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Journal of Nanomaterials
Volume 2017, Article ID 1401503, 11 pages
Research Article

Electrochemical Deposition of Zinc Oxide on the Surface of Composite Membrane Polysulfone-Graphene-Polystyrene in the Presence of Water Soluble Polymers

1Department of Chemical and Biochemical Engineering, University Politehnica of Bucharest, 1-7 Gh. Polizu Street, 011061 Bucharest, Romania
2Department of Bioresources and Polymer Science, University Politehnica of Bucharest, 1-7 Gh. Polizu Street, 011061 Bucharest, Romania
3National Institute for Research and Development in Microtechnologies (IMT-Bucharest), 126 A, Erou Iancu Nicolae Street, P.O. Box 38-160, 023573 Bucharest, Romania
4Center of Materials Technology and Photonics, School of Engineering, Technological Educational Institute of Crete, 71004 Heraklion, Greece
5Chemistry Faculty, “Alexandru Ioan Cuza” University of Iași, 11 Carol I Blvd, 700506 Iași, Romania

Correspondence should be addressed to Edina Rusen; moc.oohay@nesur_anide and Aurel Diacon; moc.oohay@nocaid_lerua

Received 27 November 2016; Revised 14 February 2017; Accepted 26 February 2017; Published 9 March 2017

Academic Editor: Michele Zappalorto

Copyright © 2017 Alexandra Mocanu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The aim of this study consisted in the development of an alternative synthesis procedure for hybrid ultrafiltration membranes for water purification. The membranes were obtained by wet-phase inversion method based on aliquots of polysulfone (PSF) and graphene nanoplatelets modified with poly(styrene) (G-PST). The hybrid materials were modified by electrochemical deposition of zinc oxide (ZnO) on one side of the membranes in the presence of water soluble polymers. Raman, XPS, and TGA analyses were used to characterize the chemical and thermal characteristics of the PST-G. SEM analysis showed the formation of asymmetric porous configuration in all cases and the generation of ZnO with different shapes/structures on the bottom surface of the membrane or inside the porous channels. EDS analysis confirmed the formation of ZnO.