Multiple Photon IR Dissociation of (CF3)3CBr and Synthesis of
(CF3)3CI in Laser-Radical Chemical Reactions
V. N. Bagratashvili,1V. N. Burimov,1M. V. Kuzmin,1V. S. Letokhov,1and A. P. Sviridov1
Received15 Dec 1981
Abstract
CO2-laser induced multiple photon excitation and dissociation of the molecule (CF3)3CBr in the environment of I2 has been studied experimentally and theoretically. The synthesis of the (CF3)3CI molecule in laser-radical chemical reactions with high yield has been demonstrated.