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Journal of Spectroscopy
Volume 2018, Article ID 3254375, 13 pages
https://doi.org/10.1155/2018/3254375
Research Article

Use of Electrochemical Impedance Spectroscopy for the Evaluation of Performance of PEM Fuel Cells Based on Carbon Cloth Gas Diffusion Electrodes

Department of Chemistry, Materials and Chemical Engineering “Giulio Natta”, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, Italy

Correspondence should be addressed to Saverio Latorrata; ti.imilop@atarrotal.oirevas

Received 15 November 2017; Accepted 13 February 2018; Published 28 March 2018

Academic Editor: Jau-Wern Chiou

Copyright © 2018 Saverio Latorrata et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. O. Erdinc and M. Uzunoglu, “Recent trends in PEM fuel cell-powered hybrid systems: investigation of application areas, design architectures and energy management approaches,” Renewable and Sustainable Energy Reviews, vol. 14, no. 9, pp. 2874–2884, 2010. View at Publisher · View at Google Scholar · View at Scopus
  2. Y. Wang, K. S. Chen, J. Mishler, S. C. Cho, and X. C. Adroher, “A review of polymer electrolyte membrane fuel cells: technology, applications, and needs on fundamental research,” Applied Energy, vol. 88, no. 4, pp. 981–1007, 2011. View at Publisher · View at Google Scholar · View at Scopus
  3. O. Groger, H. A. Gasteiger, and J. P. Suchsland, “Review–electromobility: batteries or fuel cells?” Journal of the Electrochemical Society, vol. 162, no. 14, pp. A2605–A2622, 2015. View at Publisher · View at Google Scholar · View at Scopus
  4. M. Zhou, H. L. Wang, and S. J. Guo, “Towards high-efficiency nanoelectrocatalysts for oxygen reduction through engineering advanced carbon nanomaterials,” Chemical Society Reviews, vol. 45, no. 5, pp. 1273–1307, 2016. View at Publisher · View at Google Scholar · View at Scopus
  5. Y. M. Volfkovich, V. E. Sosenkin, and V. S. Bagotsky, “Structural and wetting properties of fuel cell components,” Journal of Power Sources, vol. 195, no. 17, pp. 5429–5441, 2010. View at Publisher · View at Google Scholar · View at Scopus
  6. R. Othman, A. L. Dicks, and Z. Zhu, “Non precious metal catalysts for the PEM fuel cell cathode,” International Journal of Hydrogen Energy, vol. 37, no. 1, pp. 357–372, 2012. View at Publisher · View at Google Scholar · View at Scopus
  7. Z. W. Chen, D. Higgins, A. P. Yu, L. Zhang, and J. J. Zhang, “A review on non-precious metal electrocatalysts for PEM fuel cells,” Energy & Environmental Science, vol. 4, no. 9, pp. 3167–3192, 2011. View at Publisher · View at Google Scholar · View at Scopus
  8. G. F. Alvarez, M. Mamlouk, S. M. Senthil Kumar, and K. Scott, “Preparation and characterisation of carbon-supported palladium nanoparticles for oxygen reduction in low temperature PEM fuel cells,” Journal of Applied Electrochemistry, vol. 41, no. 8, pp. 925–937, 2011. View at Publisher · View at Google Scholar · View at Scopus
  9. S. Sui, X. Y. Wang, X. T. Zhou, Y. H. Su, S. Riffatc, and C. J. Liu, “A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells,” Journal of Materials Chemistry A, vol. 5, no. 5, pp. 1808–1825, 2017. View at Publisher · View at Google Scholar · View at Scopus
  10. G. Diloyan, M. Sobel, K. Das, and P. Hutapea, “Effect of mechanical vibration on platinum particle agglomeration and growth in polymer electrolyte membrane fuel cell catalyst layers,” Journal of Power Sources, vol. 214, pp. 59–67, 2012. View at Publisher · View at Google Scholar · View at Scopus
  11. L. Cindrella, A. M. Kannan, J. F. Lin et al., “Gas diffusion layer for proton exchange membrane fuel cells—a review,” Journal of Power Sources, vol. 194, no. 1, pp. 146–160, 2009. View at Publisher · View at Google Scholar · View at Scopus
  12. S. Park, J.-W. Lee, and B. N. Popov, “A review of gas diffusion layer in PEM fuel cells: materials and designs,” International Journal of Hydrogen Energy, vol. 37, no. 7, pp. 5850–5865, 2012. View at Publisher · View at Google Scholar · View at Scopus
