Review Article
IR and UV/VIS Spectroscopic Characterization of the Higher Fullerene C76-D2 for Its Quantitative and Qualitative Determination
Table 1
The molar absorptivity and the integrated molar absorptivity in adequate integration range of deconvoluted absorption bands of C76-D2.
| a,b (cm−1) | (L cm−1 mol−1) | Int. range (cm−1) | (Km mol−1) |
| 1733.8 | 129.711 | 1758–1721 | 1.097 | 1712.6 | 81.774 | 1721–1699 | 0.017 | 1680.7 | 91.643 | 1684–1678 | 0.004 | 1633.1 | 188.927 | 1678–1573 | 6.549 | 1551.6 | 16.919 | 1562–1543 | 0.022 | 1533.4 | 14.099 | 1542–1513 | 0.025 | 1493.4 | 252.372 | 1512–1481 | 2.242 | 1461.1 | 320.047 | 1478–1432 | 3.953 | 1398.7 | 270.701 | 1416–1396 | 0.265 | 1385.6 | 303.128 | 1393–1371 | 0.850 | 1364.2 | 146.630 | 1368–1349 | 0.230 | 1338.7 | 29.608 | 1349–1326 | 0.024 | 1312.4 | 112.792 | 1326–1300 | 0.884 | 1290.5 | 81.774 | 1296–1283 | 0.010 | 1275.6 | 91.643 | 1282–1263 | 0.096 | 1247.6 | 111.382 | 1260–1231 | 0.568 | 1208.6 | 174.828 | 1222–1202 | 0.234 | 1187.0 | 384.903 | 1200–1168 | 3.423 | 1161.6 | 159.319 | 1167–1141 | 0.254 | 1122.0 | 131.121 | 1139–1112 | 0.219 | 1101.0 | 140.990 | 1110–1099 | 0.028 | 1081.6 | 370.804 | 1098–1063 | 3.810 | 1056.4 | 112.792 | 1062–1048 | 0.027 | 1024.2 | 115.612 | 1039–1005 | 0.179 | 967.0 | 634.455 | 996–926 | 13.765 | 892.2 | 88.824 | 908–871 | 1.107 | 823.4 | 64.855 | 848–809 | 1.376 | 788.8 | 43.707 | 803–774 | 0.219 | 742.9 | 54.986 | 750–736 | 0.010 | 729.3 | 67.675 | 736–717 | 0.014 | 704.8 | 84.594 | 715–679 | 0.460 | 661.1 | 66.265 | 678–655 | 0.240 | 645.8 | 76.135 | 655–632 | 0.031 | 602.9 | 132.531 | 627–575 | 1.246 | 555.5 | 112.792 | 570–548 | 0.038 | 532.7 | 126.891 | 545–520 | 0.300 | 507.1 | 104.333 | 518–499 | 0.062 | 486.6 | 107.152 | 499–471 | 0.344 | 460.6 | 71.905 | 469–453 | 0.037 | 436.0 | 102.923 | 450–422 | 0.637 | 405.2 | 179.057 | 421–400 | 1.799 |
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