Research Article

Excess Molar Volumes and Viscosities for the Binary Mixtures of n-Octane, n-Decane, n-Dodecane, and n-Tetradecane with Octan-2-ol at 298.15K

Table 2

Densities ( ), viscosities ( ), excess molar volumes , viscosities deviations Δ , and excess Gibbs free energy of binary mixtures at T = 298.15 K.

ηΔη
kg·m−3m3·mol−1mPa·smPa·sKJmol−1

n-Octane(1) + octan-2-ol(2)
00.8170506.42900
0.04870.8114−0.0515.956−0.185115
0.10020.8054−0.0975.301−0.535149
0.14980.79959−0.1334.654−0.888137
0.20060.79361−0.163.998−1.24478
0.25160.78756−0.1773.364−1.576−30
0.30030.78176−0.1832.796−1.856−183
0.35380.77534−0.182.228−2.108−410
0.40030.76975−0.1691.79−2.27−661
0.44660.76415−0.1511.411−2.375−960
0.50010.75767−0.1231.049−2.421−1359
0.55170.75142−0.0910.778−2.387−1776
0.60020.74554−0.0570.59−2.287−2157
0.65390.73905−0.0180.454−2.106−2469
0.69940.733570.0130.39−1.901−2560
0.74490.728110.0420.366−1.656−2431
0.80.721570.0680.376−1.32−2019
0.84650.71610.0810.402−1.018−1571
0.90030.709850.0810.434−0.668−1034
0.95210.703940.0610.441−0.355−670
10.6986700.51200

n-Decane(1) + octan-2-ol(2)
00.8170506.42900
0.05540.810770.0365.222−0.898−233
0.09980.805830.0714.638−1.234−301
0.15540.799740.1193.972−1.589−403
0.19990.794990.1583.491−1.822−497
0.25540.78920.2052.951−2.052−632
0.29990.784670.2392.564−2.19−755
0.35550.779160.2752.136−2.308−927
0.39980.77490.2981.836−2.361−1078
0.45540.769690.3181.509−2.377−1285
0.49990.765640.3261.284−2.354−1461
0.55550.760740.3261.046−2.281−1690
0.59980.756940.3180.889−2.191−1871
0.65550.75230.2980.73−2.039−2080
0.70.74870.2740.63−1.89−2223
0.75540.744320.2360.538−1.673−2337
0.79980.740910.20.487−1.476−2362
0.85540.736740.1490.45−1.203−2281
0.89990.733470.1060.438−0.966−2126
0.95540.729480.0520.445−0.649−1811
10.7263500.84500

n-Dodecane(1) + octan-2-ol(2)
00.8170506.42900
0.05540.810980.1015.513−0.634−159
0.09990.806370.1674.916−1.004−296
0.15540.800910.244.254−1.383−404
0.19980.796760.2913.786−1.625−517
0.25550.79180.3453.272−1.856−659
0.29980.788050.382.916−1.986−770
0.35540.783550.4152.532−2.087−902
0.39980.780120.4352.27−2.123−999
0.45540.776030.4511.995−2.115−1102
0.49990.77290.4561.813−2.071−1167
0.55550.769160.4531.627−1.973−1219
0.59980.766310.4441.508−1.866−1236
0.65550.762880.4221.391−1.699−1221
0.69980.760270.3981.32−1.545−1180
0.75540.757130.3591.253−1.328−1095
0.79980.754730.321.213−1.142−1005
0.85550.751850.2631.176−0.896−869
0.89990.749650.211.152−0.694−750
0.95550.7470.1341.124−0.439−599
0.99970.7451901.33700

n-Tetradecane(1) + octan-2-ol(2)
00.8170506.42900
0.05550.811340.1265.619−0.568−144
0.09990.807210.1935.163−0.831−230
0.15550.802390.2684.632−1.121−330
0.19980.79880.3214.238−1.321−417
0.25540.794590.3763.786−1.533−531
0.29980.791440.4133.455−1.67−628
0.35550.787740.4493.081−1.802−751
0.39990.784960.472.813−1.876−850
0.45540.781710.4872.519−1.93−968
0.49990.779250.4922.314−1.941−1054
0.55550.776370.492.098−1.915−1144
0.59980.77420.481.957−1.863−1196
0.65540.771630.4571.82−1.759−1226
0.70.769690.4321.741−1.644−1217
0.75550.767410.391.683−1.46−1154
0.80.765690.3481.668−1.282−1060
0.85550.763650.2871.688−1.02−887
0.90.762110.231.736−0.779−703
0.95530.760290.151.835−0.439−424
0.99970.7591402.08100