Research Article | Open Access
Tran Kim Anh, Pham Thi Minh Chau, Nguyen Thi Quy Hai, Le Quoc Minh, "Cathodo-, Thermo-, and Photoluminescent Properties of Nano-Y2O3:Eu3+ Fabricated by Controlled Combustion Synthesis", Journal of Nanomaterials, vol. 2015, Article ID 637124, 7 pages, 2015. https://doi.org/10.1155/2015/637124
Cathodo-, Thermo-, and Photoluminescent Properties of Nano-Y2O3:Eu3+ Fabricated by Controlled Combustion Synthesis
Y2O3:Eu3+ nanophosphors were prepared through combustion reaction under controlled condition of the fuel ethylenediaminetetraacetic acid (EDTA-Na2) and in the temperature range from 350 to 700°C. The products were characterized by X-ray diffraction (XRD), field emission scattering electron microscopy (FESEM), and energy dispersive spectroscopy (EDS). The results showed that Y2O3:Eu3+ nanoparticles were successfully synthesized by combustion method at low temperature and in short reaction time. The light-emitting ability of Y2O3:Eu3+ nanoparticles upon the electron excitation has been studied at the potentials 5, 10, and 15 kV. The thermoluminescent glow curves have elucidated an intense peak at 117°C after UV exposure and at least two peaks at 125 and 336°C with Gamma irradiation. Photoluminescent spectra of Y2O3:Eu3+ nanoparticles exhibited strong red luminescent color with highest sharp band at 612 nm under excitation in ultraviolet at 254, 394 and in visible at 465 nm. The dependence of photoluminescent properties of Y2O3:Eu3+ nanoparticles on annealing temperature and concentration of Eu3+ was also studied.
Light emitting under electromagnetic fields exposure of the nanoparticles based on oxide yttrium (Y2O3) doped lanthanide (Ln) ions are become the promising way that open new opportunities for the application in various fields of electronics, optics and also biomedicine . Yttrium oxide is a well-known host for transition metals and various lanthanide ions due to large band gap (5.8 eV), high dielectric constant, high thermal stability, and low cut-off phonon energy (380 cm−1). The light emission efficiency of the nanomaterials based on Y2O3 doped with rare earth ions (Y2O3:Ln3+) depends on the physical properties such as surface morphology , crystalline structures , and distribution of activator in matrix [4, 5]. High luminescence efficiency, long term thermal stability, high mechanical resistance, very good refractory properties, and chemical stability are interesting properties of Y2O3:Ln3+ . Among them nano-Y2O3:Eu3+ has a great interest for application not only in the field emission display  and security printing  for electroluminescence , but also in biomedicine . Nanoparticles synthesized by different methods show variation in their size, shape, and optical properties. To enhance the brightness and resolution of display of present technology, Y2O3:Ln3+ nanostructures of different morphologies have been synthesized by using sol-gel process [7, 10, 11], solvothermal [3, 12], hydrothermal [13, 14], colloidal and coprecipitation [15, 16], thermal and laser decomposition [17, 18], microwave , and combustion synthesis [7, 20–22]. Particularly, the combustion method has advantages due to its simplicity in nature and very short synthesis time. However, it is very important to develop phosphors nano-Y2O3:Eu3+ with controlled morphology and in particular the site-selectivity and relative behavior of the strongest 5D0-7F2 (red) transition from Eu3+ needs to be further investigated for strong red phosphor application in the different fields.
In the present work Y2O3:Eu3+ nanoparticles were prepared by combustion method with EDTA-Na2 and with urea for comparison. The structural and morphological properties were studied by using XRD, FESEM, and EDS. The cathodoluminescent (CL) and thermoluminescent (TL) properties of nano-Y2O3:Eu3+ have been investigated to explore the application potential in display or dosimeter. The photoluminescent properties of the fabricated Y2O3:Eu3+ have been characterized by photoluminescence (PL) spectra and photoluminescence excitation (PLE) spectra to search for a novel red stronger luminescent nanophosphor based on Y2O3:Eu3+ to develop labeling or imaging tool in biomedicine.
