Journal of Spectroscopy

Journal of Spectroscopy / 2010 / Article
Special Issue

From Molecule to Tissue: XIII European Conference on the Spectroscopy of Biological Molecules, Palermo, Italy, August 28–September 2, 2009, Part 2 of 2

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Volume 24 |Article ID 872050 | https://doi.org/10.3233/SPE-2010-0451

Marie-Claire Dhamelincourt, Marco Vecoli, Alberto Mezzetti, Christian Cesari, Gerard Versteegh, Armelle Riboulleau, "Laser Raman micro-spectroscopy of Proterozoic and Palaeozoic organic-walled microfossils (acritarchs and prasinophytes) from the Ghadamis Basin, Libya and Volta Basin, Ghana", Journal of Spectroscopy, vol. 24, Article ID 872050, 6 pages, 2010. https://doi.org/10.3233/SPE-2010-0451

Laser Raman micro-spectroscopy of Proterozoic and Palaeozoic organic-walled microfossils (acritarchs and prasinophytes) from the Ghadamis Basin, Libya and Volta Basin, Ghana

Abstract

Laser Raman microspectroscopy was used as a microchemical analysis technique to characterize the wall chemistry of organic-walled microfossils (acritarchs and prasinophytes) extracted from Proterozoic (Tonian: ca. 900 Myr) and early Palaeozoic (Silurian: ca. 420 Myr) marine sediments in the Volta Basin of Ghana, and the Ghadamis Basin of Libya, respectively. Raman spectra of Proterozoic acritarchs show spectral features characteristic of kerogenous compounds at ~1350 and ~1600 cm−1, consistently with previously published reports. In addition, spectra from prasinophyte algae from the Silurian sample also show an interesting spectral feature at ~1707 cm−1 indicative of carbonyl moieties.Broadly speaking, shape and position of Raman bands appear to depend on the nature of the specimen considered, suggesting that laser micro-Raman analysis can potentially be used to establish phylogenetic relationships (high-rank taxonomy) among the main groups of pre-Cambrian to Palaeozoic palynomorphs.

Copyright © 2010 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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