Journal of Soft Matter / 2014 / Article / Tab 4

Research Article

Kinetic Treatment of the Reaction of Fructose and N-Bromosuccinimide in Cationic/Anionic/Nonionic Micelles

Table 4

Effect of surfactants on .

103, CTAB mol dm−3104,  s−1102, SDS mol dm−3104,  s−1

01.1101.11
0.21.250.21.02
0.41.310.41.0
0.61.500.60.97
0.82.160.750.93
1.02.900.80.91
1.23.501.00.86
1.42.401.10.84
1.62.01.20.81
1.81.721.40.78
1.6
Other parameters
, s−1 (10−4)1.071.31
( + ), dm3 mol−1 (10−6)2.573.41

Reaction conditions: fructose = 2.5 10−2 mol dm−3, NBS = 2.0 10−4 mol dm−3, [H2SO4] = 0.5 10−4 mol dm−3, Hg(OAc)2 = 5.0 10−4 mol dm−3, 30% acetic acid (v/v), and temperature 40°C.