Review Article

Nanocrystalline Metal Oxides for Methane Sensors: Role of Noble Metals

Figure 11

(a) The sensitivities of S n O 2 -based sensors having various combinations of additivities (Ca and Pt) and alumina supported metal catalysts (Pd and Pt) to methane at 658 K as a function of methane concentration. The additivities (0.1 wt.%) were added to S n O 2 by a coprecipitation method, while the supported catalysts (5 wt.%) were mixed with S n O 2 powder. ( 1 ) S n O 2 (pure), ( 2 ) S n O 2 (Ca), ( 3 ) S n O 2 (Ca, Pt), ( 4 ) S n O 2 (pure) + Pt:alumina, ( 5 ) S n O 2 (pure) + Pd:alumina, and ( 6 ) S n O 2 (Ca,Pt) + Pd:alumina. (b) Influences of Pd loading methods on the methane sensitivities at 658 K (net Pd loading: 0.25 wt.%). ( 1 ) Impregnation from Pd C l 2 solution. ( 2 ) Physical mixing of Pd black. ( 3 ) Rinsing method. ( 4 ) Physical mixing of Pd: alumina.
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