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Journal of Nanotechnology
Volume 2012 (2012), Article ID 573287, 6 pages
http://dx.doi.org/10.1155/2012/573287
Research Article

Reforming of Ethanol to Produce Hydrogen over PtRuMg/ZrO2 Catalyst

1Department of Chemical and Materials Engineering, Chung Cheng Institute of Technology, National Defense University, Tahsi, Taoyuan 33509, Taiwan
2Fuel Cell Center, Yuan Ze University, Taoyuan 32003, Taiwan
3Department of Mechanical Engineering, Yuan Ze University, Taoyuan 32003, Taiwan
4Graduate School of Renewable Energy and Engineering, Yuan Ze University, Taoyuan 32003, Taiwan

Received 15 March 2012; Accepted 24 April 2012

Academic Editor: Shrikrishna D. Sartale

Copyright © 2012 Josh Y. Z. Chiou et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. A. E. Farrell, R. J. Plevin, B. T. Turner, A. D. Jones, M. O'Hare, and D. M. Kammen, “Ethanol can contribute to energy and environmental goals,” Science, vol. 311, no. 5760, pp. 506–508, 2006. View at Publisher · View at Google Scholar · View at Scopus
  2. B. E. Dale and D. Pimentel, “Two views on whether corn ethanol and, eventually, ethanol from cellulosic biomass will efficiently deliver national energy security,” Chemical & Engineering News, vol. 85, no. 51, pp. 12–16, 2007. View at Google Scholar
  3. Y. Liu, T. Hayakawa, T. Tsunoda et al., “Steam reforming of methanol over Cu/CeO2 catalysts studied in comparison with Cu/ZnO and Cu/Zn(Al)O catalysts,” Topics in Catalysis, vol. 22, no. 3-4, pp. 205–213, 2003. View at Publisher · View at Google Scholar · View at Scopus
  4. P. D. Vaidya and A. E. Rodrigues, “Insight into steam reforming of ethanol to produce hydrogen for fuel cells,” Chemical Engineering Journal, vol. 117, no. 1, pp. 39–49, 2006. View at Publisher · View at Google Scholar
  5. A. Haryanto, S. Fernando, N. Murali, and S. Adhikari, “Current status of hydrogen production techniques by steam reforming of ethanol: a review,” Energy and Fuels, vol. 19, no. 5, pp. 2098–2106, 2005. View at Publisher · View at Google Scholar · View at Scopus
  6. H. Muroyama, R. Nakase, T. Matsui, and K. Eguchi, “Ethanol steam reforming over Ni-based spinel oxide,” International Journal of Hydrogen Energy, vol. 35, no. 4, pp. 1575–1581, 2010. View at Publisher · View at Google Scholar · View at Scopus
  7. M. Ni, D. Y. C. Leung, and M. K. H. Leung, “A review on reforming bio-ethanol for hydrogen production,” International Journal of Hydrogen Energy, vol. 32, no. 15, pp. 3238–3247, 2007. View at Publisher · View at Google Scholar · View at Scopus
  8. J. Llorca, N. Homs, J. Sales, and P. R. de la Piscina, “Efficient production of hydrogen over supported cobalt catalysts from ethanol steam reforming,” Journal of Catalysis, vol. 209, no. 2, pp. 306–317, 2002. View at Publisher · View at Google Scholar · View at Scopus
  9. A. N. Fatsikostas and X. E. Verykios, “Reaction network of steam reforming of ethanol over Ni-based catalysts,” Journal of Catalysis, vol. 225, no. 2, pp. 439–452, 2004. View at Publisher · View at Google Scholar · View at Scopus
  10. P. K. Cheekatamarla and C. M. Finnerty, “Reforming catalysts for hydrogen generation in fuel cell applications,” Journal of Power Sources, vol. 160, no. 1, pp. 490–499, 2006. View at Publisher · View at Google Scholar · View at Scopus
  11. F. Frusteri, S. Freni, L. Spadaro et al., “H2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts,” Catalysis Communications, vol. 5, no. 10, pp. 611–615, 2004. View at Publisher · View at Google Scholar · View at Scopus
  12. C. B. Wang, C. C. Lee, J. L. Bi, J. Y. Siang, J. Y. Liu, and C. T. Yeh, “Study on the steam reforming of ethanol over cobalt oxides,” Catalysis Today, vol. 146, no. 1-2, pp. 76–81, 2009. View at Publisher · View at Google Scholar · View at Scopus
  13. J. Y. Siang, C. C. Lee, C. H. Wang et al., “Hydrogen production from steam reforming of ethanol using a ceria-supported iridium catalyst: effect of different ceria supports,” International Journal of Hydrogen Energy, vol. 35, no. 8, pp. 3456–3462, 2010. View at Publisher · View at Google Scholar · View at Scopus
