Effect of Size and Shape on the Vibrational and Thermodynamic Properties of Nanomaterials

<table>Size and shape dependence of melting enthalpy of Ag using (<a href="https://static.hindawi.com/articles/jther/volume-2013/328051/figures/#EEq18">18</a>)–(<a href="https://static.hindawi.com/articles/jther/volume-2013/328051/figures/#EEq20">20</a>). The experimental data [<a href="/journals/jther/2013/328051/#B11">11</a>] are shown by <svg height="9.0625" id="M75" style="vertical-align:-0.1092pt" version="1.1" viewbox="0 0 10.1 9.0625" width="10.1" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,8.863)"><path d="M561 255q0 -109 -78.5 -186t-188.5 -77t-188.5 77t-78.5 186t78.5 186t188.5 77t188.5 -77t78.5 -186z" id="x26AB"></path></g>
</svg> for spherical.</table>

Journal of Thermodynamics

fig7

Figure 7

Figure 7: Effect of Size and Shape on the Vibrational and Thermodynamic Properties of Nanomaterials 