Quantification of Tremolite in Friable Material Coming from Calabrian Ophiolitic Deposits by Infrared Spectroscopy

Campopiano, Antonella; Olori, Angelo; Cannizzaro, Annapaola; Iannò, Antonino; Capone, Pietro Paolo

doi:https://doi.org/10.1155/2015/974902

Journal of Spectroscopy

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Research Article | Open Access

Volume 2015 | Article ID 974902 | https://doi.org/10.1155/2015/974902

Quantification of Tremolite in Friable Material Coming from Calabrian Ophiolitic Deposits by Infrared Spectroscopy

Antonella Campopiano,¹Angelo Olori,¹Annapaola Cannizzaro,¹Antonino Iannò,²and Pietro Paolo Capone³

Academic Editor: Petre Makreski

Received29 Apr 2015

Accepted14 Jul 2015

Published05 Aug 2015

Abstract

The aim of this study is to identify the infrared absorption band suitable for quantifying tremolite in three powdered samples (fine, medium, and large size classes) coming from a quarry of ophiolitic friable rocks in the western part of the Calabria region of Italy. Three IR bands were considered: OH stretching band between 3700 and 3650 cm⁻¹, the stretching bands of the Si-O-Si linkage between 1200 and 900 cm⁻¹, and the absorbance band at 756 cm⁻¹ attributable to tremolite. The amount of tremolite in the test samples was quantified by using the curve parameters of the three analytical bands. The quantitative analysis of tremolite using the band due to OH stretchings (3700–3650 cm⁻¹) and the bands attributed to the Si-O-Si stretchings (1200–900 cm⁻¹) showed high values for all test samples. Their use overestimated the tremolite amount because both bands were affected at the interfering mineral silicates such as talc, kaolinite, chlorite, and serpentinites. The abundant presence of antigorite in studied samples mainly in medium size class sample had a key role in our findings. The band at 756 cm⁻¹ was not affected at the interfering minerals and can be used for quantitative analysis of tremolite in sample coming from ophiolitic deposits.

1. Introduction

The ophiolites, commonly known as greenstones due to their typical colouring, may contain asbestos; they represent a grouping of rocks of magmatic origin which characterise, in the form of outcrops, numerous areas in almost all continents and have long been the subject of interest of researchers for their geological and petrographic aspects. In Italy, the presence of numerous deposits is confirmed in the Alps and mainly along the Apennines. These outcrops extend from the Ligurian-Piedmont through the Tuscan-Emilian Apennines as far as Val Tiberina and continue, in disjointed groupings, to the Calabrian-Lucan Apennines [1].

Calabrian ophiolites are an important mineralogical and economical resource. The fibrous variety of asbestos found in these sites is tremolite [2–4].

Due to the presence of natural asbestos in ophiolite outcrops, characterization of the asbestos minerals extracted during excavation phases of the construction projects, as well as the development of analytical procedures for an effective characterization of the asbestos hazard, is needed.

In this study, we propose an investigation of three infrared absorption bands for the quantitative determination of tremolite in the material used as inert filler coming from a quarry of ophiolitic friable rocks in the west of the Calabria region of Italy. The first infrared band is in the region of OH group stretching vibration; the other two IR bands are associated with stretching Si-O-Si and O-Si-O vibration. The data allowed for identifying the most indicative IR absorption band for quantifying tremolite in samples coming from ophiolitic deposits.

2. Materials and Methods

Test samples containing tremolite came from a quarry of ophiolitic friable rocks in the neighbouring of Platania, town in the province of Catanzaro in the western part of the Calabria region (Italy).

The material produced was used as inert filler.

The production of the friable material was subdivided into two phases; the first took place directly in the quarry with selection of raw material and the second occurred at the crushing and shifting plant where the material, transported from the greenstone quarry, was unloaded inside the hopper and crushed. Next it was moved by a belt conveyor to vibrating sieves where it was subdivided into three homogeneous size classes: fine, medium, and large. The final processing phase consisted of loading the material for transport onto motor vehicles. It is worth noting that the crushing and sizing plant was equipped with a clarification system of recycled water and mud.