  13. B. Millington, V. Whipple, and B. G. Pollet, “A novel method for preparing proton exchange membrane fuel cell electrodes by the ultrasonic-spray technique,” Journal of Power Sources, vol. 196, no. 20, pp. 8500–8508, 2011. View at Publisher · View at Google Scholar · View at Scopus
  14. C. Bois, A. Blayo, D. Chaussy, R. Vincent, A. G. Mercier, and C. Nayoze, “Catalyst layers for PEMFC manufactured by flexography printing process: performances and structure,” Fuel Cells, vol. 12, no. 2, pp. 199–211, 2012. View at Publisher · View at Google Scholar · View at Scopus
  15. C. Ruengkit and N. Tantavichet, “Influence of gas diffusion layer on Pt catalyst prepared by electrodeposition for proton exchange membrane fuel cells,” Thin Solid Films, vol. 636, pp. 116–126, 2017. View at Publisher · View at Google Scholar · View at Scopus
  16. H. B. Li, P. P. Yang, Z. Y. Xie, M. Sun, and Q. Z. Huang, “Self-supported N-doped carbon nanonet integrated on carbon paper for gas diffusion electrode,” International Journal of Hydrogen Energy, vol. 42, no. 12, pp. 8216–8223, 2017. View at Publisher · View at Google Scholar · View at Scopus
  17. I. Gatto, A. Stassi, V. Baglio et al., “Optimization of perfluorosulphonic ionomer amount in gas diffusion electrodes for PEMFC operation under automotive conditions,” Electrochimica Acta, vol. 165, pp. 450–455, 2015. View at Publisher · View at Google Scholar · View at Scopus
  18. H. Su, T. C. Jao, S. Pasupathi, B. J. Bladergroen, V. Linkov, and B. G. Pollet, “A novel dual catalyst layer structured gas diffusion electrode for enhanced performance of high temperature proton exchange membrane fuel cell,” Journal of Power Sources, vol. 246, pp. 63–67, 2014. View at Publisher · View at Google Scholar · View at Scopus
  19. İ. Fırtına, S. Güner, and A. Albostan, “Preparation and characterization of membrane electrode assembly (MEA) for PEMFC,” International Journal of Energy Research, vol. 35, no. 2, pp. 146–152, 2011. View at Publisher · View at Google Scholar · View at Scopus
  20. S. Latorrata, P. G. Stampino, E. Amici, R. Pelosato, C. Cristiani, and G. Dotelli, “Effect of rheology controller agent addition to micro-porous layers on PEMFC performances,” Solid State Ionics, vol. 216, pp. 73–77, 2012. View at Publisher · View at Google Scholar · View at Scopus
  21. E. F. Diaz, C. Cuevas-Arteaga, N. Flores-Garcia, S. M. Sintillo, and O. Sotelo-Mazon, “Corrosion performance of AISI-309 exposed to molten salts V2O5-Na2SO4 at 700°C applying EIS and Rp electrochemical techniques,” Journal of Spectroscopy, vol. 2015, Article ID 826759, 12 pages, 2015. View at Publisher · View at Google Scholar · View at Scopus
  22. G. Bolat, D. Mareci, S. Iacoban, N. Cimpoesu, and C. Munteanu, “The estimation of corrosion behavior of NiTi and NiTiNb alloys using dynamic electrochemical impedance spectroscopy,” Journal of Spectroscopy, vol. 2013, Article ID 714920, 7 pages, 2013. View at Publisher · View at Google Scholar · View at Scopus
  23. S. Godavarthi, J. Porcayo-Calderon, E. Vazquez-Velez, M. Casales-Diaz, D. M. Ortega-Toledo, and L. Martinez-Gomez, “Influence of the chemical composition in the electrochemical response of permanent magnets,” Journal of Spectroscopy, vol. 2015, Article ID 356027, 16 pages, 2015. View at Publisher · View at Google Scholar · View at Scopus
  24. S. Sbrignadello, A. Tura, and P. Ravazzani, “Electroimpedance spectroscopy for the measurement of the dielectric properties of sodium chloride solutions at different glucose concentrations,” Journal of Spectroscopy, vol. 2013, Article ID 571372, 6 pages, 2013. View at Publisher · View at Google Scholar · View at Scopus
  25. M. Ciureanu and R. Roberge, “Electrochemical impedance study of PEM fuel cells. Experimental diagnostics and modeling of air cathodes,” Journal of Physical Chemistry B, vol. 105, no. 17, pp. 3531–3539, 2001. View at Publisher · View at Google Scholar · View at Scopus
  26. S. Latorrata, P. G. Stampino, C. Cristiani, and G. Dotelli, “Development of an optimal gas diffusion medium for polymer electrolyte membrane fuel cells and assessment of its degradation mechanisms,” International Journal of Hydrogen Energy, vol. 40, no. 42, pp. 14596–14608, 2015. View at Publisher · View at Google Scholar · View at Scopus
