhardt, and A.-R. Grimmer, “Solid-state high-resolution silicon-29 chemical shifts in silicates,” Journal of Physical Chemistry, vol. 88, no. 8, pp. 1518–1522, 1984. View at Publisher · View at Google Scholar · View at Scopus
  37. C. E. Tambelli, J. F. Schneider, N. P. Hasparyk, and P. J. M. Monteiro, “Study of the structure of alkali-silica reaction gel by high-resolution NMR spectroscopy,” Journal of Non-Crystalline Solids, vol. 352, no. 32–35, pp. 3429–3436, 2006. View at Publisher · View at Google Scholar · View at Scopus
  38. R. J. Myers, S. A. Bernal, R. San Nicolas, and J. L. Provis, “Generalized structural description of calcium-sodium aluminosilicate hydrate gels: the cross-linked substituted tobermorite model,” Langmuir, vol. 29, no. 17, pp. 5294–5306, 2013. View at Google Scholar