Samples from each of the three size classes were analysed by scanning electron microscopy (SEM, LEO 440) complete with energy dispersive X-ray spectroscopy (EDS, Oxford Instrument INCA) and FTIR (Spectrum one, Perkin Elmer) to identify the tremolite. In order to know the amount of tremolite in three size classes of materials by FTIR, a calibration curve was necessary to set up by plotting the intensity of the absorption peaks as a function of the known concentration of pure tremolite.

In nature, tremolite is close in composition to its ideal end-member formula, although it can incorporate appreciable amounts of extra Mg as a result of Mg substitution for Ca and Na, K, Fe, Al, and F are always present in small amounts [5]. The variability in composition is a direct consequence of the fact that the structure can accommodate many different ions in the space between the silica ribbons, which form the fibers, and that the variable nature of the host rocks can contribute different ions to this structure [6].

For this reason, it was decided to use the powderous phase of friable rock coming from San Mango, a town near the studied quarry, as standard sample.

It was showed [2] that the samples of San Mango area had two distinct phases: the first one was white and the second one green with compact nature. SEM and FTIR analysis showed that the white powdered phase was tremolite.

To use the white phase of the mineral as standard sample, a careful separation of white phase from that green one was necessary by the stereomicroscope (Leica M205C).

Tapping slightly the mineral sample with spatula, the white phase fell down heavily and it was collected on a porcelain crucible. The coarse impurities were detected and removed by stereomicroscope. The collected powder was heat-treated in a muffle furnace (Gefran 400) at 450°C for 12 hours. The sample was analyzed by FTIR and by SEM-EDS. The analysis confirmed that the powder was tremolite.

Ten powdered samples of tremolite were weighted by a Sartorius scale (MC1, capacity 210 g, precision 0.01 mg, Sartorius AG) equipped with a device to neutralize electrostatic charges. The weighted quantities were in the range of 50 μg–1 mg. A quantity equal to 3 mg of each sample was mixed with about 250 mg of pure KBr previously dried at 120°C in an oven (Falc Instruments) for 12 hours. Ten transparent pellets of diameter 13 mm were obtained by applying a force-weight of 10 tons for about two minutes.

IR absorbance was recorded from 4000 to 400 cm⁻¹. Before analyzing the samples, spectrum acquisition of a blank consisting of a pure KBr pellet was performed. The analyses were carried out with the following operating conditions: 4000–400 cm⁻¹ acquisition interval, 4 cm⁻¹ resolution, and 32 scans. The use of a resolution of 4 cm⁻¹ was suitable for a good separation of the bands in the spectra. The optical compartment of the instrument was flushed with nitrogen before starting sample analysis. Before each scan, the sample compartment has been saturated with the same gas for about ten minutes to clean the air.

The chosen bands for quantitative analysis were between 3700 and 3650 cm⁻¹, 1200 and 900 cm⁻¹, and the band around 756 cm⁻¹.

Calibration curves were built with ten analytical points for each analytical band, by plotting the net area of the band integrated from the baseline to its minimum of absorption.

Test samples coming from three size classes, fine, medium, and large, with unknown content of tremolite, were ground using an agate mortar with some drops of absolute ethanol for analysis for reducing mechanical stress and for obtaining a particle size around 1-2 μm.

For an accurate quantitative analysis by FTIR, the particle size should not exceed 2.5 μm. In general, under this value, the scattering losses can be ignored [7]. The particle size was checked by SEM observations.

Five pellets were realized for each size class sample. The two worst pellets, which showed inhomogeneities, lesions, opacities, or imperfections, were rejected. Six IR spectrum acquisitions were performed for each of the remaining three pellets, three for each pellet side in order to mediate possible inhomogeneities invisible with naked eye. An average area and deviation standard of each studied IR band was obtained. The three average areas were used to calculate an area-weighted average of the IR band. The analytical procedure employs weighting factors which serve to take into account the accuracy of measurement . Statistical theory shows that the variance of the weighted average is minimized when the individual weights are taken as the inverse of the variance of the individual measurement [8]. Low weights are given to values with high variance.

