Table of Contents
Journal of Thermodynamics
Volume 2015, Article ID 782138, 7 pages
http://dx.doi.org/10.1155/2015/782138
Research Article

Volumetric Behavior of Binary Mixtures of Alkoxyethanols and Some Selected Amines at 298.15 K

1Department of Chemical Sciences, Niger Delta University, Wilberforce Island, PMB 71, Yenagoa, Bayelsa State, Nigeria
2Department of Chemistry, Rivers State University of Science & Technology, PMB 5080, Port Harcourt, Rivers State, Nigeria

Received 23 September 2014; Revised 9 January 2015; Accepted 9 January 2015

Academic Editor: Felix Sharipov

Copyright © 2015 Ayasen Jermaine Kemeakegha et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. A. K. Nain, “Densities and volumetric properties of binary mixtures of formamide with 1-butanol, 2-butanol, 1,3-butanediol and 1,4-butanediol at temperatures between 293.15 and 318.15 K,” Journal of Solution Chemistry, vol. 36, no. 4, pp. 497–516, 2007. View at Publisher · View at Google Scholar
  2. A. Pal and A. Kumar, “Excess molar volumes and viscosities for binary mixtures of alkoxypropanols with 1-alkanols at 298.15 K,” Journal of Molecular Liquids, vol. 123, no. 2-3, pp. 146–151, 2006. View at Publisher · View at Google Scholar
  3. M. V. Rathnam, S. Mohite, and M. S. S. Kumar, “Density, excess volume, and viscosity of vinyl acetate or benzyl acetate with (o-, m-, p-)xylenes and ethylbenzene at T = (303.15 and 313.15) K,” Journal of Solution Chemistry, vol. 39, no. 11, pp. 1735–1748, 2010. View at Publisher · View at Google Scholar
  4. V. A. Rana, H. Chaube, and D. H. Gadani, “Dielectric permittivity, density, viscosity and refractive index of binary mixtures of anisole with methanol and 1-propanol at different temperatures,” Journal of Molecular Liquids, vol. 164, no. 3, pp. 191–196, 2011. View at Publisher · View at Google Scholar · View at Scopus
  5. S. Nallani and V. Jaana, “Thermodynamic and transport properties of binary liquid mixtures of n-methylacetamide with alkyl (methyl, ethyl, n-propyl and n-butyl) acetates at 308.15 K,” Rasayan Journal of Chemistry, vol. 1, no. 3, pp. 602–608, 2008. View at Google Scholar
  6. A. Pal, H. Kumar, R. Maan, and H. K. Sharma, “Volumetric and acoustic studies of binary liquid mixtures of dipropylene glycol dimethyl ether with methyl acetate, ethyl acetate and n-butyl acetate in the temperature range T = (288.15, 293.15, 298.15, 303.15, and 308.15) K,” Journal of Solution Chemistry, vol. 42, no. 10, pp. 1988–2011, 2013. View at Publisher · View at Google Scholar · View at Scopus
  7. L. C. Ribeiro, M. D. S. Santos, and A. P. Paiva, “Apparent molar volumes of N,N-disubstituted monoamides: a convenient tool to interpret iron(Iii) extraction profiles from hydrochloric acid solutions,” Solvent Extraction and Ion Exchange, vol. 31, pp. 281–296, 2013. View at Publisher · View at Google Scholar
  8. M. S. AlTuwaim, K. H. A. E. Alkhaldi, A. S. Al-Jimaz, and A. A. Mohammad, “Comparative study of physico-chemical properties of binary mixtures of N,N-dimethylformamide with 1-alkanols at different temperatures,” The Journal of Chemical Thermodynamics, vol. 48, pp. 39–47, 2012. View at Publisher · View at Google Scholar
  9. A. A. Mohammad, M. S. AlTuwaim, K. H. A. E. Alkhaldi, and A. S. Al-Jimaz, “Viscosity and surface tension of binary systems of N,N-dimethylformamide with alkan-1-ols at different temperatures,” The Journal of Chemical Thermodynamics, vol. 56, pp. 106–113, 2013. View at Publisher · View at Google Scholar · View at Scopus
  10. M. S. AlTuwaim, K. H. A. E. Alkhaldi, A. S. Al-Jimaz, and A. A. Mohammad, “Physico-chemical properties of binary mixtures of N,N-dimethylformamide with 1-octanol, 1-nonanol and 1-decanol at different temperatures,” The Journal of Chemical Thermodynamics, vol. 58, pp. 367–376, 2013. View at Publisher · View at Google Scholar
