Table of Contents
Laser Chemistry
Volume 2, Issue 5-6, Pages 373-383
http://dx.doi.org/10.1155/LC.2.373

Determination of Vibrational Energy Distributions of CN(A2Πi) and (XΣ2+) from the C+N2O Reaction by Chemiluminescence and Laser Induced Fluorescence

1Laboratoire de Chimie Physique A, Hertzienne Université de Bordeaux I, Talence 33405, France
2Centre de Physique Moléculaire Optique, Hertzienne Université de Bordeaux I, Talence 33405, France

Copyright © 1983 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The CN(A2Πi) and (X Σ2+) vibrational distributions from the C+N2OCN+NO reaction at 300 K were determined in a low pressure flow reactor. From the chemiluminescence A2ΠiXΣ2+ the vibrational distribution of A2Πi was found to peak at υ′ = 1. From the laser induced fluorescence BΣ2+XΣ2+, the vibrational distribution of XΣ2+ was found to peak at υ″ = 4.

A C2H2—N2O combustion flame, stabilized at 2.8 torr with a temperature of 2500 K, gave a CN(A2Πi) vibrational distribution peaking at υ′ = 2 which can be attributed to the C+N2O reaction at 2500 K. However the CN ground state vibrational distribution was found to be relaxed.