It is assumed that the best estimate of band area is area-weighted average with a standard error :where the weighted factor is

3. Results and Discussion

An essential feature of amphibole structure is a double chain of corner-linked silicon-oxygen (SiO₄)⁴⁻ tetrahedrons that extend indefinitely parallel to the c crystallographic axis, the direction of elongation. The tetrahedrons alternately share two and three oxygen atoms to produce a silicon-to-oxygen ratio of 4 : 11. The structure contains, besides the tetrahedral sites that constitute the chains, additional cation sites labeled A, M4, M3, M2, and M1. In amphibole, the M1, M2, and M3 sites are octahedral and occupied by Mg²⁺ and Fe²⁺, while the M4 sites are typically occupied by Ca²⁺ and A-sites may be occupied by Na⁺ or be vacant.

Several studies of amphiboles have addressed the role of cation occupancy of the M1, M3, and A-sites on the position of OH infrared absorption bands, very useful in the discrimination between the members of the same series (e.g., tremolite-actinolite).

The chemical composition of amphiboles is not necessarily fixed due to the possibility to form solid solution series with other minerals being their end-members.

Calcic amphiboles crystallize in the monoclinic crystal system [9]. Tremolite is a calcic amphibole with ideal formula Ca₂Mg₅Si₈O₂₂(OH)₂. It is an end-member of the tremolite-ferroactinolite series. Term tremolite is used when the ratio Mg/(Mg + Fe²⁺) ≥ 0.90, actinolite when the ratio Mg/(Mg + Fe²⁺) is between 0.50 and 0.90, and ferroactinolite when the ratio Mg/(Mg + Fe²⁺) < 0.50 [10, 11].

Both vibrational spectra of tremolite and actinolite proved difficult to discriminate in the 1300–400 cm⁻¹ spectral region while in the region of hydroxyl group stretching vibrations (3700–3600 cm⁻¹) these spectra are different and prove more easily distinguishable.

The first IR band used for quantifying tremolite was in the range of 3700–3650 cm⁻¹.

According to Della Ventura et al. [12–14] and Hawthorne et al. [15], in the 3700–3600 cm⁻¹ spectral region, the hydroxyl group-metal ion bonds are present. This means that the substitution of different cations can be seen in this spectral region where the disappearing, shifting, and splitting of the bands are used in order to gain information about cation ordering, as well as supplementary details necessary in the discrimination between the minerals from the same series.

Depending on the presence and/or the absence of Fe²⁺ in M1 and M3 sites, the number of bands of the OH stretching region could range from one in tremolite up to four in ferroactinolite samples [16, 17]. The data from the literature [18] assign the weak band around 3660 cm⁻¹ to the presence of Mg in M1 sites and of Fe²⁺ in the M3 site and the stronger band at 3675 cm⁻¹ to the (3 Mg²⁺)-OH vibration (where the Mg²⁺ ion is present in all nearest-neighbour octahedral sites, i.e., M1, M2, and M3).

The shifting of the OH stretching bands towards a lower frequency, starting the replacement of Mg²⁺ by Fe²⁺ in configuration, is correlated with an increase of the electronegativity of the substituting element [19, 20].

According to Kasir et al. [21], for amphiboles, well-established correlation exists between OH stretching frequency and chemical formula of the different M-cations bonded to hydroxyl. For example, for each Fe²⁺ substituting for Mg at M1 and M3 sites, there is a decrease in OH wave number of 15 cm⁻¹. Similarly for each Al substituting for Mg, there is a reduction of 20 to 30 cm⁻¹. The value of OH stretching wave number is also affected by the contents of Na.

The second spectral band between 1200 and 900 cm⁻¹ chosen for quantifying tremolite is assigned to the asymmetric stretching of the Si-O-Si and O-Si-O vibrations [10, 22–28].

For the lower region (775–600 cm⁻¹), the vibrations observed in this spectral domain are assigned to the symmetric stretching of the Si-O-Si linkage [23, 24]. Moreover, in this spectral range, additional bending modes of the OH group [23] and of the Si-O-Si may appear [29].

Figure 1 shows some among the tremolite standard spectra used to set up the calibration curve.

Besides the typical tremolite absorption band at 3675–3673 cm⁻¹ assigned to the vibration of the O-H dipole bonded to three Mg cations [12–14, 30–35], a well-developed band is observed at 3660 cm⁻¹. This latter was attributed to the Fe²⁺ environment [22]. Moreover, no Fe³⁺ is present because absorption bands at cm⁻¹ from tremolite reference band are absent [36].

