Laser Chemistry

Laser Chemistry / 1985 / Article

Open Access

Volume 5 |Article ID 301425 | 8 pages | https://doi.org/10.1155/LC.5.223

1,4-Bis (β-Pyridyl-2-Vinyl) Benzene (P2VB) and 2,5-Distyryl-pyrazine (DSP) as Blue Laser Dyes

Received04 Jan 1985

Abstract

Solutions of P2VB and DSP in dimethyl-sulphoxide (DMSO) of concentration ca. 10–3 M/l act as laser dyes on pumping with nitrogen laser. P2VB and DSP are lasing in the ranges 390–440 nm (λmax = 416 nm) and 435–465 nm (λmax = 447 nm) respectively. An equimolar mixture of P2VB and DSP behaves as an energy transfer dye laser (ETDL) and is lasing in the range 429–455 nm (λmax = 438 nm). Such ETDL system obeys a long range coulombic energy transfer mechanism with a critical transfer distance R0 = 7.5 nm.The fluorescence quantum yields of both dyes have been measured, and in DMSO φf = 0.46 and 0.35 for P2VB and DSP respectively.Both dyes show a remarkable photostability upon nitrogen laser excitation. This has been attributed to the role of the 337 nm light in inducing a back photo-chemical reaction of the initially formed photoproducts consisting mainly of photo-oligomers and cis-photoisomers.

Copyright © 1985 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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