The sample was prepared by combustion method reported in . All chemicals are of analytical grade. Yttrium oxide (99,99%, ALFA), europium oxide (99,95%, CERAC), nitric acid (99%, Sigma-Aldrich), EDTA-Na2 (99%, Sigma), and urea (99.5%, Merck) were used as starting materials and fuels to prepare Y2O3:Eu3+. Stoichiometric amounts of yttrium and europium oxides were dissolved in aqueous nitric acid 1 : 1 ratio. The solution was heated to 100°C on hot plate while being vigorously stirred until the solution became transparent. The reaction solution was dried at 70°C for 3 hours to remove the excess nitric acid and water. After cooling down to room temperature, the dried rare earth salts were mixed with small amount of EDTA-Na2 in deionized water and vigorously stirred for 1 hour to form clear solution. Sealed containers with freshly prepared solution were then placed into an electrical oven heated up to 105°C for 1 hour. After that the containers were moved to Muffle furnace whose temperature was maintained at 350°C for 2 min and raised to 600°C for 3 min. The combustion process was completed in about 6–10 min. After completion of heating process the furnace cooled down to the room temperature. The fabricated compound was collected and washed with deionized water and ethanol and filtered to the ultimate white product, which was dried in vacuum at 70°C for 15 h to obtain Y2O3:Eu3+ fine powder. The obtained samples were foamy, fluffy, and porous.
The samples were checked by the X-ray diffractometer (XRD) Model Bruckner D8-Advance using Cu Kα, 40 kv, 20 mA. CL spectra, image, and EDS of Y2O3:Eu3+ were measured by field emission scattering electron microscope (FESEM) F 6400 JEOL. The PLE spectra and PL spectra of as-prepared and annealed samples were recorded using Spectrophotometer Model FL3-22 HORIBA with double monochromator, photomultiplier, appropriate lens and filters, and equipment NanoLog iHR 320 HORIBA Jobin Yvon. The samples preparation technique and measurement condition for luminescent intensities have been maintained throughout the entire experiment work. Therefore PL intensity results of the as-prepared or the annealing samples of Y2O3:Eu3+ could be compared precisely. The TL glow curves of Y2O3:Eu3+ were obtained in the temperature range of 50–450°C. The TL glow curves of Y2O3:Eu3+ were recorded with a homemade TL setup consisting of a small metallic plate heating strip, temperature programmer, photomultiplier tube, and multimeter recorder at heating rate of 2°Cs−1. The TL glow curves obtained above were figured on using Origin software.
3. Results and Discussion
The powder XRD patterns of Y2O3:5 mol% Eu3+ sample, which was prepared by combustion method with EDTA-Na2 as fuel, annealed at 700°C, are shown in Figure 1. The appearance of all prominent diffraction peaks of the planes , , , , , , , and corresponding to cubic form of yttrium oxide is in agreement with the JCPD41-1105. The particle sizes of these materials were estimated and found to be in the range of 24 nm for ~350°C and 26 nm for 700°C annealed sample. The obtained data were calculated by using the Scherrer equation .
These calculated particles sizes were in good agreement with those from FESEM images shown in Figure 2. This indicates the spatial structure, fluffy nature with pores, and voids with loosely agglomerated particles. The morphology of the synthesized samples depends on the nature and concentration of EDTA-Na2 or urea as organic fuel. During combustion, yttrium nitrate impregnates into the amorphous product and gets ignited. Heat dissipates by the evolution of gaseous products in minimization and thus it leads to localization of heat due to amorphous nature of the fuel. Further increasing to about 800°C for 2 hours did not much affect the morphology with particles still having a large degree of porosity and agglomeration .
