Research Article | Open Access
Manh B. Nguyen, Giang H. Le, Trang T. T. Pham, Giang T. T. Pham, Trang T. T. Quan, Trinh Duy Nguyen, Tuan A. Vu, "Novel Nano-Fe2O3-Co3O4 Modified Dolomite and Its Use as Highly Efficient Catalyst in the Ozonation of Ammonium Solution", Journal of Nanomaterials, vol. 2020, Article ID 4593054, 11 pages, 2020. https://doi.org/10.1155/2020/4593054
Novel Nano-Fe2O3-Co3O4 Modified Dolomite and Its Use as Highly Efficient Catalyst in the Ozonation of Ammonium Solution
Catalytic ozonation is a new method used for removal of NH4OH solution. Therefore, high catalytic performance (activity and selectivity) should be achieved. In this work, we report the synthesis and catalytic performance of Fe2O3-Co3O4 modified dolomite in the catalytic ozonation of NH4OH solution. Dolomite was successfully activated and modified with Fe2O3 and Co3O4. Firstly, dolomite was activated by heating at 800°C for 3 h and followed by KOH treatment. Activated dolomite was modified with Fe2O3 by the atomic implantation method using FeCl3 as Fe source. Fe2O3 modified dolomite was further modified with Co3O4 by precipitation method. The obtained catalysts were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), energy-dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), N2 adsorption–desorption (BET), and temperature-programmed reduction (H2-TPR). From SEM image, it was revealed that nano-Fe2O3 and Co3O4 particles with the size of 80–120 nm. Catalytic performance of activated dolomite, Fe2O3 modified dolomite, and Fe2O3-Co3O4 modified dolomite in catalytic ozonation of NH4+ solution was investigated and evaluated. Among 3 tested catalysts, Fe2O3-Co3O4 modified dolomite has the highest NH4+ conversion (96%) and N2 selectivity (77.82%). Selectivity toward N2 over the catalyst was explained on the basis of bond strength M-O in oxides through the standard enthalpy of oxide. Catalyst with lower value has higher N2 selectivity and the order is the following: Co3O4 ( of 60 kcal (mole O)) > Fe2O3 ( of 70 kcal (mole O)) > MgO ( of 170 kcal (mole O)). Moreover, high reduction ability of Fe2O3-Co3O4 modified dolomite could improve the N2 selectivity by the reduction of NO3- to N2 gas.
Agricultural and industrial effluents containing ammonia (NH4+-N) discharged from production operation, dairy processor, and fertilizer plants could reduce water quality and cause a danger to human health . Methods for removal of NH4OH solution such as biological nitrification processes, ion exchange, membrane separation, chlorination, and catalytic degradation have often been used [2–6]. However, ion exchange and membrane separation methods require expensive operating costs and can cause secondary pollution, while biological methods require a long treatment time and strict operation control [3–5]. An alternative approach is the catalytic ozonation. Liu et al. investigated the employing of MgO as an effective catalyst for the catalytic ozonation of NH4+ solution. This MgO catalyst exhibited high NH4OH conversion (95%) but the N2 selectivity was very low; nitrites and nitrates were the main products . Ichikawa et al. have examined a series of metal oxides such as MgO, Co3O4, Fe2O3, and CuO for catalytic ozonation of NH4+ ion to nitrogen gas (N2O, N2) and found that Co3O4 exhibited the highest N2 selectivity as compared to that of MgO, CuO, and Fe2O3 . Liu et al. demonstrated that the SrO-Al2O3 composite was an effective catalyst for ultrasound-assisted ozonation of NH4+ solution. NH4+ conversion of 83.2% and gaseous nitrogen selectivity of 51.8% were achieved . Chen et al. 2018 reported the synthesis of MgO-Co3O4 (molar ratio 8 : 2) and claimed that an ammonia nitrogen removal and gaseous nitrogen selectivity reached to the value of 85.2% and 44.8%, respectively .
Dolomite is a mineral clay composed of calcium magnesium carbonate CaMg(CO3)2 . However, raw dolomite cannot be used as adsorbent and catalyst due to its low surface and high impurities. Therefore, the activation or modification of dolomite is necessary to expand its application. Chaudhary and Prasad reported that thermally activated dolomite could enhance its surface area, pore size distribution, and pore volume, consequently increasing fluoride removal from aqueous solution . Modified dolomite can be used as an efficient adsorbent for removal of arsenic and heavy metals and dyes from aqueous solution . Thermally activated dolomite can be used as an efficient catalyst for biodiesel production and decomposition of pentachlorophenol [12, 13]. To our best knowledge, Fe2O3-Co3O4 modified dolomite used as an efficient catalyst in catalytic ozonation of NH4+ solution has not yet been reported in the literature.