The presence of Fe is confirmed by EDS spectrum shown in Figure 2 with SEM image of sample used as standard.

(a)

(b)

In the spectral range between 1200 and 900 cm⁻¹, the main absorption band system is found, consisting of partly overlapping bands. This absorption band system has several shoulders and peaks near 1100, 1060, 1000, and 950 cm⁻¹ and is attributed to Si-O and Si-O-Si stretching. Another, but less intense, band system is observed in the region between 775 and 600 cm⁻¹. The absorbance peak at 756 cm⁻¹ that is one of the wave numbers attributable to tremolite [37–41] was the third band chosen for quantifying tremolite.

In Table 1, assignment of the bands observed in IR spectra (wavenumbers, cm⁻¹) of tremolite used as standard sample is showed.

Using the three bands mentioned above, linear calibration graphs were established by the method of band area.

The basis for quantitative analysis of absorbance spectrometry is Lambert-Beer law. For a single compound in a homogeneous medium, the absorbance at any frequency is expressed as where is the measured sample absorbance at the given frequency, is the molecular absorptivity, is the absorption path length (pellet thickness), and is the concentration of the substance.

It is known that [42] Lambert-Beer law is restricted to monochromatic light, noninteracting absorbers, very dilute solutions, absence of a Christiansen effect [43], particle size smaller than wavelength used, absence of scattering, linearity of the detector, and the assumption that the slits are infinitely small. Despite all these restrictions, it has been empirically demonstrated [42, 44–47] that the mid-IR absorbance of properly ground (≈2 μm), evenly dispersed minerals at low concentration (on the order of 0.2–0.3%) in a KBr pellet shows a linear correlation with concentration.

The linear calibration graphs calculated for the three analytical bands of tremolite are shown in Figures 3, 4, and 5 with the parameters of their linear regression equation. The amount of tremolite in the test samples was quantified by using the curve parameters of the three analytical bands.

Figures 6, 7, and 8 show IR absorption band of three size class samples.

The unknown concentration of tremolite in the test samples was determined by using the area-weighted average with a standard error .

Tables 2, 3, and 4 show the weight concentrations of tremolite detected for each size class sample and each analytical band with the corresponding standard error.

The quantitative analysis of tremolite using OH stretching band between 3700 and 3650 cm⁻¹ and the Si-O-Si and O-Si-O stretching band between 1200 and 900 cm⁻¹ gave high amount of tremolite, with unlikely values for medium size class sample.

In the medium class size sample, the absorption band between 3700 and 3650 cm⁻¹ gave an amount of tremolite above 100%, improbable value. This suggested that agglomeration of fibers or particles of interfering minerals with asbestos was a significant source of error.

The three size class samples were observed by optical microscopy (DM2500P, Leica) and the fine size class sample had the appearance of fine fibrils and needle-like fibers with diameter around 0.2 μm having optical properties consistent with tremolite. Similar fibers were found also in the other two samples. SEM analysis confirmed the fibers nature as tremolite in three samples. An example of fibrous tremolite is shown in Figure 9(a) with corresponding EDS (Figure 9(b)).

(a)

(b)

The medium size class sample differed from other two samples for the presence of several prismatic fibers and acicular fibers having optical properties different from tremolite. Optical properties of such fibers were consistent with antigorite and SEM analysis gave the only presence of magnesium and silicon. Figure 10 shows an example of prismatic fibers in the medium class size sample.

The obtained IR spectrum of the medium size class sample confirmed the presence of antigorite.

In the region of OH stretching vibration, the 3678 cm⁻¹ peak appeared and a shoulder was also evident at 3697 cm⁻¹ [48–50] (Figure 6).

In the region of tetrahedral sheet stretching vibration, the most evident band occurred at 980 cm⁻¹ and another one at higher energy, near to 1080 cm⁻¹ [48, 50, 51] (Figure 7). The presence of antigorite was detected also for other two size class samples but in smaller quantities.