These estimated particles sizes of Y2O3:5 mol% Eu3+ prepared by combustion reaction in using EDTA-Na2 as fuel were greater than those of Y2O3:5 mol% Eu3+ synthesized with urea CO(NH2)2 . During the reaction process the reaction mixture underwent thermal dehydration and ignited at one spot with liberation of gaseous products such as oxides of nitrogen and carbon. The gaseous products during combustion reaction were liberated which increased surface area of powder products . For the reaction mixture of EDTA-Na2 need without further of any external heating. The heat of reaction is sufficient for decomposition of the mixture and resulted in the formation of particles. The combustion with urea can be controlled rate of the decomposition that would result in formation of particles with a small size and uniform distribution .
Figure 3 shows EDS spectrum of Y2O3:3 mol% Eu3+ sample, which shows that the product consists of the elements Y, O, and Eu. The EDS result in Figure 2 confirms the fabricated products were Y2O3 doped with Eu3+ ions. Figure 4 presents EDS layered image of Y2O3:3 mol% Eu3+ sample, in which the position of ions yttrium (green), oxygen (yellow), and europium (red dot) on yttrium oxide nanoparticles Y2O3 can be recognized. Based on these EDS spectra it can be considered that Eu3+ ions were distributed rather regularly on the particles of yttrium oxide doped europium ions.
Nanophosphors are efficient luminescent materials and irreplaceable components of light-emitting devices like cathode ray tubes, plasma display panels, and field emission display . The last ones have been recognized as one of the most promising technologies due to their most important features like great brightness, wide horizontal and vertical view angels, good contrast ration, and wide work temperature range. One of the most promising solutions is lanthanide doped oxides, garnets, and some perovskites [27–29]. Therefore we have studied the light-emitting ability of Y2O3:Eu3+ nanoparticles upon the electron excitation. CL spectra were measured by F 6400 JEOL system, which were observed upon the different potentials of 5, 10, and 15 kV in high vacuum of 10−7 mmHg. In Figure 5 are presented the CL spectra of Y2O3:3 mol% Eu3+ samples and it is indicated that our samples have strong CL intensity even at low doping concentration of 3 mol% Eu3+. These results have indicated that the obtained Y2O3:Eu3+ can be applied for display technology.
Recent studies on different luminescent nanomaterials have shown a potential application in dosimeter of ionizing radiation for measurements of high doses using the TL technique [21, 30]. RE3+ doped Y2O3 material is one of such promising materials and some attention has been paid to study its TL characteristics. In 1996 Yeh and Su have reported the possible use of rare earth doped oxide phosphor in UV light dosimeter and found that Y2O3:Eu3+ is sensitive enough to measure background UV radiation such as sun light and bulb light . Therefore they have investigated the TL behavior of Y2O3:Eu3+ after UV exposure. In this report the primary results of TL glow curves of Y2O3:5 mol% Eu3+ after UV exposure and Gamma irradiation are presented for comparison.
The Y2O3:Eu3+ samples were irradiated with D2 Lampe for 1 min and with a Gamma source for 75 h, and then their TL glow curves were recorded. The TL glow curve of Y2O3:5 mol% Eu3+ after UV irradiation was measured from 50°C to 400°C with the heating rate 2°C/sec. These TL glow curves were figured on using Origin software and one intense peak that appeared at 117°C was well resolved as can be seen in Figure 6. In the case of Gamma ray irradiation, the TL glow curves of Y2O3:Eu3+ sample for a dose of 9 mSv and exposure time 75 h, at least one prominent TL glow peak at 336°C was found (Figure 7). Tamrakar indicated that the TL glow curve of UV irradiated sample RE doped nanophosphor shows the formation of shallow trap (surface trapping) and the Gamma irradiated sample shows the formation of deep trapping [32, 33]. The estimation of trap formation was evaluated by knowledge of trapping parameters. The trapping parameters such as activation energy, order of kinetics, and frequency factor were calculated by peak shape method. Here most of the peak shows second order of kinetics. It is possible in UV irradiated Y2O3:Eu3+ phosphors that the TL response mainly generates from the traps on surface. Since these radiations cannot penetrate deeper and hence will not induce lattice defects may be caused by the trapped carriers which are produced during the sample processing.