In this work, we report the activation and Fe2O3 and Fe2O3-Co3O4 modification of dolomite. Activated and Fe2O3 and Fe2O3-Co3O4 modified dolomites were tested in the catalytic ozonation of NH4OH solution, and catalytic ozonation performances of activated and modified dolomites were evaluated and rationalized.
2. Materials and Methods
The natural dolomite was provided by Ninh Binh mineral company Vietnam. Iron(III) chloride hexahydrate (FeCl3·6H2O, 98%), cobalt(II) chloride hexahydrate (CoCl2·6H2O, 98%), ammonium chloride (NH4Cl, 99%), cetyltrimethylammonium bromide (CTAB, ≥98%), and natri hydroxit (NaOH, 97%) were provided by Sigma Corporation.
2.2.1. Activation of Raw Dolomite
Firstly, 10 g of dolomite was activated by heating at 800°C for 3 h in a furnace with a heating rate of 10°C/min. After calcination, CaMg(CO3)2 was converted into CaCO3, Ca(OH)2, and MgCO3 as the following reactions:
Activated dolomite was treated with a solution of 10 M KOH for 24 h at 80°C. The solid product was separated from the mixture by centrifuge and then was washed several times with distilled water until a pH of 7 and dried overnight at 80°C in a furnace.
2.2.2. Modification of Activated Dolomite with Fe2O3
The incorporation of Fe ions into activated dolomite framework (denoted as Fe2O3/dolomite) was carried out by using an “atomic implantation” method. Atomic implantation has occurred in a tubular quartz reactor with two compartments, separated by a membrane of quartz fibers. 0.483 g of FeCl3·6H2O and 0.9 g of activated dolomite are introduced into each compartment. Tubular quartz reactor is placed in a tubular furnace and heated up at 500°C with a heating rate of 20°C/min. At this temperature, FeCl3 is evaporated and with N2 flow (60 mL/min) went through the membrane to the compartment containing the activated dolomite (Scheme 1). At this stage, FeCl3 is dissociated into Fe3+, Cl-, and Fe3+ ions incorporated into an activated dolomite matrix. After one hour of heating at 500°C, the reactor is cooled down to the room temperature. The scheme of modifying dolomite by the atomic implantation method is illustrated as below.
2.2.3. Modification of Fe2O3/Dolomite with Co3O4 (Denoted as Fe2O3-Co3O4/Dolomite) Was Performed by Precipitation Method
0.8 g of Fe2O3/dolomite was put into a glass reactor that contained 50 mL of H2O (solution 1). After that, 0.8068 g of CoCl2·6H2O was added into 50 mL of H2O and ultrasonic treatment for 60 minutes (solution 2). 2.4708 g of CTAB was put into 20 mL of H2O, and then, the mixture was stirred to form a clear solution (solution 3). Solution 2 was dropwise added to solution 1, and then, solution 3 was dropwise added to the above mixture solution and adjusted pH of 10 by adding 2 M NaOH solution. The mixture is further stirred and aged at 80°C for 24 h. The solid product is separated by centrifuge filtration and washed with distilled water until pH of 7. The product is dried at 90°C and calcined at 450°C for 3 h and then cooled down to room temperature.
The X-ray diffraction (XRD) measurements were performed on a D8 Advance diffractometer (Bruker, Germany) using CuKα as radiation source, nm, and a range of . The morphology of samples was examined by scanning electron microscopy on JEOL JSM 6500F. The FT-IR measurement was performed on a Jasco 4700 spectrometer. The surface area of samples was determined by BET measurements on Tristar-3000 instruments using nitrogen adsorbate. EDS of samples were measured on a JEOL JED-2300 spectrometer. Temperature-programmed reduction of hydrogen (H2-TPR) was performed on an Autochem II 29020 instrument (micromeritics) with a thermal conductor detector (TCD).