  14. J. Y. Liu, C. C. Lee, C. H. Wang, C. T. Yeh, and C. B. Wang, “Application of nickel-lanthanum composite oxide on the steam reforming of ethanol to produce hydrogen,” International Journal of Hydrogen Energy, vol. 35, no. 9, pp. 4069–4075, 2010. View at Publisher · View at Google Scholar · View at Scopus
  15. P. D. Vaidya and A. E. Rodrigues, “Kinetics of steam reforming of ethanol over a Ru/Al2O3 catalyst,” Industrial & Engineering Chemistry Research, vol. 45, no. 19, pp. 6614–6618, 2006. View at Google Scholar
  16. J. R. Croy, S. Mostafa, J. Liu, Y. Sohn, H. Heinrich, and B. R. Cuenya, “Support dependence of MeOH decomposition over size-selected Pt nanoparticles,” Catalysis Letters, vol. 119, no. 3-4, pp. 209–216, 2007. View at Publisher · View at Google Scholar · View at Scopus
  17. S. M. de Lima, A. M. Silva, I. O. da Cruz et al., “H2 production through steam reforming of ethanol over Pt/ZrO2, Pt/CeO2 and Pt/CeZrO2 catalysts,” Catalysis Today, vol. 138, no. 3-4, pp. 162–168, 2008. View at Publisher · View at Google Scholar · View at Scopus
  18. J. L. Bi, S. N. Hsu, C. T. Yeh, and C. B. Wang, “Low-temperature mild partial oxidation of ethanol over supported platinum catalysts,” Catalysis Today, vol. 129, no. 3, pp. 330–335, 2008. View at Google Scholar
  19. S. N. Hsu, J. L. Bi, W. F. Wang, C. T. Yeh, and C. B. Wang, “Low-temperature partial oxidation of ethanol over supported platinum catalysts for hydrogen production,” International Journal of Hydrogen Energy, vol. 33, no. 2, pp. 693–699, 2008. View at Publisher · View at Google Scholar · View at Scopus
  20. J. L. Bi, Y. Y. Hong, C. C. Lee, C. T. Yeh, and C. B. Wang, “Novel zirconia-supported catalysts for low-temperature oxidative steam reforming of ethanol,” Catalysis Today, vol. 129, no. 3-4, pp. 322–329, 2007. View at Publisher · View at Google Scholar
  21. C. H. Wang, K. F. Ho, and J. Y. Z. Chiou, “Oxidative steam reforming of ethanol over PtRu/ZrO2 catalysts modified with sodium and magnesium,” Catalysis Communications, vol. 12, no. 10, pp. 854–858, 2011. View at Publisher · View at Google Scholar
  22. L. V. Mattos and F. B. Noronha, “Partial oxidation of ethanol on supported Pt catalysts,” Journal of Power Sources, vol. 145, no. 1, pp. 10–15, 2005. View at Publisher · View at Google Scholar · View at Scopus
  23. A. J. Vizcaino, A. Carrero, and J. A. Calles, “Hydrogen production by ethanol steam reforming over Cu-Ni supported catalysts,” International Journal of Hydrogen Energy, vol. 32, no. 10-11, pp. 1450–1461, 2007. View at Publisher · View at Google Scholar
  24. F. Frusteri, S. Freni, V. Chiodo et al., “Steam reforming of bio-ethanol on alkali-doped Ni/MgO catalysts: hydrogen production for MC fuel cell,” Applied Catalysis A, vol. 270, no. 1-2, pp. 1–7, 2004. View at Publisher · View at Google Scholar · View at Scopus
  25. J. Sun, X. P. Qiu, F. Wu, and W. T. Zhu, “H2 from steamreforming of ethanol at low temperature over Ni/Y2O3, Ni/La2O3 and Ni/Al2O3 catalysts for fuel-cell application,” International Journal of Hydrogen Energy, vol. 30, no. 4, pp. 437–445, 2005. View at Google Scholar
  26. A. Carrero, J. A. Calles, and A. J. Vizcaino, “Effect of Mg and Ca addition on coke deposition over Cu-Ni/SiO2 catalysts for ethanol steam reforming,” Chemical Engineering Journal, vol. 163, no. 3, pp. 395–402, 2010. View at Google Scholar
  27. A. N. Fatsikostas, D. I. Kondarides, and X. E. Verykios, “Production of hydrogen for fuel cells by reformation of biomass-derived ethanol,” Catalysis Today, vol. 75, no. 1–4, pp. 145–155, 2002. View at Publisher · View at Google Scholar · View at Scopus
  28. L. F. de Mello, F. B. Noronha, and M. Schmal, “NO reduction with ethanol on Pd-Mo/Al2O3 catalysts,” Journal of Catalysis, vol. 220, no. 2, pp. 358–371, 2003. View at Publisher · View at Google Scholar · View at Scopus
  29. M. A. Goula, S. K. Kontou, and P. E. Tsiakaras, “Hydrogen production by ethanol steam reforming over a commercial Pd/γ-Al2O3 catalyst,” Applied Catalysis B, vol. 49, no. 2, pp. 135–144, 2004. View at Publisher · View at Google Scholar · View at Scopus
  30. P. Lespade, A. Marchand, M. Couzi, and F. Cruege, “Caracterisation de materiaux carbones par microspectrometrie Raman,” Carbon, vol. 22, no. 4-5, pp. 375–385, 1984. View at Google Scholar · View at Scopus