In order to study the influence of excitation energy, the sample Y2O3 doped with 3 mol%, 5 mol% Eu3+ synthesized in using EDTA-Na2 was excited by different wavelengths of 254, 465, and 394 nm from HORIBA system. All the samples showed strong PL emission with peak maximum at 612 nm under an excitation wavelength of 254 nm (Figure 8). We can note that the emission intensity when excited by the 254 nm wavelength was 1.6 times stronger than excitation by 394 nm. The spectra structure showed characteristic optical properties of Eu3+ ions in the cubic Y2O3 host . The emission spectra lines of Eu3+ ion are shaped which is due to the screening of 4f orbital by 5s and 5d orbital from crystal field of the host lattice. The spectra have series of peaks well agreeing with the report values of Eu3+ emission transition [1, 3, 4]. Figure 9 shows the PL emission spectra of 5 mol% Eu3+ doped Y2O3 samples prepared by combustion method with different fuels: (1) urea and (2) EDTA-Na2. It can be seen in the combustion synthesis with EDTA-Na2 at temperature 350°C that the luminescent intensity of samples increased by near three orders in comparison with that of samples prepared by using urea. This may be due to the formation of well-crystallized cubic yttrium oxide phase [15, 34, 35].
The peaks at 582, 588, 590, 600, 612, and 632 nm are corresponding to the 5D07Fj ( = 0, 1, 2, 3, and 4) transition of Eu3+ ion in host matrix. The 5D07F0, 5D07F2, and 5D07F3 transitions originate from C2 sites by electronic dipole transition and the 5D07F1 by magnetic dipole transition situated at both S6 and C2 sites [17, 36]. The magnetic dipole transition 5D07F1 is nearly independent of the host matrix and other electric dipoles allowed 5D07Fj ( = 2, 4, and 6) transitions are strongly influenced by the local structure and site asymmetry around the Eu3+ ion [4, 25, 37].
Table 1 showed the luminescence intensity ratios of Eu3+ ion doped Y2O3 matrix. Strong energy transfer from the Eu3+ ions occupying S6 site to C2 site increased the luminescence efficiency at 612 nm. The photoluminescence intensity ratio of 5D07F2 to 5D07F1 (red to orange) provides valuable information about the site occupied by Eu3+ ions and covalent nature of the host matrix. The red/orange ratio of the sample heat treated at different temperatures from 350 up to 900°C only changed very little (10.6–11.3) as shown in Table 1. We suggested that further heat treatment at the higher temperatures will be not necessary.
Figure 10 shows photoluminescent intensity of Y2O3:5 mol% Eu3+ prepared with EDTA fuel, annealed at 900°C (curve 1), 700°C (curve 2), and 350°C (curve 3). It was indicated that the sample prepared at 350°C exhibited the highest luminescence intensity. The emission intensities from Eu3+ rare earth ions were found to increase with the increasing of Eu3+ doping from 3 mol% to 5 mol% and to decrease with higher doping content to 7 mol%. It is found that the optimal concentration of Eu3+ is 5 mol% and optimal temperature is 350°C.
Figure 11 shows the PL excitation spectra of the Y2O3:5 mol% Eu3+ nanoparticles. The excitation spectra show a broad peak at 250 nm along with higher side peaks at 395 nm and 465 nm. On increasing the annealing temperature, intensities of higher side peaks are reduced in comparison to 250 nm peak. These characteristic features of Eu3+ excitation indicate that at higher annealing temperature the energy required for excitation of nanophosphor is due to the 250 nm peak, which is a charge transfer transition (Eu3+ O2−) .
