Pd Nanoparticles Stabilized by Hypercrosslinked Polystyrene Catalyze Selective Triple C-C Bond Hydrogenation and Suzuki Cross-Coupling

Table 2

Results of testing of HPS-based catalysts in MBY hydrogenation: influence of reduction method and treatment of the catalyst with Na₂CO₃.

Catalyst	Selectivity, ±0.5% (calculated at MBY conversion 95%)	Catalytic activity , molMBY/(molPds)
Pd/MN270-NaW	94.6	3.2
Pd/MN270	95.2	3.7
Pd/MN270-H2	96.0	3.1
Pd/MN270-H2 without preliminarily liquid-phase reduction	95.4	3.4