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Journal of Nanomaterials
Volume 2017, Article ID 1603450, 9 pages
Research Article

Optical and Magnetic Properties of Ni Doped ZnS Diluted Magnetic Semiconductors Synthesized by Hydrothermal Method

1State Key Laboratory of Advanced Processing and Recycling Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
2School of Science, Lanzhou University of Technology, Lanzhou 730050, China

Correspondence should be addressed to Zhiqiang Wei; moc.361@ouziewnaiq

Received 24 March 2017; Revised 16 June 2017; Accepted 12 July 2017; Published 11 September 2017

Academic Editor: Marinella Striccoli

Copyright © 2017 Meirong Wu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Diluted magnetic semiconductors with different consistency ratio ( = 0, 0.01, 0.03, 0.05, and 0.07) were successfully synthesized by hydrothermal method using ethylenediamine as a modifier. The influence of Ni doping concentration on the microstructure, morphology, and optical and magnetic properties of undoped and Ni doped ZnS nanocrystals was characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), X-ray energy dispersive spectrometry (XEDS), ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), photoluminescence spectra (PL), and the vibrating sample magnetometer (VSM), respectively. The experiment results show the substitution of Ni2+ on Zn2+ sites without changing the hexagonal wurtzite structure of ZnS and generate single-phase with good crystallization. The lattice constant causes distortion and decreases with the increase of Ni2+ doped concentration. The appearance of the samples is one-dimensional well-dispersed nanorods. UV-vis spectra reveal the band gap of all samples greater than that of bulk ZnS (3.67 eV), and blue shift phenomenon occurs. The photoluminescence spectra of undoped and doped samples possess the broad blue emission band in the range of 400–650 nm; the PL intensities of nanorods increase with the increase of Ni content comparing to pure ZnS and reach maximum for = 0.03. Magnetic measurements indicated that the undoped ZnS samples are superparamagnetic, whereas the doped samples exhibit ferromagnetism.