Y2O3:Eu3+ nanoparticles have been successfully synthesized by the EDTA-Na2 fuel assisted combustion method at low temperature and in short reaction time. XRD studies confirmed the formation of pure cubic phase of Y2O3. The crystalline sizes of the nanoparticles were found to be 24 nm for the samples annealed at ~350°C and 26 nm for the samples annealed at 700°C. The intense peak at 117°C upon UV exposure and at least two peaks at 125 and 336°C upon Gamma irradiation were found in TL process. All the obtained samples showed bright emission under CL or PL exciting condition. The PL spectra presented a series of emission peaks between 570 nm and 650 nm corresponding to the 5D0-7Fj ( = 0, 1, 2, 3, and 4) transition of Eu3+ ion. The highest of luminescent intensity at 612 nm under an excitation wavelength of 254 nm is from transition 5D0-7F2. CL intensity of Y2O3:3% mol Eu3+ was measured independently on the excitation powers which were 5, 10, and 15 kV. The PL intensity was found to increase with increasing Eu3+ doping concentration up to 5 mol%. The nanophosphor Y2O3:Eu3+ has great potential to develop display and thermoemission dosimeter, especially for biomedical applications.
Conflict of Interests
The authors declare that there is no conflict of interests regarding the publication of this paper.
The authors are thankful to the colleagues in the Institute for Research and development High Technology of Duy Tan University; Dr. Vu Thi Thai Ha, Mr. Anh Tuan, and Dr. Nguyen Duc Van in the Institute of Materials Science; and Dr. Do Quang Trung and Ph.D. degree student Nguyen Tu in the Advanced Institute of Science and Technology for CL and PL measurements.
- L. Q. Minh, W. Strek, T. K. Anh, and K. Yu, “Luminescent nanomaterials,” Journal of Nanomaterials, vol. 2007, Article ID 48312, 1 pages, 2007.
- P. Packiyaraj and P. Thangadurai, “Structural and photoluminescence studies of Eu3+ doped cubic Y2O3 nanophosphors,” Journal of Luminescence, vol. 145, pp. 997–1003, 2014.
- F.-W. Liu, C.-H. Hsu, F.-S. Chen, and C.-H. Lu, “Microwave-assisted solvothermal preparation and photoluminescence properties of Y2O 3:Eu3+ phosphors,” Ceramics International, vol. 38, no. 2, pp. 1577–1584, 2012.
- H. Huang, G. Q. Xu, W. S. Chin, L. M. Gan, and C. H. Chew, “Synthesis and characterization of Eu:Y2O3 nanoparticles,” Nanotechnology, vol. 13, no. 3, pp. 318–323, 2002.
- P. Psuja, D. Hreniak, and W. Strek, “Rare-earth doped nanocrystalline phosphors for field emission displays,” Journal of Nanomaterials, vol. 2007, Article ID 81350, 7 pages, 2007.
- J. R. Jayaramaiah, B. N. Lakshminarasappa, and B. M. Nagabhushana, “Luminescence studies of europium doped yttrium oxide nano phosphor,” Sensors and Actuators B: Chemical, vol. 173, pp. 234–238, 2012.
- T. K. Anh, D. X. Loc, T. T. Huong, N. Vu, and L. Q. Minh, “Luminescent nanomaterials containing rare earth ions for security printing,” International Journal of Nanotechnology, vol. 8, no. 3–5, pp. 335–346, 2011.
- A. Gupta, N. Brahme, and D. Prasad Bisen, “Electroluminescence and photoluminescence of rare earth (Eu,Tb) doped Y2O3 nanophosphor,” Journal of Luminescence, vol. 155, pp. 112–118, 2014.
- L. Q. Minh, T. Endo, T. T. Huong et al., “Synthesis, structures and properties of emission nanomaterials based on lanthanide oxides and mixoxides,” Transactions of the Materials Research Society of Japan, vol. 35, no. 6, pp. 417–422, 2010.
- J. Zhang, Z. Zhang, Z. Tang, Y. Lin, and Z. Zheng, “Luminescent properties of Y2O3:Eu synthesized by sol-gel processing,” Journal of Materials Processing Technology, vol. 121, no. 2-3, pp. 265–268, 2002.
