Table of Contents
Journal of Thermodynamics
Volume 2014, Article ID 387698, 9 pages
http://dx.doi.org/10.1155/2014/387698
Review Article

Entropy Growth Is the Manifestation of Spontaneity

Department of Mechanical Engineering, Stony Brook University, Stony Brook, NY 11794, USA

Received 4 August 2014; Revised 28 October 2014; Accepted 28 October 2014; Published 7 December 2014

Academic Editor: M. A. Rosen

Copyright © 2014 Lin-Shu Wang. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Every student of thermodynamics grasps entropy growth in terms of dissipation of energy. The real nature of energy and entropy is subtle. This critical review of the evolution of thermodynamic thought uncovers the remarkable advance on our understanding of energy made by Kelvin with his dissipation of energy proposition. Maxwell and Planck, however, pointed out that dissipation of energy does not exhaust growth of entropy (i.e., the idea of spontaneity), and in fact, as it is shown here, Kelvin’s proposition of dissipation of energy (1852) is subsumed under the principle of the increase of entropy (Clausius, 1865). It is necessary, therefore, for thermodynamics to become a coherent conceptual system, to introduce spontaneity as an independent concept. Instead of the heat-work dyad framework, the introduction of spontaneity entails energy transformation to be viewed in terms of a triad framework of heat (from the reservoir)-work-spontaneity. Spontaneity is the new energy in the triad framework, and it is also clear that energy commodity (fungible energy or energy carriers) is only one kind of spontaneity, stock spontaneity; the other kind is ongoing spontaneity, the consideration of which is necessary for comprehending problems of homeostasis in both the organic and inorganic worlds.