2.4. Evaluation of Catalytic Activity and Selectivity
Catalytic ozonation of NH4+ solution is carried out in a glass reactor equipped with heating and stirring systems. The reaction conditions are the following: reaction temperature of 50°C, NH4+ solution of 50 mg/L, catalyst dosage of 0.6 g/L, reaction time of 2 h, ozone flow of 30 mg/min, and NH4Cl used as NH4+ source. NH4+ concentration was analyzed by the Nessler method. 1 mL of Nessler reagent is added to 25 mL of the mixture of reaction product. NO3- and NO2- concentration was determined by using the spectrometric methods, which complies to ISO (ISO 7890-3:2006 and ISO 6777-1984). The solution was transferred to the cuvette of the spectrophotometer (UV-Vis Lambda 25, Germany) and measured under UV light at a wavelength of 425 nm [14–16].
The conversion and selectivity are calculated as follows:
3. Results and Discussion
3.1. X-Ray Diffraction
In X-ray diffraction pattern (XRD) of raw dolomite (Figure 1(a)) appeared the peaks at 30.9°, 41.1°, 44.9°, and 51.3° which are characteristic for CaMg(CO3)2. In addition, the appearance of peaks at 2θ of 23°, 29.6°, 36°, 39.6°, 43.2°, 47.6°, 48.5°, 57.3°, and 60.8° was assigned to CaCO3 phase . In the XRD pattern of activated dolomite (Figure 1(b)), specific peaks of CaMg(CO3)2 phase disappear. The new peaks at 2θ of 42.8° and 61.9° appear which is attributed to the reflecting plane (101) and (103) which are typical for the structure of MgO . In the XRD pattern of Fe2O3/dolomite (Figure 1(c)) appeared typical peaks of Fe2O3 phase at 2θ of 33.1°, 35°, 49.5°, and 54° which is attributed to the reflecting plane (104), (110), (024), and (116), respectively . In the XRD pattern of Fe2O3-Co3O4/dolomite (Figure 1(d)), beside the peaks of Fe2O3 phase, appear the peaks at 2θ of 37.9°, 44.8°, 55.6°, 59.3°, and 65.2o which are assigned to the reflecting plane (311), (400), (422), (511), and (440) of the Co3O4 phase, respectively .
3.1.1. Fourier-Transform Infrared Spectroscopy
As observed in Figure 2(a), in the FTIR spectrum of dolomite (raw ores) appeared the bands at 720; 873; 1429; 1797; 2516; and 2868 cm-1 which are assigned to the occurrence of fluctuations in dolomite structure [21, 22]. In the FTIR spectrum of activated dolomite (Figure 2(b)) appeared the band at 3448 cm-1 which was assigned to the vibration of OH groups . In addition, the peak at 428 cm-1 is attributed to the stretching of Mg-O bonds . In the FTIR spectrum of Fe2O3/dolomite (Figure 2(c)) appeared the bands at 548 and 638 cm-1 which are characteristic for Fe-O bonding [25, 26]. In the FTIR spectrum of Fe2O3-Co3O4/dolomite (Figure 2(d)) additionally appeared the band at 666 cm-1, which assigned to the stretching of Co-O bond [27, 28].
3.1.2. Energy-Dispersive X-Ray Spectroscopy Analysis
From Figure 3 and Table 1, it was observed that the chemical composition of activated dolomite was slightly changed in O and Ca content between raw dolomite and activated dolomite. Thus, oxygen content decreases and calcium content increases. This is due to the decomposition of CaCO3 to CaO and CO2. Comparing the chemical composition of activated, Fe2O3/dolomite and Fe2O3-Co3O4/dolomite, the redistribution of elements in these samples was observed. Oxygen and calcium content were reduced and replaced by Fe and Co content.
3.1.3. Scanning Electron Microscopy (SEM) Analysis
SEM images of raw dolomite, activated dolomite, Fe2O3/dolomite, and Fe2O3-Co3O4/dolomite samples were illustrated in Figure 4. SEM image of raw dolomite (Figure 4(a)) showed the rough surface with high disorder and particles size of about 2 μm. Activated dolomite (Figure 4(b)) shows a smaller particle size of ca. 0.2-0.4 μm with uniform distribution. The strong reduction in size of dolomite can be explained by the fact that the thermal cracking of dolomite fragments and decomposition of carbonates to magnesium and calcium oxide and CO2. SEM image of Fe2O3/dolomite (Figure 4(c)) presented crystals of sheet shape, with particle size of ca. 0. .3 μm. SEM image of Fe2O3-Co3O4/dolomite (Figure 4(d)) showed the nano-Co3O4 particles size of 80-120 nm, with aggregated form of 0.2-0.3 μm size.