4. Conclusions

Spectroscopic methods are widely used in the quantitative analysis of asbestos. The validity of the quantitative information depends on the history of the sample.

The quantitative analysis of tremolite using OH stretching band between 3700 and 3650 cm⁻¹ and the Si-O-Si and O-Si-O stretching band between 1200 and 900 cm⁻¹ gave high amount of tremolite, with unlikely values for medium size class sample.

The sharp peak of the hydroxyl doublet at 3690 cm⁻¹ is used traditionally for quantitative analysis of chrysotile asbestos. In this range, other serpentine minerals of related structure (e.g., kaolinite, antigorite) show very similar absorption bands and their presence overestimates any asbestos determination based on the infrared absorption in this region.

The major broad bands of silicate materials, quartz and chlorite, are present also in the 1200–900 cm⁻¹ range and it is impossible to select a tremolite characteristic absorption peak relatively free from interference. The unlikely values of tremolite obtained for the medium size class sample are due to the abundant presence of antigorite.

Examination of tremolite fibers detectable by optical microscopy allowed a rough visual estimation that made the amount of tremolite obtained using IR absorption peak at 756 cm⁻¹ (fingerprint region) more likely. The latter is not affected at the interfering minerals and can be used for quantitative analysis in sample coming from ophiolitic deposits.

It should be noted that the medium size class sample has the higher content of tremolite. The optical microscopy observations performed on all samples had visually confirmed it. Tremolite was present both as acicular and as prismatic. We do not know how many of these prismatic tremolites were produced during comminution process. It is known that comminution of amphibole minerals during crushing or grinding may produce structures known as cleavage fragments, some of which may appear as acicular or needle-like crystals because of the way in which amphibole minerals cleave. These structures are considered nonasbestiform fibers. OSHA defines cleavage fragments as mineral particles formed during ore milling, characterized by relatively parallel sides and low aspect ratios [52]. The question of the relative toxicity of asbestiform tremolite and fibrous fragments (cleavage fragments) or prismatic tremolite and their significance as possible health hazards is not yet resolved. The precautionary principle prompts the use of the same prevention measures with nonasbestiform fibres (cleavage fragments) as with asbestiform fibres of the same size.

IR technique is capable of analysing the total, fibrous plus nonfibrous, components; only electron microscopy could be expected to identify and determine the fibrous amphibole content.