  27. S. Latorrata, R. Balzarotti, P. G. Stampino, C. Cristiani, G. Dotelli, and M. Guilizzoni, “Design of properties and performances of innovative gas diffusion media for polymer electrolyte membrane fuel cells,” Progress in Organic Coatings, vol. 78, pp. 517–525, 2015. View at Publisher · View at Google Scholar · View at Scopus
  28. S. Litster and G. McLean, “PEM fuel cell electrodes,” Journal of Power Sources, vol. 130, no. 1-2, pp. 61–76, 2004. View at Publisher · View at Google Scholar · View at Scopus
  29. L. Omati, P. Gallo Stampino, G. Dotelli, D. Brivio, and P. Grassini, “Operative conditions effect on PEM-FC performance by in-situ and ex-situ analysis of gas diffusion media with different bulk textile structure,” International Journal of Hydrogen Energy, vol. 36, no. 13, pp. 8053–8062, 2011. View at Publisher · View at Google Scholar · View at Scopus
  30. X.-Z. R. Yuan, C. Song, H. Wang, and J. Zhang, Electrochemical Impedance Spectroscopy in PEM Fuel Cells: Fundamentals and Applications, Springer, London, UK, 2010.
  31. N. Wagner and E. Gülzow, “Change of electrochemical impedance spectra (EIS) with time during CO-poisoning of the Pt-anode in a membrane fuel cell,” Journal of Power Sources, vol. 127, no. 1-2, pp. 341–347, 2004. View at Publisher · View at Google Scholar · View at Scopus
  32. R. Ferrero, G. Dotelli, P. Gallo Stampino, and S. Latorrata, “Discussion of critical measurement issues of impedance spectroscopy on PEM fuel cells,” in IEEE International Workshop on Applied Measurements for Power Systems, AMPS, pp. 97–102, Aachen, Germany, 2012. View at Publisher · View at Google Scholar · View at Scopus
  33. S. Asghari, A. Mokmeli, and M. Samavati, “Study of PEM fuel cell performance by electrochemical impedance spectroscopy,” International Journal of Hydrogen Energy, vol. 35, no. 17, pp. 9283–9290, 2010. View at Publisher · View at Google Scholar · View at Scopus
  34. P. G. Stampino, S. Latorrata, D. Molina, S. Turri, M. Levi, and G. Dotelli, “Investigation of hydrophobic treatments with perfluoropolyether derivatives of gas diffusion layers by electrochemical impedance spectroscopy in PEM-FC,” Solid State Ionics, vol. 216, pp. 100–104, 2012. View at Publisher · View at Google Scholar · View at Scopus
  35. R. Ramasamy, E. Kumbur, M. Mench, W. Liu, D. Moore, and M. Murthy, “Investigation of macro- and micro-porous layer interaction in polymer electrolyte fuel cells,” International Journal of Hydrogen Energy, vol. 33, no. 13, pp. 3351–3367, 2008. View at Publisher · View at Google Scholar · View at Scopus
  36. H. Kim and B. N. Popov, “Development of novel method for preparation of PEMFC electrodes,” Electrochemical and Solid-State Letters, vol. 7, no. 4, pp. A71–A74, 2004. View at Publisher · View at Google Scholar · View at Scopus
  37. N. Wagner, “Characterization of membrane electrode assemblies in polymer electrolyte fuel cells using a.c. impedance spectroscopy,” Journal of Applied Electrochemistry, vol. 32, no. 8, pp. 859–863, 2002. View at Publisher · View at Google Scholar · View at Scopus
  38. P. Gallo Stampino, L. Omati, C. Cristiani, and G. Dotelli, “Characterisation of nanocarbon-based gas diffusion media by electrochemical impedance spectroscopy,” Fuel Cells, vol. 10, no. 2, pp. 270–277, 2010. View at Publisher · View at Google Scholar · View at Scopus
  39. J. Wu, X. Yuan, H. Wang, M. Blanco, J. Martin, and J. Zhang, “Diagnostic tools in PEM fuel cell research: part I electrochemical techniques,” International Journal of Hydrogen Energy, vol. 33, no. 6, pp. 1735–1746, 2008. View at Publisher · View at Google Scholar · View at Scopus
  40. F. Alcaide, E. Brillas, and P.-L. Cabot, “EIS analysis of hydroperoxide ion generation in an uncatalyzed oxygen-diffusion cathode,” Journal of Electroanalytical Chemistry, vol. 547, no. 1, pp. 61–73, 2003. View at Publisher · View at Google Scholar · View at Scopus