3.1.4. N2 Adsorption–Desorption Isotherm (BET) Analysis
N2 adsorption–desorption isotherms of raw dolomite, activated dolomite, Fe2O3/dolomite, and Fe2O3-Co3O4/dolomite samples are presented in Figure 5. N2 adsorption–desorption isotherms of all dolomite samples look like a type IV according to the IUPAC classification . However, the hysteresis loop on activated, Fe2O3/dolomite, and Fe2O3-Co3O4/dolomite samples was differentiated. This hysteresis loop is due to the capillary condensation of nitrogen which is often observed on mesoporous materials. Specific surface charge (), pore diameter (), and pore volume () are listed in Table 2.
As seen in Table 2, , , and of activated dolomite were much higher than those of raw dolomite. This indicated the efficiency of activation, making dolomite structure more porous and consequently increasing the surface area, pore volume, and pore diameter. Modification of activated dolomite by Fe2O3 and Co3O4 led to increase the surface are and pore volume (from 22 m2/g to 60 m2/g). This clearly indicated the formation of new mesoporous systems by the agglomeration of nano-Fe2O3 and Co3O4 particles. The decrease in pore diameter observed on Fe2O3/dolomite and Fe2O3-Co3O4/dolomite can be explained by the fact that nano-Fe2O3 and Co3O4 particles are located within the pores of activated dolomite, causing the narrowing pore diameter.
3.1.5. H2-TPR Analysis
In the H2-TPR profile of activated dolomite material (Figure 6(a)) appeared a peak at ca. 706°C which was assigned to the reduction of MgO to Mg . In the H2-TPR profile of Fe2O3/dolomite (Figure 6(b)) appeared peaks at 318°C, 408°C, 550°C, and 689°C which are characteristic for the reduction Fe2O3 to Fe3O4, reduction of Fe3O4 to FeO, and the reduction of MgO to Mg, respectively [5, 30]. H2-TPR profile of Fe2O3-Co3O4 modified dolomite (Figure 6(c)) shows peaks at 328°C, 420°C, 548°C, and 688°C which is attributed to the reduction of Co3+ to Co2+, Co2+ to Coo, Fe3O4 to FeO, and MgO to Mg [30–32]. From the obtained results, it can be concluded that the Fe2O3 and Fe2O3-Co3O4 modified dolomite exhibits much higher reduction ability as compared to that of activated dolomite. Thus, much lower reduction temperature of modified dolomites (320-420°C) than that of activated dolomite (680-730°C) was noted. The Fe2O3-Co3O4/dolomite exhibited the highest peak intensity at 318-340°C, indicating a larger amount of H2 reduction as compared to that of Fe2O3 modified dolomite. This lowest reduction temperature of Fe2O3-Co3O4 modified dolomite is due to the fact that M-O strength of this catalyst is weak. The high reduction ability of this catalyst played a decisive role in the improvement of N2 selectivity, by enhancing the reduction of NO3- to N2.
3.1.6. Catalytic Ozonation of NH4+ Solution
NH4+ conversion to NO3- and N2 overactivated and modified dolomites is presented in Figure 7. As seen in Figure 7, all samples exhibited high NH4+ conversion (86-96%) and among these catalysts, Fe2O3-Co3O4/dolomite has the highest activity (conversion of 96%). The N2 selectivity is decreased in the order activated dolomite (45%) < Fe2O3/dolomite (65.13%) < Fe2O3-Co3O4/dolomite (77.68%) and NO3- selectivity is increased in the order: activated dolomite (54.32%) > Fe2O3/dolomite (34.87%) > Fe2O3-Co3O4/dolomite (22.32%). Among the tested samples, Fe2O3-Co3O4/dolomite exhibited the highest N2 selectivity of 77.68% and lowest NO3- selectivity of 22.32%. The result obtained in this work is better than that reported in the literature. Thus, Chen et al.  have shown the N2 selectivity of 44.8% over MgO-Co3O4 catalyst in the catalytic ozonation of ammonium solution. Liu et al.  have shown the conversion of 83.2% and gaseous nitrogen selectivity of 51.8% on SrO-Al2O3 catalyst in the catalytic ozonation of ammonium solution. The mechanism of catalytic ozonation of NH4+ solution is involved with the following process. The ozonation reaction was conducted at pH of 9, and ammonium exists as NH3 molecule, (Equation (3)). At pH of 9, the ozonation catalyzes the formation of HO2· and OH radical, according to Equations (4) and (5) .