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

References

E. Abbate, V. Bortolotti, and G. Principi, “Apennine ophiolites: a peculiar oceanic crust,” in Tethyan Ophiolites, G. Rocci, Ed., Special Issue 1, pp. 59–96, Western Areas, Ofioliti, 1980.
View at: Google Scholar
A. Campopiano, A. Olori, A. M. Zakrzewska, P. P. Capone, and A. Iannò, “Chemical-mineralogical characterisation of greenstone from San Mango d'Aquino,” Prevention Today, vol. 5, pp. 25–38, 2009.
View at: Google Scholar
S. Silvestri, A. Veraldi, M. Falcone et al., “Serpentine and amphiboles in Calabria: preliminary results of a monitoring programme in the general environment and in the workplace,” Epidemiologia e Prevenzione, vol. 29, no. 5-6, pp. 63–64, 2005.
View at: Google Scholar
A. M. Zakrzewska, P. P. Capone, A. Iannò et al., “Calabrian ophiolites: dispersion of airborne asbestos fibers during mining and milling operations,” Periodico di Mineralogia, vol. 77, no. 2, pp. 27–34, 2008.
View at: Publisher Site | Google Scholar
K. N. Bozhilov and D. M. Jenkins, “Analytical electron microscopy of tremolite,” in Modern Research and Educational Topics in Microscopy, A. Méndez-Vilas and J. Díaz, Eds., vol. 2, pp. 616–625, 2007.
View at: Google Scholar
S. Speil and J. P. Leineweber, “Asbestos minerals in modern technology,” Environmental Research, vol. 2, no. 3, pp. 166–208, 1969.
View at: Publisher Site | Google Scholar
Z. Xu, B. C. Cornilsen, D. C. Popko, W. D. Pennington, J. R. Wood, and J.-Y. Hwang, “Quantitative mineral analysis by FTIR spectroscopy,” Internet Journal of Vibrational Spectroscopy, vol. 5, no. 4, 2001.
View at: Google Scholar
R. C. Paule and J. Mandel, “Consensus values and weighting factors,” Journal of Research of the National Bureau of Standards, vol. 87, no. 5, pp. 377–385, 1982.
View at: Publisher Site | Google Scholar
F. C. Hawthorne, “The crystal chemistry of the amphiboles,” Canadian Mineralogist, vol. 21, no. 2, pp. 173–480, 1983.
View at: Google Scholar
P. Makreski, G. Jovanovski, and A. Gajović, “Minerals from Macedonia: XVII. Vibrational spectra of some common appearing amphiboles,” Vibrational Spectroscopy, vol. 40, no. 1, pp. 98–109, 2006.
View at: Publisher Site | Google Scholar
P. Roth, “The early history of tremolite,” Axis, vol. 2, no. 3, pp. 1–10, 2006.
View at: Google Scholar
G. Della Ventura, J.-L. Robert, and F. C. Hawthorne, “Characterization of OH-F short-range order in potassium-fluor-richterite by infrared spectroscopy in the OH-stretching region,” Canadian Mineralogist, vol. 36, no. 1, pp. 181–185, 1998.
View at: Google Scholar
G. Della Ventura, F. C. Hawthorne, J.-L. Robert, F. Delbove, M. F. Welch, and M. Raudsepp, “Short-range order of cations in synthetic amphiboles along the richterite-pargasite join,” European Journal of Mineralogy, vol. 11, no. 1, pp. 79–94, 1999.
View at: Publisher Site | Google Scholar
G. Della Ventura, F. C. Hawthorne, J.-L. Robert, and G. Iezzi, “Synthesis and infrared spectroscopy of amphiboles along the tremolite-pargasite join,” European Journal of Mineralogy, vol. 15, no. 2, pp. 341–347, 2003.
View at: Publisher Site | Google Scholar
F. C. Hawthorne, M. D. Welch, G. Della Ventura, S. Liu, J.-L. Robert, and D. M. Jenkins, “Short-range order in synthetic aluminous tremolites: An infrared and triple-quantum MAS NMR study,” American Mineralogist, vol. 85, no. 11-12, pp. 1716–1724, 2000.
View at: Google Scholar
R. W. T. Wilkins, “Iron-magnesium distribution in the tremoliteactinolite series,” American Mineralogist, vol. 55, pp. 1993–1998, 1970.
View at: Google Scholar
K. Ishida, F. C. Hawthorne, and Y. Ando, “Fine structure on infrared OH-stretching bands in natural and heat-treated amphiboles of the tremolite-ferro-actinolite series,” American Mineralogist, vol. 87, no. 7, pp. 891–898, 2002.
View at: Google Scholar
A. I. Apopei, N. Buzgar, and A. Buzatu, “Raman and infrared spectroscopy of kaersutite and certain common amphiboles,” AUI-GEOLOGIE, vol. 57, no. 2, pp. 35–58, 2011.