  11. L. Venkatramana, K. Sreenivasulu, K. Sivakumar, and K. Dayananda Reddy, “Thermodynamic properties of binary mixtures containing 1-alkanols,” Journal of Thermal Analysis and Calorimetry, vol. 115, no. 2, pp. 1829–1834, 2014. View at Publisher · View at Google Scholar · View at Scopus
  12. M. Habibullah, I. M. M. Rahman, M. A. Uddin et al., “Densities, viscosities, and speeds of sound of binary mixtures of heptan-1-ol with 1,4-dioxane at temperatures from (298.15 to 323.15) K and atmospheric pressure,” Journal of Chemical and Engineering Data, vol. 58, no. 11, pp. 2887–2897, 2013. View at Publisher · View at Google Scholar · View at Scopus
  13. F. E. M. Alaoui, E. A. Montero, G. Qiu, F. Aguilar, and J. Wu, “Liquid density of biofuel mixtures: 1-heptanol + heptane system at pressures up to 140 MPa and temperatures from 298.15 K to 393.15 K,” The Journal of Chemical Thermodynamics, vol. 65, pp. 174–183, 2013. View at Publisher · View at Google Scholar
  14. A. Ali, A. K. Nain, B. Lal, and D. Chand, “Densities, viscosities, and refractive indices of binary mixtures of benzene with isomeric butanols at 30°C,” International Journal of Thermophysics, vol. 25, no. 6, pp. 1835–1847, 2004. View at Publisher · View at Google Scholar · View at Scopus
  15. A. Pal and A. Kumar, “Excess molar volumes and viscosities of binary liquid mixtures of n-alkoxyethano1 + 1-propanol systems at 298.15, 308.15 and 318.15 K,” Indian Journal of Chemistry A, vol. 43, pp. 722–729, 2004. View at Google Scholar
  16. A. Pal and A. Kumar, “Excess molar volumes and viscosities of binary mixtures of some polyethers with 1-propanol at 288·15, 298·15, and 308·15 K,” Journal of Chemical Sciences, vol. 116, no. 1, pp. 39–47, 2004. View at Publisher · View at Google Scholar
  17. B. Sinha, “Excess molar volumes, viscosity deviations and speeds of sound for some alkoxyethanols and amines in cyclohexanone at 298.15 K,” Physics and Chemistry of Liquids, vol. 48, no. 2, pp. 183–198, 2010. View at Publisher · View at Google Scholar
  18. L. Sarkar and M. N. Roy, “Investigation on viscous synergism and antagonism prevailing in binary mixtures of cyclohexylamine with isomeric butanols by volumetric, viscometric, refractive index and ultrasonic speed measurements,” Physics and Chemistry of Liquids, vol. 49, no. 2, pp. 219–236, 2011. View at Publisher · View at Google Scholar
  19. J. A. González, “Thermodynamics of mixtures containing amines. X. Systems with cyclic amines or morpholine,” Industrial & Engineering Chemistry Research, vol. 50, no. 16, pp. 9810–9820, 2011. View at Publisher · View at Google Scholar
  20. M. N. Roy, R. K. Das, and R. Chanda, “Study on solution properties of binary mixtures of some industrially important solvents with cyclohexylamine and cyclohexanone at 298.15 K,” International Journal of Thermophysics, vol. 31, no. 3, pp. 535–545, 2010. View at Publisher · View at Google Scholar
  21. A. Pal, R. Gaba, and S. Sharma, “Densities, excess molar volumes, speeds of sound, and isothermal compressibilities for 2-(2-hexyloxyethoxy)ethanol + n-alkylamine at temperatures between 288.15 K and 308.15 K,” Journal of Chemical & Engineering Data, vol. 53, no. 7, pp. 1643–1648, 2008. View at Publisher · View at Google Scholar
  22. S. R. Patil, U. G. Deshpande, and A. R. Hiray, “Molecular interaction studies of binary liquid mixtures of 1-hexanol and 1-heptanol with nitrobenzene as a common solvent,” Rasayan Journal of Chemistry, vol. 3, no. 1, pp. 66–73, 2010. View at Google Scholar · View at Scopus
  23. P. P. Patil, S. R. Patil, A. U. Borse, and D. G. Hundiwale, “Density, excess molar volume and apparent molar volume of binary liquid mixtures,” Rasayan Journal of Chemistry, vol. 4, no. 3, pp. 599–604, 2011. View at Google Scholar