The decomposition of NH3 in water through ozonation with a metal oxide catalyst is performed by hydroxyl radicals (Equation (6)). In addition, the hydroxyl radical oxidizes NH3 in the solution to intermediate product nitrite, which rapidly oxidizes to nitrate (Equation (7)) and (Equation (8)) . NH3 in solution can be oxidized to nitrate nitrogen by hydroxyl radical (Equation (9)).
In summary, the reactions occurring during ammonium decomposition by catalytic ozonation are as follows:
According to the mentioned reactions, in order to obtain high N2 selectivity, reactions (11) and (12) should be suppressed. Ichikawa et al. studied the relationship between N2 selectivity and standard enthalpy change of formation per mole of oxygen atom () of the metal oxides. Ichikawa et al. found that the N2 selectivity was high for the catalyst with a low value of and N2 selectivity was low for the catalyst with high value of . For example, Co3O4 with of 60 kcal (mole of O)-1 has the highest N2 selectivity of 90% and MgO with of 140 kcal (mole O)-1 has the lowest N2 selectivity of 20 kcal (mole O)-1 . They claimed that indicates the bond strength between the metal cation (M) and lattice oxygen (M-O) in the metal oxides. Thus, the metal oxides with low value have weak M-O bond strength. This means the weak bond strength between M on the surface and active oxygen (O) formed by the reaction of O3 with the surface. O would be unstable, easy to participate in the NH4+ oxidation. Since NH4Cl was used as a NH4+ source, Cl- in solution could participate in the NH4+ oxidation. Cl- anions could react with O3 to form ClO- which oxidized NH4+ ion to nitrogen [4, 7]. To investigate the stability of the catalysts, we carry out three cycles of catalytic ozonation of NH4+ solution over Fe2O3-Co3O4/dolomite, and the result is presented in Figure 8.
As observed in Figure 8, NH4+ conversion over Fe2O3-Co3O4/dolomite after 3 cycles was slightly decreased, less than 5% as compared to that of the fresh catalyst. N2 selectivity over Fe2O3-Co3O4/dolomite after 3 cycles of reaction decreased only ca. 7-8% as compared to that of the fresh catalyst, while NO3- selectivity slightly increased (ca. 5%). From the obtained result, it could confirm that the Fe2O3-Co3O4/dolomite has high activity stability and it can be reused.
To check the change of structure and morphology of the Fe2O3-Co3O4/dolomite after 3 cycles of reaction, XRD pattern and SEM image of the spent catalyst were performed.
From XRD patterns (Figures 9(a) and 9(b)) and SEM images (Figures 9(c) and 9(d)), it can be seen that the structure and morphology of the spent catalyst were maintained; no change of metal oxide phase as well as agglomerating of metal oxide particles were noted. Based on the above results, the high catalytic activity and stability of the Fe2O3-Co3O4/dolomite catalyst could be proved.
From the obtained results, some conclusions could be drawn.
It was successful to modify dolomite with Fe2O3 by using the “atomic implantation” method. By this method, nano-Fe2O3 particles with small size and high dispersion on dolomite surface were achieved.
It was also successful to modify Fe2O3/dolomite with Co3O4 by the precipitation method. As seen in SEM images, nano-Fe2O3, Co3O4 particles of 80-130 nm with high dispersion on dolomite surface were obtained.
Catalytic performance of activated dolomite, Fe2O3/dolomite, and Fe2O3-Co3O4/dolomite in catalytic ozonation of NH4+ solution was investigated and evaluated. Among three catalysts, Fe2O3-Co3O4/dolomite has the highest NH4+ conversion (96%) and N2 selectivity (77.82%). Selectivity toward N2 over the catalyst can be rationalized by bond strength M-O through the standard enthalpy . The catalyst with low value has higher N2 selectivity. Moreover, the H2 reduction ability also plays an important role in the improvement of N2 selectivity by the reduction of NO3- to N2 gas.
The data used to support the findings of this study are available from the corresponding author upon request.
Conflicts of Interest
The authors declare that they have no conflicts of interest.
