Table of Contents
Laser Chemistry
Volume 1, Issue 3, Pages 133-151

Multiple Photon IR Dissociation of (CF3)3CBr and Synthesis of (CF3)3CI in Laser-Radical Chemical Reactions

Center for Laser Technology, Academy of Sciences, Moscow region, Troitzk 142092, Russia

Received 15 December 1981

Copyright © 1983 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


CO2-laser induced multiple photon excitation and dissociation of the molecule (CF3)3CBr in the environment of I2 has been studied experimentally and theoretically. The synthesis of the (CF3)3CI molecule in laser-radical chemical reactions with high yield has been demonstrated.