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Journal of Spectroscopy
Volume 2015, Article ID 289298, 7 pages
http://dx.doi.org/10.1155/2015/289298
Research Article

Study of the Synergistic Effect of Nanoporous Nickel Phosphates on Novel Intumescent Flame Retardant Polypropylene Composites

1Key Laboratory of Safety and High Efficiency Coal Mining Ministry of Education, School of Mining and Safety Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China
2IMDEA Materials Institute, C Eric Kandel 2, 28906 Madrid, Spain
3Integrated Composites Laboratory (ICL), Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, TX 77710, USA

Received 29 October 2014; Revised 29 December 2014; Accepted 12 January 2015

Academic Editor: Luciano Bachmann

Copyright © 2015 Shibin Nie et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. Y. Liu, J. Yi, and X. Cai, “The investigation of intumescent flame-retarded polypropylene using poly(hexamethylene terephthalamide) as carbonization agent,” Journal of Thermal Analysis and Calorimetry, vol. 107, no. 3, pp. 1191–1197, 2012. View at Publisher · View at Google Scholar · View at Scopus
  2. H. L. Vandersall, “Intumescent coating systems, their development and chemistry,” Journal of Fire and Flammability, vol. 1, no. 2, pp. 97–140, 1970. View at Google Scholar · View at Scopus
  3. G. Camino, L. Costa, L. Trossarelli, F. Costanzi, and A. Pagliari, “Study of the mechanism of intumescence in fire retardant polymers: part VI-Mechanism of ester formation in ammonium polyphosphate-pentaerythritol mixtures,” Polymer Degradation and Stability, vol. 12, no. 3, pp. 213–228, 1985. View at Publisher · View at Google Scholar · View at Scopus
  4. S. Nie, C. Peng, S. Yuan, and M. Zhang, “Thermal and flame retardant properties of novel intumescent flame retardant polypropylene composites,” Journal of Thermal Analysis and Calorimetry, vol. 113, no. 2, pp. 865–871, 2013. View at Publisher · View at Google Scholar · View at Scopus
  5. S. B. Nie, S. H. Qi, M. S. He, and B. Li, “Synergistic effects of zeolites on a novel intumescent flame-retardant low-density polyethylene (LDPE) system,” Journal of Thermal Analysis and Calorimetry, vol. 114, no. 2, pp. 581–587, 2013. View at Publisher · View at Google Scholar · View at Scopus
  6. C. M. Feng, Y. Zhang, S. W. Liu, Z. Chi, and J. Xu, “Synergistic effects of 4A zeolite on the flame retardant properties and thermal stability of a novel halogen-free PP/IFR composite,” Polymers for Advanced Technologies, vol. 24, no. 5, pp. 478–486, 2013. View at Publisher · View at Google Scholar · View at Scopus
  7. S. Bourbigot, M. Le Bras, R. Delobel, and J.-M. Trémillon, “Synergistic effect of zeolite in an intumescence process: study of the interactions between the polymer and the additives,” Journal of the Chemical Society: Faraday Transactions, vol. 92, no. 18, pp. 3435–3444, 1996. View at Publisher · View at Google Scholar · View at Scopus
  8. K. Q. Zhou, S. H. Jiang, B. B. Wang et al., “Combined effect of transition metal phosphide (MxPy, M=Ni, Co, and Cu) and intumescent flame retardant system on polypropylene,” Polymers for Advanced Technologies, vol. 25, no. 7, pp. 701–710, 2014. View at Publisher · View at Google Scholar · View at Scopus
  9. D. Liu, G. Cai, J. Wang et al., “Thermal and flammability performance of polypropylene composites containing melamine and melamine phosphate-modified α-type zirconium phosphates,” Journal of Applied Polymer Science, vol. 131, no. 10, Article ID 40254, 2014. View at Publisher · View at Google Scholar · View at Scopus
  10. M. Lewin and M. Endo, “Catalysis of intumescent flame retardancy of polypropylene by metallic compounds,” Polymers for Advanced Technologies, vol. 14, no. 1, pp. 3–11, 2003. View at Publisher · View at Google Scholar · View at Scopus
  11. N. Guillou, Q. Gao, M. Nogues et al., “Zeolitic and magnetic properties of a 24-membered ring porous nickel(II) phosphate, VSB-1,” Comptes Rendus de l'Academie des Sciences—Series IIC: Chemistry, vol. 2, no. 7-8, pp. 387–392, 1999. View at Publisher · View at Google Scholar · View at Scopus
  12. S. Nie, Y. Hu, L. Song, S. He, and D. Yang, “Study on a novel and efficient flame retardant synergist-nanoporous nickel phosphates VSB-1 with intumescent flame retardants in polypropylene,” Polymers for Advanced Technologies, vol. 19, no. 6, pp. 489–495, 2008. View at Publisher · View at Google Scholar · View at Scopus
  13. S. Nie, Y. Hu, L. Song, Q. He, D. Yang, and H. Chen, “Synergistic effect between a char forming agent (CFA) and microencapsulated ammonium polyphosphate on the thermal and flame retardant properties of polypropylene,” Polymers for Advanced Technologies, vol. 19, no. 8, pp. 1077–1083, 2008. View at Publisher · View at Google Scholar · View at Scopus
  14. “Toxic classification of fire effluents hazard for materials,” Tech. Rep. GB/T20285-2006, 2006.
  15. S. Bourbigot, M. Le Bras, R. Delobel, P. Bréant, and J.-M. Trémillon, “Carbonization mechanisms resulting from intumescence-part II. Association with an ethylene terpolymer and the ammonium polyphosphate-pentaerythritol fire retardant system,” Carbon, vol. 33, no. 3, pp. 283–294, 1995. View at Publisher · View at Google Scholar · View at Scopus
  16. G. Camino, L. Costa, L. Trossarelli, F. Costanzi, and G. Landoni, “Study of the mechanism of intumescence in fire retardant polymers: part IV—evidence of ester formation in ammonium polyphosphate-pentaerythritol mixtures,” Polymer Degradation and Stability, vol. 8, no. 1, pp. 13–22, 1984. View at Publisher · View at Google Scholar · View at Scopus
  17. S. V. Levchik, G. Camino, L. Costa, and G. F. Levchik, “Mechanism of action of phosphorus-based flame retardants in nylon 6. I. Ammonium polyphosphate,” Fire and Materials, vol. 19, no. 1, pp. 1–10, 1995. View at Publisher · View at Google Scholar · View at Scopus
  18. M. Bugajny, S. Bourbigot, M. le Bras, and R. Delobel, “The origin and nature of flame retardance in ethylene-vinyl acetate copolymers containing hostaflam AP 750,” Polymer International, vol. 48, no. 4, pp. 264–270, 1999. View at Publisher · View at Google Scholar · View at Scopus
  19. B. B. Wang, Q. L. Tai, S. B. Nie et al., “Electron beam irradiation cross linking of halogen-free flame-retardant ethylene vinyl acetate (EVA) copolymer by silica gel microencapsulated ammonium polyphosphate and char-forming agent,” Industrial and Engineering Chemistry Research, vol. 50, no. 9, pp. 5596–5605, 2011. View at Publisher · View at Google Scholar · View at Scopus