View at: Google Scholar
R. G. Burns and R. G. J. Strens, “Infrared study of the hydroxyl bands in clinoamphiboles,” Science, vol. 153, no. 3738, pp. 890–892, 1966.
View at: Publisher Site | Google Scholar
E. Libowitzky and A. Beran, “The structure of hydrous species in nominally anhydrous minerals: information form polarized IR spectroscopy,” Reviews in Mineralogy and Geochemistry, vol. 62, pp. 29–52, 2006.
View at: Publisher Site | Google Scholar
F. A. Kasir, M. Z. Al-Tai, and Y. A. Al-Jawady, “Infra-red absorption spectra study of some amphibole minerals,” Rafidain Journal of Science, vol. 17, no. 2, pp. 70–77, 2006.
View at: Google Scholar
H. Skogby and G. R. Rossman, “The intensity of amphibole OH bands in the infrared absorption spectrum,” Physics and Chemistry of Minerals, vol. 18, no. 1, pp. 64–68, 1991.
View at: Publisher Site | Google Scholar
M. Andrut, M. Gottschalk, S. Melzer, and J. Najorka, “Lattice vibrational modes in synthetic tremolite-Sr-tremolite and tremolite-richterite solid solutions,” Physics and Chemistry of Minerals, vol. 27, no. 5, pp. 301–309, 2000.
View at: Publisher Site | Google Scholar
H. F. Shurvell, L. Rintoul, and P. M. Fredericks, “Infrared and Raman spectra of jade and jade minerals,” Internet Journal of Vibrational Spectroscopy, vol. 5, no. 4, 2001.
View at: Google Scholar
J. T. Kloprogge, D. Visser, H. Ruan, and R. L. Frost, “Infrared and Raman spectroscopy of holmquistite, Li₂(Mg,Fe²⁺)₃(Al,Fe³⁺)₂(Si,Al)8O₂₂(OH)₂,” Journal of Materials Science Letters, vol. 20, no. 16, pp. 1497–1499, 2001.
View at: Publisher Site | Google Scholar
J. T. Kloprogge, M. H. Case, and R. L. Frost, “Raman microscopic study of the Li-amphibole holmquistite, from the Martin Marietta Quarry, Bessemer City, NC, USA,” Mineralogical Magazine, vol. 65, no. 8, pp. 775–785, 2001.
View at: Publisher Site | Google Scholar
K. Ishida, D. M. Jenkins, and F. C. Hawthorne, “Mid-IR bands of synthetic calcic amphiboles of tremolite-pargasite series and of natural calcic amphiboles,” American Mineralogist, vol. 93, no. 7, pp. 1112–1118, 2008.
View at: Publisher Site | Google Scholar
G. Jovanovski, P. Makreski, B. Kaitner, and B. Boev, “Silicate minerals from macedonia. Complementary use of vibrational spectroscopy and X-ray powder diffraction for identification and detection purposes,” Croatica Chemica Acta, vol. 82, no. 2, pp. 363–386, 2009.
View at: Google Scholar
R. G. J. Strens, “The layer silicates,” in The Infrared Spectra of Minerals, V. C. Farmer, Ed., pp. 305–330, Mineralogical Society, London, UK, 1974.
View at: Google Scholar
F. C. Hawthorne, G. D. Ventura, and J. L. Robert, “Short-range order of (Na, K) and Al in tremolite: an infrared study,” American Mineralogist, vol. 81, no. 5, pp. 782–784, 1996.
View at: Google Scholar
F. C. Hawthorne, G. D. Ventura, J.-L. Robert, M. D. Welch, M. Raudsepp, and D. M. Jenkins, “A Rietveld and infrared study of synthetic amphiboles along the potassium-richterite-tremolite join,” American Mineralogist, vol. 82, no. 7-8, pp. 708–716, 1997.
View at: Google Scholar
G. Della Ventura, J. L. Robert, J. M. Beny, F. C. Hawthorne, G. Della Ventura, and M. D. Welch, “Site occupancies in synthetic monoclinic amphiboles: rietveld structure refinement and infrared spectroscopy of (nichel, magnesium, cobalt-richterite),” American Mineralogist, vol. 82, pp. 291–301, 1997.
View at: Google Scholar
J.-L. Robert, G. Della Ventura, and J.-L. Thauvin, “The infrared OH-stretching region of synthetic richterites in the system Na₂O-K₂O-CaO-MgO-SiO₂-H₂O-HF,” European Journal of Mineralogy, vol. 1, no. 2, pp. 203–211, 1989.
View at: Publisher Site | Google Scholar
M. Gottschalk, M. Andrut, and S. Melzer, “The determination of the cummingtonite content of synthetic tremolite,” European Journal of Mineralogy, vol. 11, no. 6, pp. 967–982, 1999.
View at: Publisher Site | Google Scholar
F. C. Hawthorne and G. Della Ventura, “Short-range order in amphiboles,” Reviews in Mineralogy and Geochemistry, vol. 67, pp. 173–222, 2007.