- G. H. Mhlongo, M. S. Dhlamini, H. C. Swart, O. M. Ntwaeaborwa, and K. T. Hillie, “Dependence of photoluminescence (PL) emission intensity on Eu3+ and ZnO concentrations in Y2O3:Eu3+ and ZnO·Y2O3:Eu3+ nanophosphors,” Optical Materials, vol. 33, no. 10, pp. 1495–1499, 2011.
- C. Feldmann, “Polyol-mediated synthesis of nanoscale functional materials,” Advanced Functional Materials, vol. 13, no. 2, pp. 101–107, 2003.
- Y. Liu, Y. Ruan, L. Song, W. Dong, and C. Li, “Morphology-controlled synthesis of Y2O3:Eu3+ and the photoluminescence property,” Journal of Alloys and Compounds, vol. 581, pp. 590–595, 2013.
- G. Wakefield, E. Holland, P. J. Dobson, and J. L. Hutchison, “Luminescence properies of nanocrystalline Y2O3:Eu3+,” Advanced Materials, vol. 13, no. 20, pp. 1557–1560, 2001.
- G. Siddaramana Gowd, M. Kumar Patra, S. Songara et al., “Effect of doping concentration and annealing temperature on luminescence properties of Y2O3:Eu3+ nanophosphor prepared by colloidal precipitation method,” Journal of Luminescence, vol. 132, no. 8, pp. 2023–2029, 2012.
- M. Kabir, M. Ghahari, and M. Shafiee Afarani, “Co-precipitation synthesis of nano Y2O3:Eu3+ with different morphologies and its photoluminescence properties,” Ceramics International, vol. 40, no. 7, pp. 10877–10885, 2014.
- W. Chen, Y. Tong, Y. Liu et al., “Facile synthesis and luminescent properties of Y2O3:Eu3+ nanophosphors via thermal decomposition of cocrystallized yttrium europium propionates,” Ceramics International, vol. 39, no. 4, pp. 3741–3745, 2013.
- W. Xie, Y. Wang, C. Zou, J. Quan, and L. Shao, “A red-emitting long-afterglow phosphor of Eu3+, Ho3+ co-doped Y2O3,” Journal of Alloys and Compounds, vol. 619, pp. 244–247, 2015.
- A. M. Khachatourian, F. Golestani-Fard, H. Sarpoolaky, C. Vogt, and M. S. Toprak, “Microwave assisted synthesis of monodispersed Y2O3 and Y2O3:Eu3+ particles,” Ceramics International, vol. 41, no. 2, pp. 2006–2014, 2015.
- Y. Vidya, K. S. Anantharaju, H. Nagabhushana et al., “Combustion synthesized tetragonal ZrO2: Eu3+ nanophosphors: structural and photoluminescence studies,” Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 135, pp. 241–251, 2015.
- S. T. Mukherjee, V. Sudarsan, P. U. Sastry, A. K. Patra, and A. K. Tyagi, “Annealing effects on the microstructure of combustion synthesized Eu3+ and Tb3+ doped Y2O3 nanoparticles,” Journal of Alloys and Compounds, vol. 519, pp. 9–14, 2012.
- J. A. Capobianco, F. Vetrone, J. C. Boyer, A. Speghini, and M. Bettinelli, “Optical spectroscopy of nanocrystlline, cubic Y2O3:Eu3+ obtained via combustion synthesis,” Physical Chemistry Chemical Physics, vol. 2, pp. 3203–3207, 2000.
- T. K. Anh, P. Benalloul, C. Barthou, L. T. K. Giang, N. Vu, and L. Q. Minh, “Luminescence, energy transfer, and upconversion mechanisms of y2O3 nanomaterials doped with Eu3+, Tb3+, Tm3+, Er3+, and Yb3+ ions,” Journal of Nanomaterials, vol. 2007, Article ID 48247, 10 pages, 2007.
