Review Article

A Review on Nanofluids: Fabrication, Stability, and Thermophysical Properties

Table 3

Summary of available studies on water base nanofluids stability measurements and dispersion improvement.

ResearchersBasefluidsParticles materialParametersSurfactantpH controlStability evaluation methods Observations

Li et al. [27]WaterCu = 0.0005–0.5 wt%
= 25 nm
SDBS and CTABSedimentation photographs and zeta size analyserNanofluids with CTAB lasted for 1 week without sedimentation.

Kim et al. [28]WaterAu = (0.6 × 10−4)–(2.6 × 10−4) vol%
= 7.1–12.1 nm
Zeta potential analyserGood particle dispersion for 1 month.

Paul et al. [29]WaterAu = (0.6 × 10−4)–(2.6 × 10−4) vol%
= 21 nm
TEM, SEM, and DLSNo agglomeration or sedimentation even after 48 h.

Qu et al. [30]WaterAl2O3 = 0.1–1.2 wt%
= 43 nm
4.9SEMNanoparticles suspended stably for 3 days.

Anoop et al. [31]WaterAl2O3 = 1–6 wt%
= 45 and 150 nm
6.5 (1 wt%)
6.0 (2 wt%)
5.5 (4 wt%)
5.0 (6 wt%)
TEMSeveral weeks of stability was achieved.

Rohini Priya et al. [32]WaterCuO vol%
10 : 1 length to thickness ratio
TironZeta potential analysis and visual observationStability was maintained throughout the experiment.

Chang et al. [33]WaterCuO = 0.01–0.4 vol%
= 20–30 nm
Sodium hexametaphosphate (NaHMP)6.64–6.70 (with surfactant), and >9.5 (without surfactant)Zeta potential analysisCuO content > 0.04 vol% showed very high instability and particles tended to settle within minutes.

Liu et al. [34]WaterCuO = 0.5, and 1 wt%
= 30 nm
TEMThe uniformity and stability of the suspensions were poor after a couple of days.

Yang and Liu [35]WaterSiO2 = 0.5–2.5 wt%
= 30 nm
TrimethoxysilaneSEMFunctionalized nanofluids kept good dispersion for 12 months; pure nanofluid developed sedimentation after several days.

Qu and Wu [36]WaterSiO2;
Al2O3
= 0.1–0.6 wt%
= 30 nm;
= 0.1–1.2 wt%
= 56 nm
9.7;
4.9
TEMBoth types of nanofluids maintained their stability for several days, but the alumina nanofluid had better particles dispersion.

Suganthi and Rajan [37]WaterZnO = 0.25–2.0 vol%
= 30–45 nm
Sodium hexametaphosphate (SHMP)Zeta potential analysis and SEMAll samples showed good stability, with highest stability at 2 vol%; sonication for 3 h reduced the aggregated size leading to a better improvement.

Duangthongsuk and Wongwises [38]WaterTiO2 = 0.2–2.0 vol%
= 21 nm
CTABTEMFew agglomerations were observed after 3 h from sonication.

Hari et al. [39]DIWAgBasefluid = 20 ml
AgNo3 = 0.25 mM
Tri-sodium = 0.25 mM
Size = 21 nm
CTABUV-Vis spectroscopyThe suspensions were stable for one week.

Kole and Dey [40]DIWCu = 0.0005–0.5 wt%
= 40 nm
DLS and TEMNo visible signs of sedimentation for more than 15 days.

Kathiravan et al. [41]DIWCu = 0.25, 0.5, and 1.0 wt%
= 10 nm
SDSTEMNanofluid maintained particles dispersion for more than 10 h.

Yousefi et al. [42]DIWMWCNTs = 0.2 wt%
= 10–30 nm
Triton X-1007.4TEMColloid was stable for 10 days; optimum sonication time was found to be 30 min.

Garg et al. [43]DIWMWCNTs = 1.0 wt%
= 10–20 nm
= 0.5–40 µm
Gum ArabicTEMOver 1 month suspension stability achieved with no visible sedimentation or settling.

Ding et al. [44]DIWMWCNTs = 0–1.0 vol%
= 5–10 nm
= 10–30 µm
Gum Arabic2, 6, 10.5, and 11SEMNanofluids showed good stability for months.

Abareshi et al. [45]DIWFe3O4 = 0.025–3.0 vol%
Size = 15–22 nm
Tetramethyl ammonium hydroxide12.8Zeta potential analysisSuspensions showed good dispersion and stability.

Phuoc et al. [46]DIWAg = 0.01 vol%
= 20–30 nm
TEMNanofluids were stable for several months.

Parametthanuwat et al. [47]DIWAg = 0.5% w/v
< 100 nm
Samples stability lasted for 48 h.

Yousefi et al. [48]DIWAl2O3 = 0.2, and 0.4 wt%
= 15 nm
Triton X-100Visual observationSuspension stability lasted for about 3 days.

Hung et al. [49]DIWAl2O3 = 0.5, 1.0, and 3.0 wt%
= 20 nm
ChitosanUV-vis spectroscopyNanofluid of 3.0 wt% showed a difference of 5% in its stability, compared to the 0.5 wt% sample.

Heyhat et al. [50]DIWγ- Al2O3 = 1.0–2.0 vol%
= 40 nm
SEM and Zeta potential analysisSuspensions were stable due to having a zeta potential value of 30 mV.

Note. Particles concentration, diameter, height, and weight by volume are represented as , , , and w/v, respectively.