  24. S. L. Oswal and H. S. Desai, “Studies of viscosity and excess molar volume of binary mixtures: 4. 1-Alkanol + tri-n-butylamine mixtures at 303.15 and 313.15 K,” Fluid Phase Equilibria, vol. 204, no. 2, pp. 281–294, 2003. View at Publisher · View at Google Scholar · View at Scopus
  25. S. L. Oswal, “Studies of viscosity and excess molar volume of binary mixtures: 5. Characterization of excess molar volume of 1-alkanol with alkylamines, dialkylamines and trialkylamines in terms of the ERAS model,” Thermochimica Acta, vol. 425, no. 1-2, pp. 59–68, 2005. View at Publisher · View at Google Scholar · View at Scopus
  26. S. L. Oswala and S. P. Ijardar, “Studies of partial molar volumes of alkylamine in non-electrolyte solvents III: alkyl amines in butanols at 303.15 K,” Journal of Molecular Liquids, vol. 144, no. 3, pp. 115–123, 2009. View at Publisher · View at Google Scholar
  27. G. P. Dubey and K. Kumar, “Studies of thermophysical properties of binary liquid mixtures of amine and alcohols at various temperatures,” The Journal of Chemical Thermodynamics, vol. 50, pp. 7–14, 2012. View at Publisher · View at Google Scholar
  28. G. P. Dubey and K. Kumar, “Studies of thermodynamic, thermophysical and partial molar properties of liquid mixtures of diethylenetriamine with alcohols at 293.15 to 313.15 K,” Journal of Molecular Liquids, vol. 180, pp. 164–171, 2013. View at Publisher · View at Google Scholar
  29. S. S. Ahmad, M. Yaqub, and A. Karim, “Studies on three excess properties of binary liquid mixtures of 1-butylamine with some alcohols at two different temperatures,” Journal of Natural Sciences and Mathematics, vol. 46, pp. 21–32, 2006. View at Google Scholar
  30. C. M. Saxena, A. Saxena, A. K. Srivastava, and N. K. Shukla, “Densities, viscosities and ultrasonic studies of binary liquid mixture of ethylamine and benzyl alcohol at different temperatures,” American Chemical Science Journal, vol. 3, no. 4, pp. 468–478, 2013. View at Publisher · View at Google Scholar
  31. M. Kwaterski, E. N. Rezanova, and R. N. Lichtenthaler, “Excess molar volumes and excess molar enthalpies of binary and ternary mixtures of 1-butanol, a tertiary amine (tri-n-butylamine or tri-n-octylamine) and n-hexane: experimental results and ERAS-model calculations,” The Journal of Chemical Thermodynamics, vol. 38, no. 10, pp. 1199–1213, 2006. View at Publisher · View at Google Scholar · View at Scopus
  32. A. Pal and H. Kumar, “Excess molar volumes and partial molar volumes of dipropylene glycol monomethyl ether + n-alkanol mixtures at 25°C,” Journal of Solution Chemistry, vol. 30, no. 5, pp. 411–423, 2001. View at Publisher · View at Google Scholar · View at Scopus
  33. A. Pal and A. Kumar, “Temperature dependence of the volumetric properties of some alkoxypropanols + n-alkanol mixtures,” The Journal of Chemical Thermodynamics, vol. 36, no. 3, pp. 173–182, 2004. View at Publisher · View at Google Scholar
  34. A. Pal and A. Kumar, “Excess molar volumes and viscosities for binary mixtures of dipropylene glycol monomethyl ether and of dipropylene glycol monobutyl ether with 1-propanol and 2-propanol at 298.15 K,” Journal of the Indian Chemical Society, vol. 80, pp. 824–831, 2003. View at Google Scholar
  35. M. D. Holgado, C. Deschaefer, and E. L. Arancibia, “Viscosities, densities, and excess volumes at various temperatures for 2-methoxyethanol (1) + 2-butanone (2),” Journal of Chemical and Engineering Data, vol. 41, no. 6, pp. 1429–1430, 1996. View at Publisher · View at Google Scholar
  36. J. Riddick and W. B. Bunger, Organic Solvents, Physical Properties and Methods of Purification, John Wiley & Sons, New York, NY, USA, 3rd edition, 1970.