The authors thank Vietnam Academy of Science and Technology (VAST.07.01/18−19) and the Institute of Chemistry (VHH. 2019.01.02) for the financial support.
- T.-J. Park, J.-H. Lee, M.-S. Lee et al., “Development of water quality criteria of ammonia for protecting aquatic life in freshwater using species sensitivity distribution method,” Science of the Total Environment, vol. 634, pp. 934–940, 2018.
- G. C. C. Yang and H.-L. Lee, “Chemical reduction of nitrate by nanosized iron: kinetics and pathways,” Water Research, vol. 39, no. 5, pp. 884–894, 2005.
- C. D. Rocca, V. Belgiorno, and S. Meriç, “Overview of in-situ applicable nitrate removal processes,” Desalination, vol. 204, no. 1-3, pp. 46–62, 2007.
- S.-i. Ichikawa, L. Mahardiani, and Y. Kamiya, “Catalytic oxidation of ammonium ion in water with ozone over metal oxide catalysts,” Catalysis Today, vol. 232, pp. 192–197, 2014.
- M. Chen, Y. Wang, T. Liang, J. Yang, and Z. Yang, “Hydrogen production from steam reforming of ethylene glycol over iron loaded on MgO,” in AIP Conference Proceedings, vol. 1794, no. 1, p. 050002, American Institute of Physics, 2017.
- H. Liu, L. Chen, and L. Ji, “Ozonation of ammonia at low temperature in the absence and presence of MgO,” Journal of Hazardous Materials, vol. 376, pp. 125–132, 2019.
- C. Liu, Y. Chen, C. He, R. Yin, J. Liu, and T. Qiu, “Ultrasound-enhanced catalytic ozonation oxidation of ammonia in aqueous solution,” International Journal of Environmental Research and Public Health, vol. 16, no. 12, p. 2139, 2019.
- Y. Chen, Y. Wu, C. Liu et al., “Low-temperature conversion of ammonia to nitrogen in water with ozone over composite metal oxide catalyst,” Journal of Environmental Sciences, vol. 66, no. 265, p. 273, 2018.
- M. Mehmood, “Dolomite and dolomitization model - a short review,” International Journal of Hydrology, vol. 2, no. 5, 2018.
- V. Chaudhary and S. Prasad, “Rapid removal of fluoride from aqueous media using activated dolomite,” Analytical Methods, vol. 7, no. 19, pp. 8304–8314, 2015.
- Y. Salameh, A. B. Albadarin, S. Allen, G. Walker, and M. N. M. Ahmad, “Arsenic(III,V) adsorption onto charred dolomite: charring optimization and batch studies,” Chemical Engineering Journal, vol. 259, pp. 663–671, 2015.
- R. C. R. Santos, R. B. Vieira, and A. Valentini, “Optimization study in biodiesel production via response surface methodology using dolomite as a heterogeneous catalyst,” Journal of Catalysts, vol. 2014, Article ID 213607, 11 pages, 2014.
- I. Belarbi, A. Çoruh, R. Hamacha, K. Marouf-Khelifa, and A. Khelifa, “Development and characterization of a new dolomite-based catalyst: application to the photocatalytic degradation of pentachlorophenol,” Water Science and Technology, vol. 79, no. 4, pp. 741–752, 2019.
- H. Jeong, J. Park, and H. Kim, “Determination of NH4+ in environmental water with interfering substances using the modified Nessler method,” Journal of Chemistry, vol. 2013, Article ID 359217, 9 pages, 2013.
- L. Zhou and C. E. Boyd, “Comparison of Nessler, phenate, salicylate and ion selective electrode procedures for determination of total ammonia nitrogen in aquaculture,” Aquaculture, vol. 450, pp. 187–193, 2016.
- S. N. Hazwani-Oslan, J. S. Tan, M. Z. Saad, M. Halim, and A. B. Ariff, “Improved cultivation of gdhA derivative Pasteurella multocida B:2 for high density of viable cells through in situ ammonium removal using cation-exchange resin for use as animal vaccine,” Process Biochemistry, vol. 56, pp. 1–7, 2017.
- L. M. Correia, N. de Sousa Campelo, D. S. Novaes et al., “Characterization and application of dolomite as catalytic precursor for canola and sunflower oils for biodiesel production,” Chemical Engineering Journal, vol. 269, no. 35, pp. 35–43, 2015.
