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Journal of Nanomaterials
Volume 2015 (2015), Article ID 810579, 11 pages
Research Article

Degradation Kinetics of Photoelectrocatalysis on Landfill Leachate Using Codoped TiO2/Ti Photoelectrodes

1College of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Center, Guangzhou 510006, China
2Guizhou Academy of Sciences, Shanxi Road 1, Guiyang 550001, China
3State Key Laboratory of Subtropical Building Sciences, South China University of Technology, Guangzhou 510640, China
4Key Laboratory of Environmental Protection and Eco-Remediation of Guangdong Regular Higher Education Institutions, South China University of Technology, Guangzhou Higher Education Mega Center, Guangzhou 510641, China

Received 6 December 2014; Revised 4 March 2015; Accepted 12 March 2015

Academic Editor: Ki-Joon Jeon

Copyright © 2015 Xiao Zhou et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The photoelectrocatalytic (PEC) oxidation degradation of landfill leachate rejected by reverse osmosis (RO) using a Cu/N codoped TiO2/Ti photoelectrode was kinetically investigated in terms of COD concentration. The key factors affecting the reaction rate of PEC oxidation and the removal efficiency of COD concentration were studied, including the COD concentration of landfill leachate, potential bias applied, pH value of landfill leachate, and the reaction temperature of photoelectrocatalytic reactor. The apparent kinetic model was applied to describe the photoelectrocatalysis reaction. The results showed that the kinetic equation for photoelectrocatalytic oxidation of landfill leachate was fitting well with the experimental data ( 0.967~0.998), with average activation energy 6.35 × 104 Jmol−1. It was found that there was an optimal bias voltage of 20 V and low pH value was favorable for COD removal in landfill leachate. The reaction order of initial COD concentration (1.326) is higher than that of potential bias (1.102) and pH value (0.074), which indicates that the reaction rate can be controlled efficiently through adjusted initial concentration. The experiments demonstrated that potential bias would approach its statured value with increasing potential bias.