  37. J. A. Bunger, W. B. Riddick, and T. K. Sakano, Techniques of Chemistry, Organic Solvents, Physical Properties and Methods of Purification, II, John Wiley & Sons, New York, NY, USA, 4th edition, 1986.
  38. R. D. Robert, Physical Properties of Chemical Compounds, American Chemical Society, 1981.
  39. C. M. Kinart, W. J. Kinart, D. Checinska-Majak, and A. Bald, “Densities and relative permittivities for mixtures of 2-methoxyethanol with DEA and TEA, at various temperatures,” Journal of Thermal Analysis and Calorimetry, vol. 75, no. 1, pp. 347–354, 2004. View at Publisher · View at Google Scholar · View at Scopus
  40. I. R. Radović, M. J. Kijevčaninand, and A. Ž. Tasić, “Densities and excess molar volumes of alcohol + cyclohexylamine mixtures,” The Journal of the Serbian Chemical Society, vol. 74, no. 11, pp. 1303–1318, 2009. View at Publisher · View at Google Scholar
  41. C. M. Kinart, W. J. Kinart, A. Ćwilińska, and M. Klimczak, “Excess molar volumes of the binary mixtures of polyethylene glycol 300 with ethoxyethanols at various temperatures,” The Journal of Chemical Thermodynamics, vol. 38, no. 8, pp. 1017–1024, 2006. View at Publisher · View at Google Scholar · View at Scopus
  42. W.-A. L. Izonfuo and J. A. Kemeakegha, “Intermolecular interaction studies of binary mixtures of a ketoester and carbonyl compounds. I: excess volumes of binary mixtures of ethyl acetoacetate with aliphatic ketones at 298.15K,” Indian Journal of Chemistry A, vol. 48, no. 9, pp. 1242–1246, 2009. View at Google Scholar
  43. B. García, R. Alcalde, S. Aparicio, J. M. Leal, and J. L. Trenzado, “Thermophysical behavior and temperature effect on the N-methylpyrrolidone + (C1−C10) alkan-1-ols mixed solvents,” Industrial & Engineering Chemistry Research, vol. 42, no. 4, pp. 920–928, 2003. View at Publisher · View at Google Scholar
  44. A. K. Nain, “Ultrasonic and viscometric studies of molecular interactions in binary mixtures of formamide with ethanol, 1-propanol, 1,2-ethanediol and 1,2-propanediol at different temperatures,” Journal of Molecular Liquids, vol. 140, no. 1–3, pp. 108–116, 2008. View at Publisher · View at Google Scholar
  45. A. Awasthi and A. Awasthi, “Intermolecular interactions in formamide + 2-alkoxyethanols: viscometric study,” Thermochimica Acta, vol. 537, pp. 57–64, 2012. View at Publisher · View at Google Scholar
  46. P. K. Pandey and A. Awasthi, “Acoustic, volumetric and spectroscopic investigations in binary mixtures of formamide/N-methylformamide + 2-chloroethanol at various temperatures,” Journal of Molecular Liquids, vol. 187, pp. 343–349, 2013. View at Publisher · View at Google Scholar · View at Scopus
  47. F. Comelli, R. Francesconi, A. Bigi, and K. Rubini, “Excess molar enthalpies, molar heat capacities, densities, viscosities, and refractive indices of dimethyl sulfoxide + 1-propanol at (288.15, 298.15, and 308.15) K and at normal pressure,” Journal of Chemical & Engineering Data, vol. 51, no. 5, pp. 1711–1716, 2006. View at Publisher · View at Google Scholar
  48. K. F. Loughlin, “Comments on ‘Excess molar enthalpies, molar heat capacities, densities, viscosities, and refractive indices of dimethyl sulfoxide + 1-propanol at (288.15, 298.15, and 308.15) K at normal pressures’,” Journal of Chemical & Engineering Data, vol. 52, no. 3, p. 1149, 2007. View at Publisher · View at Google Scholar