- J. Bang, M. Abboudi, B. Abrams, and P. H. Holloway, “Combustion synthesis of Eu-, Tb- and Tm- doped Ln2O2S (Ln=Y, La, Gd) phosphors,” Journal of Luminescence, vol. 106, no. 3-4, pp. 177–185, 2004.
- J. R. Jayaramaiah, B. N. Lakshminarasappa, and B. M. Nagabhushana, “Luminescence studies of europium doped yttrium oxide nano phosphor,” Sensors and Actuators, B: Chemical, vol. 173, pp. 234–238, 2012.
- D. Kumar, J. Sankar, K. G. Cho, V. Craciun, and R. K. Singh, “Enhancement of cathodoluminescent and photoluminescent properties of Eu:Y2O3 luminescent films by vacuum cooling,” Applied Physics Letters, vol. 77, no. 16, pp. 2518–2520, 2000.
- L. E. Shea, “Low-voltage cathodoluminescent phosphors,” Electrochemical Society Interface, vol. 7, no. 2, pp. 24–27, 1998.
- A. M. Srivastava and C. R. Ronda, “Phosphors,” Electrochemical Society Interface, vol. 12, no. 2, pp. 48–51, 2003.
- X. Liu, C. Lin, and J. Lin, “White light emission from Eu3+ in CaIn2O4 host lattices,” Applied Physics Letters, vol. 90, no. 8, Article ID 081904, 4 pages, 2007.
- N. Brahme, A. Gupta, D. P. Bisen, R. S. Kher, and S. J. Dhoble, “Thermoluminescence and mechanoluminescence of Eu doped Y2O3 nanophosphors,” Physics Procedia, vol. 29, pp. 97–103, 2012.
- S.-M. Yeh and C.-S. Su, “UV induced thermoluminescence in rare earth oxide doped phosphors: possible use for UV dosimetry,” Radiation Protection Dosimetry, vol. 65, no. 1–4, pp. 359–362, 1996.
- R. Tamrakar, V. Dubey, N. K. Swamy, R. Tiwari, S. V. N. Pammi, and P. V. Ramakrishna, “Thermoluminescence studies of UV-irradiated Y2O3:Eu3+ doped phosphor,” Research on Chemical Intermediates, vol. 39, no. 8, pp. 3919–3923, 2013.
- R. K. Tamrakar, D. P. Bisen, I. P. Sahu, and N. Brahme, “UV and gamma ray induced thermoluminescence properties of cubic Gd2O3:Er3+ phosphor,” Journal of Radiation Research and Applied Sciences, vol. 7, no. 4, pp. 417–429, 2014.
- T. S. Atabaev, H. H. Thi Vu, H.-K. Kim, and Y.-H. Hwang, “The optical properties of Eu3+ and Tm3+ codoped Y2O3 submicron particles,” Journal of Alloys and Compounds, vol. 525, pp. 8–13, 2012.
- T. Igarashi, M. Ihara, T. Kusunoki, K. Ohno, T. Isobe, and M. Senna, “Relationship between optical properties and crystallinity of nanometer Y2O3: Eu phosphor,” Applied Physics Letters, vol. 76, no. 12, pp. 1549–1551, 2000.
- M. G. Ivanov, U. Kynast, and M. Leznina, “Eu3+ doped Yttrium oxide nanoluminophors from laser synthesis,” in Proceedings of the International Conference on Luminescence and Optical Spectroscopy of Condensed Matter (ICL '14), Wroclaw, Poland, July 2014.
- G. Y. Hong, B. S. Jeon, Y. k. Yoo, and J. S. Yoo, “Photolumiescence chracteristics of spherica Y2O3:Eu3+ phosphors by aerosol pyrolysis,” Journal of The Electrochemical Society, vol. 148, no. 11, pp. H161–H166, 2001.
Copyright © 2015 Tran Kim Anh et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.