View at: Publisher Site | Google Scholar
M. Raudsepp, A. C. Turnock, F. C. Hawthorne, B. K. Sheriff, and J. S. Hartman, “Characterization of synthetic pargasitic amphiboles (NaCa₂Mg₄M3Si₆Al₂O₂₂(OH,F); M₃=Al,Cr,Ga,Sc,In) by infrared spectroscopy, rietveld structure refinement and 27Al, 29Si and 19F MAS NMR spectroscopy,” American Mineralogist, vol. 72, pp. 580–593, 1987.
View at: Google Scholar
J. P. Coates, “Infrared analysis of toxic dusts: part 1, analysis of collected samples of quartz and asbestos,” American Laboratory, vol. 9, no. 11, pp. 105–111, 1977.
View at: Google Scholar
J. H. Patterson and D. J. O'Connor, “Chemical studies of amphibole asbestos. I. Structural changes of heat-treated crocidolite, amosite, and tremolite from infrared absorption studies,” Australian Journal of Chemistry, vol. 19, no. 7, pp. 1155–1164, 1966.
View at: Publisher Site | Google Scholar
A. Marconi, “Application of infrared spectroscopy in asbestos mineral analysis,” Annali dell'Istituto Superiore di Sanità, vol. 19, no. 4, pp. 629–637, 1983.
View at: Google Scholar
J. Addison and L. S. T. Davies, “Analysis of amphibole asbestos in chrysotile and other minerals,” Annals of Occupational Hygiene, vol. 34, no. 2, pp. 159–175, 1990.
View at: Publisher Site | Google Scholar
T. Huang, Y. Sun, and T. Wu, “36° Colloquium Spectroscopicum Internationale-Budapest (Hungary),” p. 273, 2009.
View at: Google Scholar
H. W. Van der Marel and H. Beutelspacher, Atlas of Infrared Spectroscopy of Clay Minerals and their Admixtures, Elsevier, Amsterdam, The Netherlands, 1976.
R. Prost, “The influence of the christiansen effect on I.R. spectra of powders,” Clays and Clay Minerals, vol. 21, no. 5, pp. 363–368, 1973.
View at: Publisher Site | Google Scholar
G. Duyckaerts, “The infra-red analysis of solid substances. A review,” Analyst, vol. 84, no. 997, pp. 201–214, 1959.
View at: Publisher Site | Google Scholar
R. Chester and H. Elderfield, “The application of infra-red absorption spectroscopy to carbonate mineralogy,” Sedimentology, vol. 9, no. 1, pp. 5–21, 1967.
View at: Publisher Site | Google Scholar
C. Pichard and F. Frohlich, “Quantitative IR analysis of sediments. Example of quartz and calcite determination,” Revue de I Institut Francais du Petrole, vol. 41, no. 6, pp. 809–819, 1986.
View at: Publisher Site | Google Scholar
F. Frohlich, “Deep-sea biogenic silica: new structural and analytical data from infrared analysis—geological implications,” Terra Nova, vol. 1, no. 3, pp. 267–273, 1989.
View at: Publisher Site | Google Scholar
L. Heller-Kallai, S. Yariv, and S. Gross, “Hydroxyl-stretching frequencies of serpentine minerals,” Mineralogical Magazine, vol. 40, no. 310, pp. 197–200, 1975.
View at: Publisher Site | Google Scholar
S. Uehara and H. Shirozu, “Variations in chemical composition and structural properties of antigorites,” Mineralogical Journal, vol. 12, no. 7, pp. 299–318, 1985.
View at: Publisher Site | Google Scholar
M. Mellini, Y. Fuchs, C. Viti, C. Lemaire, and J. Linarés, “Insights into the antigorite structures from Mössbauer and FTIR spectroscopies,” European Journal of Mineralogy, vol. 14, no. 1, pp. 97–104, 2002.
View at: Publisher Site | Google Scholar
C. Groppo and R. Compagnoni, “Ubiquitous fibrous antigorite veins from the Lanzo Ultramafic Massif, Internal Western Alps (Italy): characterisation and genetic conditions,” Periodico di Mineralogia, vol. 76, no. 2, pp. 169–181, 2007.
View at: Publisher Site | Google Scholar
Occupational Safety and Health Administration (OSHA), “Occupational exposure to asbestos, tremolite, anthopyllite and actinolite,” Federal Register 57:110, 29 CFR Parts 1910 and 1926, Docket NO H-033-d.24310, OSHA, 1992.
View at: Google Scholar

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Copyright © 2015 Antonella Campopiano et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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