- T. H. Y. Duong, T. N. Nguyen, H. T. Oanh et al., “Synthesis of magnesium oxide nanoplates and their application in nitrogen dioxide and sulfur dioxide adsorption,” Journal of Chemistry, vol. 2019, Article ID 4376429, 9 pages, 2019.
- T. T. Nguyen, G. H. le, C. H. le et al., “Atomic implantation synthesis of Fe-Cu/SBA-15 nanocomposite as a heterogeneous Fenton-like catalyst for enhanced degradation of DDT,” Materials Research Express, vol. 5, no. 11, 2018.
- H. Xu, Z. Hai, J. Diwu et al., “Synthesis and microwave absorption properties of core-shell structured Co3O4-PANI nanocomposites,” Journal of Nanomaterials, vol. 2015, Article ID 845983, 8 pages, 2015.
- J. Ji, Y. Ge, W. Balsam, J. E. Damuth, and J. Chen, “Rapid identification of dolomite using a Fourier transform infrared spectrophotometer (FTIR): a fast method for identifying Heinrich events in IODP Site U1308,” Marine Geology, vol. 258, no. 1-4, pp. 60–68, 2009.
- S. Gunasekaran and G. Anbalagan, “Thermal decomposition of natural dolomite,” Bulletin of Materials Science, vol. 30, no. 4, pp. 339–344, 2007.
- S. Zhao, S. Niu, H. Yu et al., “Experimental investigation on biodiesel production through transesterification promoted by the La-dolomite catalyst,” Fuel, vol. 257, p. 116092, 2019.
- R. Mahadevaiah, H. S. Lalithamba, S. Shekarappa, and R. Hanumanaika, “Synthesis of Nα-protected formamides from amino acids using MgO nano catalyst: study of molecular docking and antibacterial activity,” Scientia Iranica, vol. 24, no. 6, pp. 3002–3013, 2017.
- R. Suresh, K. Giribabu, R. Manigandan, A. Stephen, and V. Narayanan, “Fabrication of Ni–Fe2O3 magnetic nanorods and application to the detection of uric acid,” RSC Advances, vol. 4, no. 33, pp. 17146–17155, 2014.
- H. T. Vu, M. B. Nguyen, T. M. Vu et al., “Synthesis and application of novel nano Fe-BTC/GO composites as highly efficient photocatalysts in the dye degradation,” Topics in Catalysis, 2020.
- M. Salavati-Niasari, A. Khansari, and F. Davar, “Synthesis and characterization of cobalt oxide nanoparticles by thermal treatment process,” Inorganica Chimica Acta, vol. 362, no. 4937-4942, p. 14, 2009.
- S. A. Makhlouf, Z. H. Bakr, K. I. Aly, and M. S. Moustafa, “Structural, electrical and optical properties of Co3O4 nanoparticles,” Superlattices and Microstructures, vol. 64, pp. 107–117, 2013.
- Y. T. Algoufi, G. Kabir, and B. H. Hameed, “Synthesis of glycerol carbonate from biodiesel by-product glycerol over calcined dolomite,” Journal of the Taiwan Institute of Chemical Engineers, vol. 70, pp. 179–187, 2017.
- X. Wei, Y. Zhou, Y. Li, and W. Shen, “Polymorphous transformation of rod-shaped iron oxides and their catalytic properties in selective reduction of NO by NH3,” RSC Advances, vol. 5, no. 81, pp. 66141–66146, 2015.
- Y. Liu, K. Murata, and M. Inaba, “Steam reforming of bio-ethanol to produce hydrogen over co/CeO2 catalysts derived from Ce1−xCoxO2−y precursors,” Catalysts, vol. 6, no. 2, p. 26, 2016.
- L. Bai, F. Wyrwalski, J.-F. Lamonier, A. Y. Khodakov, E. Monflier, and A. Ponchel, “Effects of β-cyclodextrin introduction to zirconia supported-cobalt oxide catalysts: from molecule-ion associations to complete oxidation of formaldehyde,” Applied Catalysis B: Environmental, vol. 138-139, pp. 381–390, 2013.
- S. Khuntia, S. K. Majumder, and P. Ghosh, “Removal of ammonia from water by ozone microbubbles,” Industrial and Engineering Chemistry Research, vol. 52, no. 1, pp. 318–326, 2013.
Copyright © 2020 Manh B. Nguyen et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.