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Journal of Nanomaterials
Volume 2017, Article ID 5075326, 12 pages
Research Article

Heat Treatment Effect on Eu3+ Doped TeO2-BaO-Bi2O3 Glass Systems with Ag Nanoparticles

1Department of Solid State Physics, Faculty of Applied Physics and Mathematics, Gdańsk University of Technology, Gabriela Narutowicza 11/12, 80-233 Gdańsk, Poland
2Laboratory of Electron Microscopy, Faculty of Biology, University of Gdańsk, ul. Wita Stwosza 57/246, 80-952 Gdańsk, Poland

Correspondence should be addressed to Tomasz Lewandowski;

Received 28 July 2017; Accepted 1 October 2017; Published 30 October 2017

Academic Editor: Xuping Sun

Copyright © 2017 Tomasz Lewandowski et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Glass systems of 73TeO2-4BaO-3Bi2O3-2Eu2O3-xAg (in molar ratio where x = 0, 1, 2, and 3) compositions have been successfully synthesized. Silver nanoparticles were obtained with the employment of heat treatment (HT) procedure executed at 350°C. Glass transition temperatures of different compositions have been determined through DSC measurements. XRD results presented characteristic amorphous halo indicating lack of long range order in the samples. FTIR structural studies revealed that glass matrix is mainly composed of TeO3 and TeO4 species and is stable after different applied heat treatment times. X-ray photoelectron spectroscopy (XPS) measurements confirmed that in selected samples part of Ag ions changed oxidation state to form Ag0 species. TEM measurements revealed nanoparticles of size in the range of 20–40 nm. UV-vis absorption results demonstrated characteristic transitions of Eu3+ ions. Additionally, UV-vis spectra of samples heat-treated for 6, 12, 24, and 48 hours presented bands related to silver nanoparticles. Photoluminescence (PL) studies have been performed with excitation wavelength of  nm. Obtained spectra exhibited peaks due to 5D0-7FJ (where ) and 5D1-7FJ (where ) transitions of Eu3+. Moreover, luminescence measurement indicated enhancement of rare earth ions emissions in several of the annealed samples. Increase of emission intensity of about 35% has been observed.